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Chin J Mater Res  2010, Vol. 24 Issue (1): 17-24    DOI:
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Vapor Phase Synthesis and Optic Properties of MoO2 Micro/nanosheet
LIU Xinli1;  WANG Shiliang 1;2;3;  ZHANG Quan1; DENG Yida4;  HE Yuehui1
1.State Key Laboratory of Powder Metallurgy; Central South University; Changsha 410083
2.School of Physics Science and Technology; Central South University; Changsha 410083
3.Key Laboratory of Low Dimensional Materials and Application Technology (Xiangtan University); Ministry of Education; Xiangtan 411005
4.State Key Laboratory of Metal Matrix Composites; Shanghai Jiao Tong University; Shanghai 200030
Cite this article: 

LIU Xinli WANG Shiliang ZHANG Quan DENG Yida HE Yuehu. Vapor Phase Synthesis and Optic Properties of MoO2 Micro/nanosheet. Chin J Mater Res, 2010, 24(1): 17-24.

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Abstract  

MoO2 micro/nanosheets were synthesized by vapor-deposit process and characterized by XRD, SEM, TEM, UV-Vis and photoluminescence (PL) photometer. The results show that MoO2 micro/nanosheet is rectangle, and the length and width range from several to dozens of micrometers and about 200 nm thick. The MoO2  micro/nanosheets have absorbance peaks between 200–300 nm, and three fluorescent excitations at 304.6, 343.4 and 359.6 nm. The synthesis mechanism of MoO2 micro/nanosheets was discussed based on the experimental results and the thermodynamic computation.

Key words:  inorganic nonmetallic materials              molybdenum dioxide        micro/nanosheet       optics property       growth mechanism     
Received:  30 July 2009     
Fund: 

Supported by National Natural Science Foundation of China Nos.50825102, 50804057, 50823006 and
50721003, the China-Australia Special Fund No.50711120183, Natural Science Foundation of Hunan Province
No.08JJ3110, and the Open Project Program of Key Laboratory of Low Dimensional Materials & Application
Technology (Xiangtan University), Ministry of Education, No.KF0705.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2010/V24/I1/17

1 J.Hu, T.W.Odom, C.M.Lieber, Chemistry and physics in one dimension:synthesis and properties of nanowires and nanotubes, Acc. Chem. Res., 32(5), 435(1999)
2 J.J.Auborn, Y.L.Barberio, Lithium intercalation cells without metallic MoO2/LiCoO2 and WO2/LiCoO2, J. Electrochem. Soc., 134(3), 638(1987)
3 G.M.Wallraff, W.D.Hinsberg, Lithographic imaging techniques for the formation of nanoscopic features, Chem. Rev., 99(7), 1801(1999)
4 I.V.Malikov, G.M.Mikhailov, Electrical resistivity of epitaxial molybdenum films grown by laser ablation deposition, Appl. Phys., 82(11), 5555(1997)
5 Zhang S.-L, d’Heurle, F.M,Influence of molybdenum on the formation of C54 TiSi2: template phenomenon versus grain-size effect, Appl. Phys. Lett., 76(14), 1831(2000)
6 Y.K.Liu, C.G.Liang, Z.L.Wang, Y.Z.He, X.L.Lang, M.H.Zhou, Molybdenum film technology for power metal oxide semiconductor field effect transistor gate electrode applications, Jpn. J. Appl. Phys., 39, 3915(2000)
7 Jos´e R.C.Rocha, Lu´?s Kosminsky, Thiago R.L.C.Paix˜a, Mauro Bertotti, Anodic oxidation of nitrite at a molybdenum oxide layer, Electroanalysis, 13(2), 155(2001)
8 K.Galatsis, Y.X.Li, W.Wlodarski, E.Comini, G.Sberveglieri, C.Cantalini, S.Santucci, Comparison of single and binary oxide MoO3, TiO2 and WO3 sol-gel gas, Sensors and Actuators B, 83(1-3), 276(2002)
9 J.N.Yao, K.Hashimoto, A.Fujishima, Photochromism induced in an electrolytically Pretreated MoO3 thin film by visible light, Nature, 355, 624(1992)
10 C.Bechinger, S.Ferrere, A.Zaban, J.Sprague, B.A.Gregg, A photoelectrochromic windows and displays, Nature, 383, 608(1996)
11 S.K.Deb, Reminiscences on the discovery of electrochromic phenomena in transition metal oxides, Sol. Energy Mater. Sol. Cells., 39(2-4), 191(1995)
12 P.Birke, W.F.Chu, W.Weppner, Materials for lithium thin-film batteries for application in silicon technology, Solid State Ion, 93(1-2), 1(1996)
13 J.J.Auborn, Y.L.Barberio, Lithium intercalation cells without metallic lithium, J. Electrochem. Soc., 134(3), 638(1987)
14 Y.B.Li, Y.Bando, D.Golberg, K.Kurashima, Field emission from MoO3 nanobelts, Appl. Phys. Lett., 81(26), 5048(2002)
15 Jingguo Liu, Zhengjun Zhang, Chunyu Pan, Ye Zhao, Xin Su, Ya Zhou, Dapeng Yu, Enhanced field emission properties of MoO2 nanorods with controllable shape and orientation, Mater. Lett., 58(29), 3812(2004)
16 Jun Zhou, Ningsheng Xu, Shaozhi Deng, Jun Chen, Juncong She, Zhonglin Wang, Large-area nanowire arrays of molybdenum and molybdenum oxides, synthesis and field emission properties, Adv. Mater., 15(21), 1835(2003)
17 Yubao Li, Yoshio Bando, Quasi-aligned MoO3 nanotubes grown on Ta substrate, Chem. Phys. Lett., 364(5-6), 484(2002)
18 S.Mitra, K.Sridharan, J.Unnam, K.Ghosh, Synthesis of nanometal oxides and nanometals using hot-wire and thermal CVD, Thin Solid Films, 516(5), 798(2008)
19 Latha Kumari, Yuan-Ron Ma, Chai-Chang Tsai, Yi-Way Lin,Sheng Yun Wu, Kai-Wen Cheng ,Yung Liou, X-ray diffraction and Raman scattering studies on large-area array and nanobranched structure of 1D MoO2 nanorods, Nanotecnology, 18, 115717(2007)
20 WANG Fan, ZHANG Yuling, WEI Qingshuo, WU Kai, XIE Youchang, Synthesis of MoOx nano-arrays on anodic aluminum oxide template by thermal diffusion, Acta Phys.-Chim. Sin., 20(6), 637(2004)
(王 凡, 张玉玲, 卫庆硕, 吴 凯, 谢有昌, 阳极氧化铝模板上热扩散法制备MoOx纳米阵列, 物理化学学报,   20(6), 637(2004))
21 P.M.Ajayan, O.Stephan, Ph.Redlich, C.Colliex, Carbon nanotubes as removable templates for metal oxide nanocomposites and nanostructures, Nature, 375, 564(1995)
22 B.C.Satishkumar, A.Govindaraj, Manashi Nath, C.N.R.Rao, Synthesis of metal oxide nanorods using carbon nanotubes as templates, J. Mater. Chem., 10, 2115(2000)
23 QI Yanyuan, CHEN Wen, MAI Liqiang, HU Bin, JIN Wei, Synthesis and electrochemical property of MoO3 nanobelts from peroxomolybdic acid sols, Rare Metals, 31(1), 67(2007)
(祁琰媛, 陈文, 麦立强, 胡 彬, 金 伟, 过氧钼酸溶胶制备的MoO3纳米带及其电化学性能研究, 稀有金属,  31(1), 67(2007))
24 LOU Xiongweng, Zeng Huachun, Hydrothermal synthesis of α-MoO3 nanorods via acidification of ammonium hep tamolybdate terahydrate, Chem. Mater., 14, 4781(2002)
25 Greta R. Patzke, Alexej Michailovski, Frank Krumeich, Reinhard Nesper, Jan-Dierk Grunwaldt, and Alfons Baiker, One-step synthesis of submicrometer fibers of MoO3, Chem. Mater., 16(6), 1126(2004)
26 WANG Wendi, XU Huayun, LIU Jinhua, ZHANG Shouquan, WANG Dazhi, CHEN Chunhua, Hydrothermal synthesis of MoO3 nanobelts and their electrochemical characterization, Functional Materials, 37(3), 434(2006)
(王文帝, 徐化云, 刘金华, 章守权, 王大志, 陈春华, MoO3纳米纤维电极材料的水热合成和化学表征, 功能材料,  37(3), 434(2006))
27 LI Junsheng, ZHAO Peng, YAO Yanyan, TIAN Xiaozhen, Synthesis of strip-shaped nanoscale MoO3 by hydrothermal process, New Chemical Materials, 35(4), 44(2007)
(李军升, 赵 鹏, 姚燕燕, 田晓珍, 水热法制备薄片状纳米级MoO3微粉, 化工新型材料,  35(4), 44(2007))
28 Antonella M. Taurino, Angiola Forleo, Luca Francioso, Pietro Siciliano, Synthesis, electrical, characterization and gas sensing properties of molybdenum oxide nanorods, Appl. Phys. Lett., 88, 1521111(2006)
29 Z.R.Dai, Z.W.Pan, Z.L.Wang, Novel nanostructures of functional oxides synthesized by thermal evaporation, Advanced Functional Materials, 13(1), 9(2003)
30 A.Katrib, D.Mey, G.Maire, Molybdenum and tungsten dioxides, XO2 (X=Mo, W), as reforming catalysts for hydrocarbon compounds, Catalysis Today, 65(2-4), 179(2001)
31 A.Gulino, S.Parker, F.H.Hones, R.G.Egdell, Influence of metal-metal bonds on electron spectra of MoO2 andWO2, Chem. Soc., Faraday Trans., 92, 2137(1996)
32 Y.G.Liang, S.J.Yang, Z.H.Yi, X.F.Lei, J.T.Sun, Y.H.Zhou, Low temperature synthesis of a stable MoO2 as suitable anode materials for lithium batteries, Mater. Sci. Eng. B, 121, 152(2005)

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