Preparation and Properties of Modified Silicon-containing Arylacetylene Resin Composite Reinforced by Carbon Fiber Cloth

doi:10.11901/1005.3093.2017.626

Chinese Journal of Materials Research

2018, Vol. 32

Issue (6): 464-472 DOI: 10.11901/1005.3093.2017.626

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Preparation and Properties of Modified Silicon-containing Arylacetylene Resin Composite Reinforced by Carbon Fiber Cloth

Tangjun YANG, Sikun DONG, Qiaolong YUAN(

), Farong HUANG

Key Laboratory for Specially Polymeric Materials and Related Technology of the Ministry of Education , East China University of Science and Technology, Shanghai 200237, China

Cite this article:

Tangjun YANG, Sikun DONG, Qiaolong YUAN, Farong HUANG. Preparation and Properties of Modified Silicon-containing Arylacetylene Resin Composite Reinforced by Carbon Fiber Cloth. Chinese Journal of Materials Research, 2018, 32(6): 464-472.

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Abstract

Silicon-containing aryl propargyl ether of bisphenol A (SAPE-BA) and silicon-containing aryl propargyl ether of diphenyl ether (SAPE-DPE) were synthesized and characterized. Then they were used to modify the silicon-containing arylacetylene resin (PSA) respectively by blend process. The modified PSA resins (PSA/SAPE-BA and PSA/SAPE-DPE) were reinforced with T300 carbon fabric to form composites of PSA resins by hot press. The processability, thermal stability, and the mechanical properties of the modified resins and their composites were further investigated. Results show that the modified PSA resins have not only good processing performance, but also high heat-resistance. In comparison with the cured simple PSA resin, the temperature at which 5% mass loss (T_d5) of the two cured modified PSA resins in nitrogen were higher than 550℃ and 590℃, respectively, and the T_g of the cured modified PSA resins were higher than 500℃; The flexural strength of the cured modified resins, PSA/SAPE-BA and PSA/SAPE-DPE increased by 78.3% and 54.2%, respectively. While in comparison with the composite of T300 carbon fabric (T300CF) reinforced simple PSA, the flexural strength and interlayer shear strength (ILSS) of the composite of T300 carbon fabric (T300CF) reinforced PSA/SAPE-BA resin increased by 38.4% and 33.5%, and the flexural strength and ILSS of the composite of T300CF reinforced PSA/SAPE-DPE resin increased by 23.4% and 21.8%, respectively.

Key words: composites silicon-containing aryl propargyl ether silicon-containing arylacetylene blend mechanical property

Received: 20 October 2017

ZTFLH:

TB332

Fund: Supported by the Fundamental Research Funds for the Central Universities (No. 222201717001)

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	Tangjun YANG
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https://www.cjmr.org/EN/10.11901/1005.3093.2017.626 OR https://www.cjmr.org/EN/Y2018/V32/I6/464

Fig.1 Synthetic route of silicon-containing aryl propargyl ether of bisphenol A

Fig.2 Chemical structure of silicon-containing aryl propargyl ether of diphenylether

Fig.3 ¹H NMR spectra of silicon-containing aryl propargyl ether

Fig.4 FTIR spectra of silicon-containing aryl propargyl ether

Fig.5 Viscosity vs time curves of the PSA modified by SAPE-BA (a) and SAPE-DPE (b) at 110℃

Table 1 Gel time of the different SAPE-modified PSA at 170℃

Fig.6 DSC curves of PSA modified by SAPE-BA (a) and SAPE-DPE (b)

Table 2 DSC analysis results of PSA blended with SAPE-BA resin

Table 3 DSC analysis results of PSA blended with SAPE-DPE

Fig.7 TGA curves of cured PSA modified by SAPE-BA (a) and SAPE-DPE (b)

Table 4 TGA analysis results of cured PSA blended with SAPE-BA resin

Table 5 TGA analysis results of cured PSA blended with SAPE-DPE

Fig.8 Thermal cure mechanism of SAPE

Fig.9 Thermal cure mechanism of PSA

Fig.10 Flexural properties of PSA modified by SAPE-BA (a) and SAPE-DPE (b)

Fig.11 Thermal cure mechanism of alkynyl groups between PSA and SAPE

Fig.12 DMA curves of the cured PSA/SAPE-BA20 (a) and PSA/SAPE-DPE15 (b)

Table 6 Mechanical properties of T300CF reinforced SAPE-modified PSA composites

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