Preparation and Characterization of Polytriazole/Carbon Nanotube Composites

doi:10.11901/1005.3093.2014.118

Chinese Journal of Materials Research

2014, Vol. 28

Issue (7): 555-560 DOI: 10.11901/1005.3093.2014.118

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Preparation and Characterization of Polytriazole/Carbon Nanotube Composites

Cunchao ZHANG,Liqiang WAN(

),Jianwen XU,Bing GUO,Farong HUANG

Key Laboratory for Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237

Cite this article:

Cunchao ZHANG,Liqiang WAN,Jianwen XU,Bing GUO,Farong HUANG. Preparation and Characterization of Polytriazole/Carbon Nanotube Composites. Chinese Journal of Materials Research, 2014, 28(7): 555-560.

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Abstract

Azido-carbon nanotube (ACNT) was prepared by the reaction of azide group with carbon nanotube (CNT). The azidation of CNT was proved by FTIR, XPS and so on. Under the effect of ultrasonic wave, ACNT was uniformly dispersed into monomers of polytriazole (PTA), and then PTA/ACNT composites were prepared via in situ polymerization. The dispersion status of ACNT in the matrix resin and the microstructure of PTA/ACNT composites were observed by TEM. The influence of ACNT addition on glass transition temperature (T_g), thermostability parameter (T_d5) and thermal conductivity (λ) of PTA/ACNT composites were also examined. The results showed that in comparison with the blank PTA resin, T_g increased 33℃, T_d5 increased 15℃ in nitrogen atmosphere and 8℃ in air for the PTA/ACNT composite with 1.0% ACNT; while λ increased by 45% at 30℃ and 30% at 150℃ for the PTA/ACNT composite with 5.0% ACNT.

Key words: composites polytriazole CNT azidation thermal properties

Received: 13 March 2014

Fund: *Supported by Shanghai Leading Academic Discipline Project No. B502.

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	Cunchao ZHANG
	Liqiang WAN
	Jianwen XU
	Bing GUO
	Farong HUANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.118 OR https://www.cjmr.org/EN/Y2014/V28/I7/555

Fig.1 Preparation of the PTA/ACNT composites

Fig.2 FTIR spectra of PCNT (a) and ACNT (b)

表1 PCNT和ACNT表面元素含量分析

Fig.3 XPS N1s spectrum of ACNT surface

Fig.4 DSC curves of mixtures, (a) A2/B4, (b) A2/B4/ACNT

Fig.5 Influence of ACNT loading on the T_g of PTA/ACNT composites

表2 不同ACNT含量PTA/ACNT复合材料的T_g数据

Fig.6 TEM images of the PTA/ACNT composites, (a) 1.0 %, (b) 2.0 %

Fig.7 Comparation of TGA (air) curves of PTA/ACNT composite and PTA resin

Fig.8 Comparation of TGA (N₂) curves of PTA/ACNT composite and PTA resin

Table3 TGA data of PTA resin and PTA/ACNT composite

表4 PTA/ACNT复合材料的导热系数

Fig.9 Influence of ACNT loading on the conductivity of PTA/ACNT composites

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