镍钴离子比例对铁氧体吸波性能的影响

doi:10.11901/1005.3093.2023.606

材料研究学报

2025, Vol. 39

Issue (2): 137-144 DOI: 10.11901/1005.3093.2023.606

研究论文

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镍钴离子比例对铁氧体吸波性能的影响

王光明¹, 马志军¹^,²(

), 郑云生¹, 程亮¹, 杭文武¹

1 辽宁工程技术大学矿业学院阜新 123000
2 辽宁工程技术大学材料科学与工程学院阜新 123000

Effect of Nickel-cobalt Ion Ratio on Ferrite Wave-absorbing Properties

WANG Guangming¹, MA Zhijun¹^,²(

), ZHENG Yunsheng¹, CHENG Liang¹, HANG Wenwu¹

1 College of Mining, Liaoning Technical University, Fuxin 123000, China
2 College of Materials Science & Engineering, Liaoning Technical University, Fuxin 123000, China

引用本文:

王光明, 马志军, 郑云生, 程亮, 杭文武. 镍钴离子比例对铁氧体吸波性能的影响[J]. 材料研究学报, 2025, 39(2): 137-144.
Guangming WANG, Zhijun MA, Yunsheng ZHENG, Liang CHENG, Wenwu HANG. Effect of Nickel-cobalt Ion Ratio on Ferrite Wave-absorbing Properties[J]. Chinese Journal of Materials Research, 2025, 39(2): 137-144.

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摘要:

用溶胶-凝胶法制备尖晶石型Ni _x Co_{1 -}_x Fe₂O₄，使用X射线衍射仪(XRD)、透射电子显微镜(TEM)、矢量网络分析仪(VNA)等手段表征其晶型、粒度、微观形貌、电磁损耗以及吸波性能，研究了镍钴离子比例对其结构和吸波性能的影响。结果表明：柠檬酸与金属离子摩尔比为1∶1的铁氧体Ni _x Co_{1 -}_x Fe₂O₄其平均粒径为66.00~70.00 nm。Ni²⁺∶Co²⁺ = 5∶5的铁氧体Ni _x Co_{1 -}_x Fe₂O₄吸波性能最好，在吸收层厚度为3.00 mm频率为17.32 GHz处的反射损耗值最小值为-16.15 dB，有效频带宽度为2.21 GHz (15.79~18.00 GHz)，处于Ku波段内。Ni_0.5Co_0.5Fe₂O₄优异的吸波性能，归因于交换共振和涡流损耗的共同作用。

关键词 ：溶胶-凝胶法, 尖晶石, 镍钴铁氧体, 离子比例, 吸波性能

Abstract：

Spinel ferrite Ni _x Co_{1 -}_x Fe₂O₄ was prepared by sol-gel method, and the effect of different ion ratios Ni²⁺∶Co²⁺ on its structure and wave-absorbing properties were studied by means of X-ray diffraction (XRD), transmission electron microscopy (TEM) and vector network analyzer (VNA). Focus on its following features: crystallographic structure, particle size, micromorphology, electromagnetic loss and wave-absorbing performance. The results showed that the average particle size of ferrite wave-absorbers prepared with a molar ratio of citric acid to metal ions of 1∶1 by pH = 7 and followed by being crystalized 950 ^oC for 3 h, is 66.00~70.00 nm. When Ni²⁺∶Co²⁺ = 5∶5, Ni_0.5Co_0.5Fe₂O₄ has the best wave-absorbing performancewith the minimum reflection loss value is -16.15 dB at the absorption layer thickness of 3.00 mm and the frequency is 17.32 GHz, and the effective frequency band width is 2.21 GHz (15.79~18.00 GHz), which is in the Ku band, and the excellent wave-absorbing performance of Ni_0.5Co_0.5Fe₂O₄ is attributed to the combined effect of exchange resonance and eddy current loss.

Key words： sol-gel method spinel nickel-cobalt ferrite ion ratio wave-absorbing properties

收稿日期: 2023-12-25

ZTFLH:

TM277

基金资助:国家自然科学基金(52274265)

通讯作者: 马志军，教授，zhijunma0930@126.com，研究方向为功能性矿物材料

Corresponding author: MA Zhijun, Tel: 13941881359, E-mail: zhijunma0930@126.com

作者简介: 王光明，男，1997年生，硕士

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https://www.cjmr.org/CN/10.11901/1005.3093.2023.606 或 https://www.cjmr.org/CN/Y2025/V39/I2/137

图1 不同Ni2+、Co2+掺杂比例的镍钴铁氧体的XRD谱

表1 镍钴铁氧体的结构参数

图2 不同Ni2+、Co2+掺杂比的镍钴铁氧体的TEM照片

图3 不同掺杂比Ni x Co1 - x Fe2O4样品的反射损耗、频率和厚度曲线

表2 镍钴铁氧体、镍铁氧体和钴铁氧体的晶粒尺寸

表3 镍钴铁氧体、镍铁氧体和钴铁氧体的吸波性能

表4 用不同方法制备的镍钴铁氧体、镍铁氧体和钴铁氧体的吸波性能

图4 Ni x Co1 - x Fe2O4样品的tanδe、tanδm和频率曲线

图5 Ni x Co1 - x Fe2O4样品的tanδ、C0和频率曲线

图6 Ni x Co1 - x Fe2O4样品的衰减常数和频率曲线

图7 Ni0.5Co0.5Fe2O4样品的阻抗匹配、反射损耗和频率曲线

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