Please wait a minute...
材料研究学报  2010, Vol. 24 Issue (5): 513-454    
  研究论文 本期目录 | 过刊浏览 |
工艺条件对Mg-3Sn-Mn合金连续流变成形组织的影响机理
赵占勇, 管仁国,  曹富荣, 崔彤, 黄红乾
东北大学材料与冶金学院 沈阳 110004
Effects of Process Conditions on the Microstructure of Mg--3Sn--Mn Alloy During Continuous Rheo--forming Process
ZHAO Zhanyong, GUAN Renguo, CAO Furong, CUI Tong, HUANG Hongqian
School of Materials and Metallurgy, Northeastern University, Shenyang 110004
引用本文:

赵占勇 管仁国 曹富荣 崔彤 黄红乾. 工艺条件对Mg-3Sn-Mn合金连续流变成形组织的影响机理[J]. 材料研究学报, 2010, 24(5): 513-454.
, . Effects of Process Conditions on the Microstructure of Mg--3Sn--Mn Alloy During Continuous Rheo--forming Process[J]. Chin J Mater Res, 2010, 24(5): 513-454.

全文: PDF(1167 KB)  
摘要: 制备Mg--3Sn--Mn合金型材, 研究了连续流变成形工艺条件对制品组织的影响机理。结果表明: 当轧辊转速一定而合金浇注温度在690--750℃变化时, 随着浇注温度的降低, 结晶前沿的成分过冷度增大, 合金中心固相率增加, 从而使制品边部柱状晶区增大, 中心等轴晶区减小, 等轴晶区的晶粒平均直径减小。当合金浇注温度一定, 二轧辊转速在0.052--0.087 m · s -1变化时, 随着轧辊转速的减小凝固界面趋于稳定, 合金在辊靴型腔中随剪切时间的增加制品边部柱状晶区减小, 中心等轴晶区增大。浇注温度为690℃、轧辊转速为0.052 m · s-1时制备的断面为5 mm x 50 mm的镁合金型材,其表面质量和组织良好, 制品晶粒平均直径为27 μm。
关键词 材料合成与加工工艺  连续流变成形  镁合金  工艺条件  组织  机理    
Abstract:Mg–3Sn–Mn alloy profiles have been successfully manufactured by the continuous rheo–forming equipment self–designed, and the effects of process conditions on the microstructures of the products were investigated. The results show that when the roll is at a certain speed and the casting temperature varies from 690oC  to 750oC with the decrease of casting temperature, the composition supercooling in front of solid–liquid interface and the solid fraction in the center increase, so, the width of columnar grain zone near the edge of the product increases, the equiaxed grain zone in the central position decreases, and the average diameter of grains in the equiaxed grain zone decreases. When casting temperature is kept constant and roll speed varies from 0.052 m·s−1 to 0.087 m·s−1, with the decrease of roll speed, the solid–liquid interface tends to be stable and the melt is subjected to the shear in the roller–shoe cavity for a long time, so, the width of columnar grain zone near the edge of the product decreases and the width of equiaxed grain zone in the central position increases. When the casting temperature is 690oC  and roll speed is 0.052 m·s−1, magnesium alloy profiles with cross–section of 5 mm×50 mm have been obtained, the surface and microstructure of the products are excellent, and the average grain size of the product is 27 μm.
Key wordssynthesizing and processing technics    continuous rheo--forming     magnesium alloy    procedure conditions    microstructure    mechanism
收稿日期: 2010-06-21     
ZTFLH: 

TG244

 
基金资助:

国家自然科学基金50974038、51034002,中央高校基本科研业务费N090502003, 国家高技术研究发展计划2007AA03Z111和教育部新世纪优秀人才支持计划NCET--08--0097资助项目。

[1]R.F.DECKER.The renaissance in magnesium.Advanced Material & Process,1998,157(9):31- [2]YU Kun, LI Wenxian, WANG Richu, MA Zhengqing, Research.development and application of wrought magnesium alloys.The Chinese Journal of Nonferrous Metals,2003,13(2):277- [3]余琨, 黎文献, 王日初, 马正青.变形镁合金的研究、开发及应用.中国有色金属学报,2003,13(2):277- [4]A.YAMASHITA, Z.HORITA, T.G.Improving the mechanical properties of magnesium and a magnesium alloy through severe plastic deformation.Mat. Sci. Eng,2001,A300:142- [5]A.BUSSIBA, A.BENARTZY, A.SHTECHMAN, S.IFERGAN, M.KUPIEC.Grain refinement of AZ31 and ZK60 Mg alloys-towards superplasticity studies.Mat. Sci. Eng,2001,A302:56- [6]J.B.COLLEEN, A.G.MARK.Current wrought magnesium alloys strengths and weaknesses.JOM,2005,57(5):46- [7]Y.CHINO, M.KOBATA, H.WASAKI, M.MABUCHI.An investigation of compressive deformation behaviour for AZ91 Mg alloy containing a small 51 of liquid.Acta Materialia,2003,51:3309- [8]M.C.FLEMINGS.Behavior of metal alloys in the semisolid state.Metall. Trans,1991,22A:957- [9]D.H.KIRKWOOD.Semisolid metal processing.International Materials Reviews,1994,39:173- [10]S.P.MIDSON.Rheocasting processes for semi-solid casting of aluminum alloys.Die Casting Engineer,2006,50(1):48- [11]S.JI, Z.FAN, M.J.BEVIS.Semi-solid processing of engineering alloys by a twin-screw rheomolding process.Mat. Sci. Eng,2001,A299:210- [12]R.A.MARTINEZ, M.C.FLEMINGS.Evolution of particle morphology in semisolid processing.Metallurgical and Materials Transactions A,2005,36(8):2205- [13]D.APELIAN, Q.Y.PAN, M.FINDON.Low cost and energy efficient methods for the manufacture of semi-solid (SSM) feedstock.Die Casting Engineer,2004,48(1):22- [14]T.HAGA, P.KAPRANOS.Simple rheocasting processes.Journal of Materials Processing Technology,2002,130/131:594- [15]T.HAGA, K.TKAHASHI, M.IKAWAAND, H.WATARI.Twin roll casting of aluminum alloy strips.Journal of Materials Processing Technology,2004,153-154:42- [16]WEN Jinglin, GUAN Renguo, LIU Xianghua.Manufaeturing semisolid A2017 alloy by srs Proeess and semisolid extending forming.Chinese Journal of Materials Research,2003,17(1):56- [17]温景林, 管仁国, 刘相华.A2017半固态合金的半固态扩展成形.材料研究学报,2003,17(1):56- [18]ZHAO Zhanyong, GUAN Renguo, LI Jiangping, WANG Fuxing.Effect of Casting Temperature on Microstructure of AZ31 Alloy in Continuous Rheo-Extrusion Process.Journal of Northeastern University(Natural Science,2010,31(4):535- [19]赵占勇, 管仁国, 李江平, 王付兴.浇注温度对AZ31镁合金连续流变挤压成形组织的影响.东北大学学报(自然科学版,2010,31(4):535- [20] HU Hanqi, Metal Solidification Principle (Beijing, China Machine Press, 2000) P.12 [21](胡汉起, 金属凝固原理, 第二版, (北京: 机械工业出版社, 2000年)P.127
[1] 周海涛, 侯湘武, 汪彦博, 肖旅, 袁勇, 孙京丽. Nb-TiAl合金的高温变形行为及其板材的性能[J]. 材料研究学报, 2022, 36(6): 471-480.
[2] 闫福照, 李静, 熊良银, 刘实. FeCr-ODS铁素体合金的氧化+粉锻工艺制备及其微观结构[J]. 材料研究学报, 2022, 36(6): 461-470.
[3] 王永鹏, 贾治豪, 刘梦竹. 二维CdO纳米棒的制备及其用于葡萄糖传感器的可行性[J]. 材料研究学报, 2021, 35(1): 53-58.
[4] 夏傲, 赵晨鹏, 曾啸雄, 韩曰鹏, 谈国强. B掺杂MnO2的制备及其电化学性能[J]. 材料研究学报, 2021, 35(1): 36-44.
[5] 蔡国栋, 程西云, 王典. FDM3D打印316L不锈钢试样和La对析出物形貌和分布的影响[J]. 材料研究学报, 2020, 34(8): 635-640.
[6] 谢礼兰, 杨冬升, 凌静. 高容量锂电池负极材料TiNb2O7的合成及其机理[J]. 材料研究学报, 2020, 34(5): 385-391.
[7] 马炜杰,杨西荣,罗雷,刘晓燕,郝凤凤. 复合形变超细晶纯钛的动态再结晶模型[J]. 材料研究学报, 2020, 34(3): 217-224.
[8] 姜巨福, 王迎, 肖冠菲, 邓腾, 刘英泽, 张颖. 变质细化和热处理对挤压铸造成形A356铝合金构件性能的影响[J]. 材料研究学报, 2020, 34(12): 881-891.
[9] 杨占鑫, 吴琼, 任奕桥, 屈凯凯, 张哲豪, 仲为礼, 范广宁, 齐国超. 宏量制备层状Ti3C2及其超级电容的性能[J]. 材料研究学报, 2020, 34(11): 861-867.
[10] 秦斌,王群,王富孟,靳利娥,解小玲,曹青. 高电导率低热膨胀系数针状焦的制备[J]. 材料研究学报, 2019, 33(1): 53-58.
[11] 王强, 郝瑞亭, 赵其琛, 刘思佳. 多周期分层溅射硫化物靶制备铜锌锡硫薄膜太阳电池[J]. 材料研究学报, 2018, 32(6): 409-414.
[12] 刘正华, 王兢, 杜海英, 王惠生, 李晓干, 王小风. 基于联合仿真方法研究静电纺丝轨迹[J]. 材料研究学报, 2018, 32(2): 127-135.
[13] 李延伟, 谢志平, 刘参政, 姚金环, 姜吉琼, 杨建文. 二维褶皱状V2O5纳米材料的制备和储锂性能[J]. 材料研究学报, 2017, 31(5): 374-380.
[14] 李成冬, 姚志垒, 李举, 徐进, 熊新. LaF3表面修饰Li[Li0.2Mn0.54Ni0.13Co0.13]O2的制备及其电化学性能[J]. 材料研究学报, 2017, 31(5): 394-400.
[15] 唐昭辉, 丁学勇, 董越, 刘程宏, 魏国. w(MgO)对高钛高炉渣黏流特性的影响*[J]. 材料研究学报, 2016, 30(6): 443-447.