Please wait a minute...
材料研究学报  2001, Vol. 15 Issue (4): 467-472    
  论文 本期目录 | 过刊浏览 |
新型锂离子电池负极材料CoFe3Sb12
蒋小兵;赵新兵;张丽娟;曹高劭;吕春萍;周邦昌
浙江大学
引用本文:

蒋小兵; 赵新兵; 张丽娟; 曹高劭; 吕春萍; 周邦昌 . 新型锂离子电池负极材料CoFe3Sb12[J]. 材料研究学报, 2001, 15(4): 467-472.

全文: PDF(386 KB)  
摘要: 采用真空熔炼与高能球磨方法制备了CoFe3Sb12合金粉末,并研究了其电化学性能。研究结果表明CoFe3Sb12的活性元素Sb可以与锂离子进行可逆电化学反应,其嵌锂产物为Li3Sb。CoFe3Sb12电极在20mA/g的电流密度下第一次可逆容量可以达到396mAh/g。在材料中加入50at.%石墨(化学计量式为CoFe3Sb12-C16),以100mA/g进行充放电时,第一次可逆容量达到380mAh/g;而且其在大电流和小电流密度下的循环寿命皆比较优良。所以其可作为锂离子电池负极材料的候选材料。
关键词 锂离子电池负极材料CoFe3Sb12    
Key words
收稿日期: 1900-01-01     
1 T.Tsuchiyama,R.Hirota,K.Fukunaga,S.Takaki,Ridging- free ferritic stainless steel produced through recrystalliza- tion of lath martensite,ISIJ Int.,45(6),923(2005)
2 H.C.Chao,J.D.Defilippi,Effect of chromium and molyb- denurn segregation on the ridging behavior of type 434 stainless steel,Metall.Trans.,2(11),3209 (1971)
3 K.Suzuki,S.Asami,K.Suzuki,Formation of ridging re- lated to the banded segregation pattern of chromium and carbon on ferritic stainless steel sheet,Trans.ISIJ,23(9), 731 (1983)
4 H.C.Chao,The mechanism of ridging in ferritic stainless steels,Trans.ASM,60(1),37(1967)
5 H.Takechi,H.Kato,T.Sunami,T.Nakayama,The mecha- nism of ridging phenomenon in 17% chromium stainless steel sheets,Trans.JIM,31(6),717 (1967)
6 R.N.Wright,Anisotropic plastic flow in ferritic stainless steels and the roping phenomenon,Metall.Trans.,3(1), 83(1972)
7 K.Bethke,M.HSlcher,K.Liicke,Local orientation investi- gation on the ridging phenomenon in iron 17% chromium steel,Mater.Sci.Forum,15"g-162(2),1137(1994)
8 H.M.Kim,J.A.Szpunar,Ridging phenomena in textured ferritic stainless steel sheets,Mater.Sci.Forum,157- 162,753(1994)
9 M.Brochu,T.Yokota,S.Satoh,Analysis of grain colonies in type 430 ferritic stainless steels by electron back scat- tering diffraction,ISIJ Int.,37(9),872(1997)
10 K.Sztwiertnia,J.Pospiech,Orientation topography and ridging phenomenon in ferritic stainless steel sheets,Arch Metall,44(2),157(1999)
11 H.Takeuchi,H.Mori,Y.Ikehara,T.Komano,T.Yanai,The effects of electromagnetic stirring on cast structure of continuously cast SUS430 stainless steel slabs,Tetsu-to- Hagané,66,638(1980)
12 Y.Itoh,S.Takao,T.Okajima,K.Tashiro,Effects of alloying elements and inoculators on refining of solidification struc- tures of type 430 stainless steel,Tetsu-to-Hagané,66(6), 710(1980)
13 Y.Itoh,T.Okajima,H.Maede,K.Tashiro,Refining of solid- ification structures of continuously cast type 430 stainless steel slabs by electromagnetic stirring,Tetsu-to-Hagané, 67(7),946(1981)
14 H.J.Shin,J.K.An,S.H.Park,D.N.Lee,The effect of tex- ture on ridging of ferritic stainless steel,Acta Materialia, 51,4693(2003)
15 J.Hamada,Y.Matsumoto,F.Fudanoki,S.Maeda,Effect of initial solidified structure on ridging phenomenon and tex- ture in type 430 ferritic stainless steel sheets,ISIJ Int., 43(12),1989(2003)
16 N.Tsuji,K.Tsuzaki,T Maki,Effects of rolling reduction and annealing temperature on the recrystailization struc- ture of solidified columnar crystals in a 19% Cr ferritic stainless steel,ISIJ Int.,34(12),1008(1994)
17 N.Tsuji,K.Tsuzaki,T.Maki,Effect of initial orientation on the cold rolling behavior of solidified columnar crys- tals in a 19% Cr ferritic stainless steel,ISIJ Int.,32(12), 1319(1992)
18 N.Tsuji,K.Tsuzaki,T.Maki,Effect of initial orientation on the recrystallization behavior of solidified columnar crystals in a 19% Cr ferritic stainless steel,ISIJ Int.,33(7), 783(1993)
19 M.-Y.Huh,O.Engler,Effect of intermediate annealing on texture,formability and ridging of 17%Cr ferritic stainless steel sheet,Mater.Sci.Eng.A,308,74(2001)
20 Y.Yazawa,Y.Ozaki,Y.Kato,O.Furukimi,Development of ferritic stainless steel sheets with excellent deep drawabil- ity by {111} recrystallization texture control,JSAE Rev., 24,483(2003)
21 D.Daniel,J.J.Jonas,Measurement and prediction of plas- tic anisotropy in deep-drawing steels,Metall.Trans.A, 21A,33(1990)
[1] 李延伟, 罗康, 姚金环. Ni(OH)2 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[2] 刘东璇, 陈平, 曹新荣, 周雪, 刘莹. 碗状C@FeS2@NC复合材料的制备及其电化学性能[J]. 材料研究学报, 2023, 37(1): 1-9.
[3] 李玲芳, 原志朋, 范长岭. SnO2@Ti3C2Tx 负极材料的制备及其应用[J]. 材料研究学报, 2022, 36(8): 602-608.
[4] 赵超锋, 郑小燕, 李凯瑞, 贾世奎, 张明, 黎业生, 吴子平. 碳纳米管膜表面金属化用于高电流输出柔性锂离子电池[J]. 材料研究学报, 2022, 36(5): 373-380.
[5] 肖揽, 于文华, 黄昊, 吴爱民, 靳晓哲. 锂离子电池负极材料TiS3 纳米片的制备和性能[J]. 材料研究学报, 2022, 36(11): 821-828.
[6] 夏傲, 赵晨鹏, 曾啸雄, 韩曰鹏, 谈国强. B掺杂MnO2的制备及其电化学性能[J]. 材料研究学报, 2021, 35(1): 36-44.
[7] 刘芝君, 李之锋, 王春香, 谢光明, 黄庆研, 钟盛文. 四氧化三钴/碳纳米管薄膜的水热合成及其储锂性能[J]. 材料研究学报, 2020, 34(8): 584-590.
[8] 李玲芳, 曾斌, 原志朋, 范长岭. 一步水热法制备纳米SnO2@C复合材料及其储锂性能研究[J]. 材料研究学报, 2020, 34(8): 591-598.
[9] 谢礼兰, 杨冬升, 凌静. 高容量锂电池负极材料TiNb2O7的合成及其机理[J]. 材料研究学报, 2020, 34(5): 385-391.
[10] 巩桂芬,李泽,王磊,崔巍巍. 静电纺TiO2改性联苯型聚酰亚胺锂离子电池隔膜[J]. 材料研究学报, 2020, 34(3): 169-175.
[11] 薛江陪,姜春海,邹智敏,潘炳炫. LiCoO2/LiNi0.8Co0.15Al0.05O2混合正极的颗粒级配与电化学性能[J]. 材料研究学报, 2019, 33(3): 170-176.
[12] 肖雅丹,靳晓哲,黄昊,吴爱民,高嵩,刘佳. MoP纳米粒子锂离子电池负极材料的制备及其电化学性能[J]. 材料研究学报, 2019, 33(1): 65-71.
[13] 高荣贞, 李晓冬, 刘文凤, 尹艳红, 杨书廷. 分级结构类球形MgFe2O4/C复合材料的制备及其储锂性能[J]. 材料研究学报, 2018, 32(9): 713-720.
[14] 钟盛文, 张华军, 姚文俐, 张骞, 付宇坤, 唐小冬. LiNi0.5Mn0.5-xCoxO2(0≤x≤0.12)正极材料的制备及其电化学性能[J]. 材料研究学报, 2018, 32(7): 487-494.
[15] 李成冬, 姚志垒, 李举, 徐进, 熊新. LaF3表面修饰Li[Li0.2Mn0.54Ni0.13Co0.13]O2的制备及其电化学性能[J]. 材料研究学报, 2017, 31(5): 394-400.