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Chinese Journal of Materials Research  2026, Vol. 40 Issue (4): 313-320    DOI: 10.11901/1005.3093.2025.155
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Preperation and Electrochemical Performance of Rare Earth La3+-doped Vanadium Dioxide
ZHAO Ruize, TIAN Li(), SONG Peiyuan, FANG Yao, SUN Meng, FAN Sainan, OU Zhimin, ZHU Haibo, HUANG Rongjiao, YANG Li
School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, Hunan University of Science and Technology, Xiangtan 411201, China
Cite this article: 

ZHAO Ruize, TIAN Li, SONG Peiyuan, FANG Yao, SUN Meng, FAN Sainan, OU Zhimin, ZHU Haibo, HUANG Rongjiao, YANG Li. Preperation and Electrochemical Performance of Rare Earth La3+-doped Vanadium Dioxide. Chinese Journal of Materials Research, 2026, 40(4): 313-320.

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Abstract  

Regarding the structural instability and poor cycling performance of vanadium-based oxide cathode materials during the charge-discharge processes in aqueous zinc-ion batteries, a series of La3+-doped VO2 materials (La3+-VO2) have been synthesized via a simple hydrothermal method. The results of electrochemical measurement indicate that an appropriate amount of rare-earth La3+-doping could enhance the rate capability and cycling stability of VO2 electrodes. When the V:La molar ratio is 2:0.3, the prepared La3+-VO2 electrode exhibits a specific capacity of 160.2 mAh·g-1 at a current density of 0.1 A·g-1 and a discharge specific capacity of 131.9 mAh·g-1 with a capacity retention rate of 82% after 100 cycles. The rate capability tests reveal the electrode with a maximum specific capacity of 209.8 mAh·g-1 at a current density of 0.1 A·g-1 and with a capacity of 60.8 mAh·g-1 at a high current density of 5.0 A·g-1, and with a maximum specific capacity of 217.6 mAh·g-1 when the current density returned 0.1 A·g-1, showing good reversibility and structural stability of the La3+-VO2 electrodes. The electrode maintains a specific capacity of 52.2 mAh·g-1 after 1000 cycles at 1.0 A·g-1 demonstrating good cycling performance even at high current densities. The electrochemical kinetic analysis indicates that the charge-discharge process of the La3+-VO2 electrode is simultaneously governed by both capacitive and diffusion-controlled reactions with the pseudocapacitive contribution percentages of 77% and 88% at scan rates of 0.2 mV·s-1 and 1.0 mV·s-1, respectively showing its fast kinetic behavior. The contribution of the capacitive charge storage mechanism ensures the excellent cycling stability of the La3+-VO2 electrode at high capacity and high-rate conditions.

Key words:  inorganic non-metallic materials      aqueous zinc-ion battery      hydrothermal method      vanadium dioxide     
Received:  24 April 2025     
ZTFLH:  TQ152  
Fund: National Natural Science Foundation of China(51202066);Program for New Century Excellent Talents in University(NCET-13-0784);National College Student Innovation and Entrepreneurship Training Program(202510534057);Hunan Province Postgraduate Research Innovation Project(CX20251560);National College Student Innovation and Entrepreneurship Training Program(S202510534131);Teaching Reform Research Project (No.G325E3) and Student Research and Innovation Program (No.YZ2553) of Hunan University of Science and Technology(G325E3)
Corresponding Authors:  TIAN Li, Tel: 18627323439, E-mail: 849050031@qq.com

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2025.155     OR     https://www.cjmr.org/EN/Y2026/V40/I4/313

Fig.1  XRD patterns of La3+ pre-intercalated VO2 electrode materials
Fig.2  EDS pattern and element distribution (inset) of La3+-doped VO2 electrode materials (0.30La3+-VO2)
Fig.3  SEM images of 0La3+-VO2 sample (a-d) and 0.3La3+-VO2 sample (e-h)
Fig.4  First three cycles of cyclic voltammetry curves of 0La3+-VO2 (a), 0.15La3+-VO2 (b), 0.3La3+-VO2 (c) and 0.45La3+-VO2 (d) at a scan rate of 0.1 mV·s-1
Fig.5  Cycling performance of La3+-VO2 (a) and GCD curves of 0.30La3+-VO2 at 0.1 A·g-1 (b)
Fig.6  Rate performance of La3+-VO2 (a) and GCD curves of 0.30La3+-VO2 at different current densities ranging from 0.1 A·g-1 to 5.0 A·g-1 (b)
Fig.7  Cycling performance of La3+-VO2 at 1.0 A·g-1
Fig.8  First cycle Nyquist curves of La3+-VO2
Fig.9  CV curves of 0.3La3+-VO2 (a) and 0.45La3+-VO2 (b) at different scan rates and b-value fitting graphs for 0.30La3+-VO2 (c) and 0.45La3+-VO2 samples (d)
Fig.10  Pseudocapacitance contribution ratio of 0.30La3+-VO2 (a) and 0.45La3+-VO2 (b) at 0.2 mV·s-1 and capacitive contribution rate of 0.30La3+-VO2 (c) and 0.45La3+-VO2 (d) samples at different scan rates
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