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| Preparation and Photovoltaic Performance of Novel Ruthenium Complex and Its Self-assembly Membrane |
Li YANG1,2,3,Zhiyuan TANG1,2,3,Tengteng LI1,2,3,Qiwei DUAN1,2,3,Jiali HU1,2,3,Sufang ZHANG1,2,3,Zhaoqiang ZHENG1,2,3( ) |
1. Engineering & Technology Research Center for Environmental Protection Materials and Equipment of Jiangxi Province, Pingxiang 337055, China
2. Key Laboratory for Industrial Ceramics of Jiangxi Province, School of Materials and Chemistry Engineering, Pingxiang University, Pingxiang 337055, China
3. School of Materials and Chemistry Engineering, Pingxiang University, Pingxiang 337055, China |
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Cite this article:
Li YANG,Zhiyuan TANG,Tengteng LI,Qiwei DUAN,Jiali HU,Sufang ZHANG,Zhaoqiang ZHENG. Preparation and Photovoltaic Performance of Novel Ruthenium Complex and Its Self-assembly Membrane. Chinese Journal of Materials Research, 2019, 33(8): 614-620.
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Abstract A novel symmetrical ruthenium complex (Ru-1) bearing pyrene groups was synthesized, and its molecular structure and purity were characterized by 1H-NMR and ESI-MS. The ruthenium complex delivered ideal stability and performance over a wider range of temperature (below 400°C), which suggests that the stability of this material can satisfy the requirement of dye-sensitized solar cell. Thin films of Ru-1 complex can be prepared onto both graphene- and HOPG-electrode surface via self-assembly process, then their surface morphology and photoelectricity property were examined by means of AFM, Cyclic voltammetry and UV-vis spectroscopy. The results show that the growth of the film was uniform. A couple of sensitive and reversible redox peaks were acquired from the cyclic voltammograms of Ru-1 modified carbon electrodes, the Ru (II/III) oxidative peak was observed at 0.47 V. Uv-vis absorption spectra show that the membrane materials have intense and wide absorption peaks in a wider range, which is favorable for capture sunlight at longer wavelength. In sum, a carbon electrode of excellent photoelectric properties and stability can be obtained by modifying both graphene and HOPG electrodes with Ru-1complex.
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Received: 23 December 2018
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| Fund: Supported by National Science and Technology Major Project(No. SQ2016ZY01003836);National Natural Science Foundation of China(No. 21767023);Jiangxi Educational Committee Science Foundation for Youths(Nos. GJJ151258);Jiangxi Educational Committee Science Foundation for Youths(Nos. GJJ151260) |
| [1] | Gal M, Lobo-Recio M A, Marzin C, et al. Dynamic NMR conformational studies of ruthenium(II) tetraazaporphyrinogen complexes [J]. Inorg. Chem., 1994, 33: 4054 | | [2] | Wan D, Lai S H, Zeng C C, et al. Ruthenium(II) polypyridyl complexes: synthesis, characterization and anticancer activity studies on BEL-7402 cells [J]. J. Inorg. Biochem., 2017, 173: 1 | | [3] | Zhao J, Ma J, Nan X, et al. Effect of nanotube morphologies on multi-walled carbon nanotubes based counter electrode for dye-sensitized solar cell [J]. J. Nanosci. Nanotechnol., 2017, 17: 788 | | [4] | Cisneros R, Beley M, Lapicque F, et al. Hydrophilic ethylene‐glycol‐based ruthenium sensitizers for aqueous dye‐sensitized solar cells [J]. Eur. J. Inorg. Chem., 2016, 2016: 33 | | [5] | Dong Q C, Qu W S, Wang P, et al. A novel supramolecular system with multiple fluorescent states constructed by orthogonal self-assembly [J]. Polym. Chem, 2016, 7: 3827 | | [6] | Konti G, Vougioukalakis G C, Bidikoudi M, et al. A Ru(II) molecular antenna bearing a novel bipyridine-acrylonitrile ligand: Synthesis and application in dye solar cells [J]. Polyhedron, 2014, 82: 12 | | [7] | Kuramochi Y, Ishitani O, Ishida H. Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes [J]. Coord. Chem. Rev., 2018, 373: 333 | | [8] | Cheng F X, He C X, Yu S W, et al. Highly selective SCN- fluorescent sensing by a Ru(II) complex containing functionalized polypyridine [J]. Inorg. Chim. Acta, 2017, 462: 43 | | [9] | Butler M J, Crimmin M R. Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals [J]. Chem. Commun., 2017, 53(8): 1348 | | [10] | Wang Z M, Zhu X L, Li Y M, et al. Effect of B and Ru co-modification on structure and photocatalytic activity of TiO2 nanotubes [J]. Chin. J. Mater. Res., 2018, 32(9): 655 | | [10] | 王竹梅, 朱晓玲, 李月明等. B和Ru共改性对TiO2纳米管阵列的结构和光催化性能的影响 [J]. 材料研究学报, 2018, 32(9): 655) | | [11] | Wang Y H, Qin Y, Yao M, et al. Molecular dynamics simulation of a chiral self-assembled structure of a BIC and HA system on a HOPG surface driven by hydrogen bonds [J]. Acta Phys. Chim. Sin., 2016, 32: 2255 | | [11] | 王云赫, 秦 圆, 姚 曼等. BIC和HA体系的氢键驱动的HOPG表面手性自组装分子动力学模拟 [J]. 物理化学学报, 2016, 32: 2255 | | [12] | Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films [J]. Science, 2004, 306: 666 | | [13] | Hou D S, Lu Z Y, Li X Y, et al. Reactive molecular dynamics and experimental study of graphene-cement composites: structure, dynamics and reinforcement mechanisms [J]. Carbon, 2017, 115: 188 | | [14] | Lv S H, Zhang J, Luo X Q, et al. Microstructure and properties for composites of graphene oxide/cement [J]. Chin. J. Mater. Res., 2018, 32(8): 233 | | [14] | 吕生华, 张 佳, 罗潇倩等. 氧化石墨烯/水泥基复合材料的微观结构和性能 [J]. 材料研究学报, 2018, 32(8): 233) | | [15] | Kuilla T, Bhadra S, Yao D H, et al. Recent advances in graphene based polymer composites [J]. Prog. Polym. Sci., 2010, 35: 1350 | | [16] | Zhao L J, Zhao F Q, Zeng B Z. Preparation and application of sunset yellow imprinted ionic liquid polymer - ionic liquid functionalized graphene composite film coated glassy carbon electrodes [J]. Electrochim. Acta, 2014, 115: 247 | | [17] | Xu Y X, Bai H, Li G W, et al. Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets [J]. J. Am. Chem. Soc., 2008, 130: 5856 | | [18] | Yang Y C, Wu B, Liu Y Q. Synthesis of bilayer graphene via chemical vapor deposition and its optoelectronic devices [J]. Acta Phys. Sin., 2017, 66(21): 177 | | [18] | 杨云畅, 武 斌, 刘云圻. 双层石墨烯的化学气相沉积法制备及其光电器件 [J]. 物理学报, 2017, 66(21): 177) | | [19] | Ratnesh R K, Mehata M S. Synthesis and optical properties of core-multi-shell CdSe/CdS/ZnS quantum dots: Surface modifications [J]. Opt. Mater., 2017, 64: 250 | | [20] | Zaragoza-Galán G, Fowler M A, Duhamel J, et al. Synthesis and characterization of novel pyrene-dendronized porphyrins exhibiting efficient fluorescence resonance energy transfer: optical and photophysical properties [J]. Langmuir, 2012, 28: 11195 | | [21] | Yang L, Ozawa H, Koumoto M, et al. “Janus-type” ruthenium complex bearing both phosphonic acids and pyrene groups for functionalization of ITO and HOPG Surfaces [J]. Chem. Lett., 2015, 44: 160 | | [22] | Donley C, Dunphy D, Paine D, et al. Characterization of indium-tin oxide interfaces using X-ray photoelectron spectroscopy and redox processes of a chemisorbed probe molecule: effect of surface pretreatment conditions [J]. Langmuir, 2002, 18: 450 | | [23] | Huet B, Raskin J P. Role of Cu foil in-situ annealing in controlling the size and thickness of CVD graphene domains [J]. Carbon, 2018, 129: 270 | | [24] | Bessho T, Yoneda E, Yum J H, et al. New paradigm in molecular engineering of sensitizers for solar cell applications [J]. J. Am. Chem. Soc., 2009, 131: 5930 | | [25] | Wei C, Wei H B, Yan W B, et al. Water-soluble and highly luminescent europium (III) complexes with favorable photostability and sensitive pH response behavior [J]. Inorg. Chem., 2016, 55: 10645 | | [26] | Penfold N J W, Parnell A J, Molina M, et al. Layer-by-layer self-assembly of polyelectrolytic block copolymer worms on a planar substrate [J]. Langmuir, 2017, 33: 14425 |
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