Study on Pyrolysis Kinetics of Typical Carbon Fiber Bidirectional Sheet

doi:10.11901/1005.3093.2016.158

Chinese Journal of Materials Research

2017, Vol. 31

Issue (1): 57-64 DOI: 10.11901/1005.3093.2016.158

Orginal Article

Current Issue | Archive | Adv Search

Study on Pyrolysis Kinetics of Typical Carbon Fiber Bidirectional Sheet

Yanying XU^1,²,Ying ZHANG^1,²,Zhi WANG^1,²(

),Jian CHEN^1,²

1 Liaoning Key Laboratory of General aviation, Shenyang Aerospace University, Shenyang 110136, China
2 Liaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology, Shenyang Aerospace University, Shenyang 110136, China

Cite this article:

Yanying XU,Ying ZHANG,Zhi WANG,Jian CHEN. Study on Pyrolysis Kinetics of Typical Carbon Fiber Bidirectional Sheet. Chinese Journal of Materials Research, 2017, 31(1): 57-64.

Download:

HTML

PDF(959KB)
Export: BibTeX | EndNote (RIS)

Abstract

The influence of heating rate on the pyrolysis characteristics of a carbon fiber bidirectional sheet (T300-3000) in air stream was investigated by means of DTG-60(AH) TG/DTA simultaneous thermal analyzer. The results show that the thermal degradation behavior of the sheet was affected greatly by heating rate. The temperature related with the maximum mass loss rate shifted towards high temperature,and the distance between the two peaks of DTG curves was gradually larger and the peak areas increased with the increasing heating rate. The pyrolysis process of the carbon fiber bidirectional sheet can be divided into three stages including two decomposition stages of epoxy resin and one of the carbon fiber decomposition. The pyrolysis kinetics curves of the carbon fiber bidirectional sheet were analyzed by Kissinger method and Flynn-Wall-Ozawa method,and the acquired apparent activation energy and the apparent pre-exponential factor for different heating rates were of good accordance with each other. The thermostability of the carbon fiber bidirectional sheet with epoxy resin is relatively strong and controllable within a certain range of mass loss.

Key words: composites carbon fiber bidirectional sheet pyrolysis kinetics apparent activation energy thermal stability

Received: 25 March 2016

Fund: Supported by Science Public Welfare Research Fund of Liaoning (No.GY2014-C-005) and Natural Science Foundation of Liaoning Province (No.201602567)

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Yanying XU
	Ying ZHANG
	Zhi WANG
	Jian CHEN

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2016.158 OR https://www.cjmr.org/EN/Y2017/V31/I1/57

Fig.1 TG curves of epoxy resin in different heating rates

Fig.2 DTG curves of epoxy resin in different heating rates

Table 1 Pyrolysis parameters of the epoxy resin

Fig.3 TG curves of carbon fiber bidirectional sheet powder in different heating rates

Fig.4 DTG curves of carbon fiber bidirectional sheet powder in different heating rates

Table 2 Pyrolysis parameters of the carbon fiber bidirectional sheet powder

Fig.5 TG curves of carbon fiber bidirectional sheet blocks in different heating rates

Fig.6 DTG curves of carbon fiber bidirectional sheet blocks in different heating rates

Table 3 Pyrolysis parameters of the carbon fiber bidirectional sheet blocks

Fig.7 Relation curves of lnβiTpi2 versus 1Tpiin epoxy resin thermal degradation process

Fig.8 Relation curves of lnβiTpi2 versus 1Tpiin carbon fiber bidirectional sheet powder thermal degradation process

Fig.9 Relation curves of lnβiTpi2 versus 1Tpiin carbon fiber bidirectional sheet blocks thermal degradation process

Fig.10 Relation curves of lgβ versus 1T in epoxy resin thermal degradation process

Fig.11 Relation curves of lgβ versus 1T in carbon fiber bidirectional sheet powder thermal degradation process

Fig.12 Relation curves of lgβ versus 1T in carbon fiber bidirectional sheet blocks thermal degradation process

Table 4 Pyrolysis kinetic parameters of the three materials with Kissinger method

Table 5 Apparent activation energy of the three materials with Flynn-Wall-Ozawa method

[1]	Li J L, Zhao F, Zhang Y, et al.Application of carbon fiber and its composites in military industry[J]. Synth. Fiber China, 2014, 43(3): 33
[1]	(李建利, 赵帆, 张元等. 碳纤维及其复合材料在军工领域的应用[J]. 合成纤维, 2014, 43(3): 33)
[2]	Chen K S, Yeh R Z.Pyrolysis kinetics of epoxy resin in a nitrogen atmosphere[J]. J. Hazard. Mater., 1996, 49: 105
[3]	Wu L Y.The application extend of advanced composite materials: technology markets of ACM application in aeronautics, astronautics and civil aviation[J]. New Chem. Mater., 2012, 40(1): 4
[3]	(吴良义. 先进复合材料的应用扩展: 航空、航天和民用航空先进复合材料应用技术和市场预测[J]. 化工新型材料, 2012, 40(1): 4)
[4]	Eibl S.Influence of carbon fibre orientation on reaction-to-fire properties of polymer matrix composites[J]. Fire Mater., 2012, 36: 309
[5]	Szolnoki B, Bocz K, Sóti P L, et al.Development of natural fibre reinforced flame retarded epoxy resin composites[J]. Polym. Degrad. Stabil., 2015, 119: 68
[6]	Régnier N, Fontaine S.Determination of the thermal degradation kinetic parameters of carbon fibre reinforced epoxy using TG[J]. J. Therm. Anal. Calorim., 2001, 64: 789
[7]	Quang Dao D, Luche J, Richard F, et al.Determination of characteristic parameters for the thermal decomposition of epoxy resin/carbon fibre composites in cone calorimeter[J]. Int. J. Hydrogen Energy, 2013, 38: 8167
[8]	Yu Q, Chen P, Lu C.Numerical simulation of thermal stress distribution in CF/BMI composite subjected to thermal cycles[J]. Chinese J. Mater. Res., 2012, 26: 583
[8]	(于祺, 陈平, 陆春. 碳纤维/双马树脂基复合材料在热循环过程中热应力分布的数值模拟[J]. 材料研究学报, 2012, 26: 583)
[9]	Chen B, Wan H, Mu J Y, et al.Ablative mechanism of carbon-fiber/epoxy composite irradiated by repetition frequency laser[J]. High Power Laser and Particle Beams, 2008, 20: 547
[9]	(陈博, 万红, 穆景阳等. 重频激光作用下碳纤维/环氧树脂复合材料热损伤规律[J]. 强激光与粒子束, 2008, 20: 547)
[10]	Huang C, Yang H T, Li X Y, et al.Research and development of Kissinger equation[J]. Chinese J. Explos. Propel., 2014, 37: 26
[10]	(黄川, 杨洪涛, 李翔宇等. 基辛格方程的研究与发展[J]. 火炸药学报, 2014, 37: 26)
[11]	Hu R Z, Gao S L, Zhao F Q, et al.Thermal Analysis Kinetics [M]. 2nd Ed. Beijing: Science Press, 2008
[11]	(胡荣祖, 高胜利, 赵凤起等. 热分析动力学 [M]. 第二版. 北京: 科学出版社, 2008)
[12]	Chen Z Q, Liu H B, He Y D, et al.Thermal characteristics of high char yield phenolic resin[J]. Eng. Plast. Appl., 2006, 34(11): 56
[12]	(陈智琴, 刘洪波, 何月德等. 高残炭率酚醛树脂的耐热性能研究[J]. 工程塑料应用, 2006, 34(11): 56)
[13]	He H Z, Luo Z Y, Cen K F.Study on dynamic reaction parameters of anthracite combustion by using different thermoanalytical methods[J]. Power Eng., 2005, 25: 493
[13]	(何宏舟, 骆仲泱, 岑可法. 不同热分析方法求解无烟煤燃烧反应动力学参数的研究[J]. 动力工程, 2005, 25: 493)
[14]	Ren N, Zhang J J.Progress in datum treatment methods of thermal analysis kinetics[J]. Progr. Chem., 2006, 18: 410
[14]	(任宁, 张建军. 热分析动力学数据处理方法的研究进展[J]. 化学进展, 2006, 18: 410)

[1]	JI Yuchen, LIU Shuhe, ZHANG Tianyu, ZHA Cheng. Research Progress of MXene Used in Lithium Sulfur Battery[J]. 材料研究学报, 2023, 37(7): 481-494.
[2]	ZHANG Tengxin, WANG Han, HAO Yabin, ZHANG Jiangang, SUN Xinyang, ZENG You. Damping Enhancement of Graphene/Polymer Composites Based on Interfacial Interactions of Hydrogen Bonds[J]. 材料研究学报, 2023, 37(6): 401-407.
[3]	SHAO Mengmeng, CHEN Zhaoke, XIONG Xiang, ZENG Yi, WANG Duo, WANG Xuhui. Effect of Si²⁺ Ion Beam Irradiation on Performance of C/C-ZrC-SiC Composites[J]. 材料研究学报, 2023, 37(6): 472-480.
[4]	JIANG Shuimiao, MING Kaisheng, ZHENG Shijian. A Review on Grain Boundary Segregation, Interfacial Phase and Mechanical Property Adjusting-controlling for Nanocrystalline Materials[J]. 材料研究学报, 2023, 37(5): 321-331.
[5]	LIN Shifeng, XU Dongan, ZHUANG Yanxin, ZHANG Haifeng, ZHU Zhengwang. Preparation and Mechanical Properties of TiZr-based Bulk Metallic Glass/TC21 Titanium Alloy Dual-layered Composites[J]. 材料研究学报, 2023, 37(3): 193-202.
[6]	MIAO Qi, ZUO Xiaoqing, ZHOU Yun, WANG Yingwu, GUO Lu, WANG Tan, HUANG Bei. Pore Structure, Mechanical and Sound Absorption Performance for Composite Foam of 304 Stainless Steel Fiber/ZL104 Aluminum Alloy[J]. 材料研究学报, 2023, 37(3): 175-183.
[7]	XIE Donghang, PAN Ran, ZHU Shize, WANG Dong, LIU Zhenyu, ZAN Yuning, XIAO Bolv, MA Zongyi. Effect of Reinforced Particle Size on the Microstructure and Tensile Properties of B₄C/Al-Zn-Mg-Cu Composites[J]. 材料研究学报, 2023, 37(10): 731-738.
[8]	WANG Yankun, WANG Yu, JI Wei, WANG Zhihui, PENG Xiangfei, HU Yuxiong, LIU Bin, XU Hong, BAI Peikang. Microstructure and Mechanical Properties of Carbon Fiber/Aluminum Laminated Composites[J]. 材料研究学报, 2022, 36(7): 536-544.
[9]	ZONG Ping, LI Shiwei, CHEN Hong, MIAO Sainan, ZHANG Hui, LI Chao. In-situ Thermolysis Preparation of Carbon Capsulated Nano-copper and Its Stability[J]. 材料研究学报, 2022, 36(11): 829-836.
[10]	ZONG Yixun, LI Shufeng, LIU Lei, ZHANG Xin, PAN Deng, WU Daihuiyu. Interface Regulation and Strengthening Mechanism of GNP-Ni/Cu Composites[J]. 材料研究学报, 2022, 36(10): 777-785.
[11]	HOU Jing, YANG Peizhi, ZHENG Qinhong, YANG Wen, ZHOU Qihang, LI Xueming. Preparation and Performance of Graphite/TiO₂ Composite Photocatalyst[J]. 材料研究学报, 2021, 35(9): 703-711.
[12]	YANG Yana, CHEN Wenge, XUE Yuanlin. Interficial Bonding within Cu-based Composites Reinforced with TiC- or Ni-coated Carbon Fiber[J]. 材料研究学报, 2021, 35(6): 467-473.
[13]	LI Wanxi, DU Yi'en, GUO Fang, CHEN Yongqiang. Preparation and Electromagnetic Properties of CoFe₂O₄-Co₃Fe₇ Nanoparticles and CoFe₂O₄/Porous Carbon[J]. 材料研究学报, 2021, 35(4): 302-312.
[14]	HU Manying, OUYANG Delai, CUI Xia, DU Haiming, XU Yong. Properties of TiC Reinforced Ti-Composites Synthesized in Situ by Microwave Sintering[J]. 材料研究学报, 2021, 35(4): 277-283.
[15]	SONG Yuehong, DAI Weili, XU Hui, ZHAO Jingzhe. Preparation and Photocatalytic Properties of g-C₃N₄/Bi₁₂O₁₇Cl₂ Composites[J]. 材料研究学报, 2021, 35(12): 911-917.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed