Preparation and Capacitance Properties of Polyaniline/Carbon Microcoil Composites

doi:10.11901/1005.3093.2015.361

Chinese Journal of Materials Research

2016, Vol. 30

Issue (3): 186-191 DOI: 10.11901/1005.3093.2015.361

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Preparation and Capacitance Properties of Polyaniline/Carbon Microcoil Composites

ZHU Shize, TANG Guoxia, WANG Jian, LU Juan, ZHU Yabo^**(

)

(School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, China)

Cite this article:

ZHU Shize, TANG Guoxia, WANG Jian, LU Juan, ZHU Yabo. Preparation and Capacitance Properties of Polyaniline/Carbon Microcoil Composites. Chinese Journal of Materials Research, 2016, 30(3): 186-191.

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Abstract

Composites of polyaniline/carbon microcoils (PANI/CMCs) were prepared by microemulsion-polymerization method. The observation by scanning electron microscopy (SEM) showed that the surface of the CMCs became rough due to the coverage of PANI on the surface after the synthesis process. The infrared spectroscopy measurement proved the presence of chemical bonding between PANI and CMCs. When the volume ratio of chloroform, as co-emulsifier, to the total reaction matters was 1: 24, the maximum amount of PANI coverage can be acquired, which well grafted on the surface of CMCs. Results of constant current charge-discharge and cyclic voltammetry tests show that in comparison with the single PANI or CMCs, the composites possess superior capacitive performance with a specific capacitance 134.8 F·g^-1 and an excellent cycling stability with a remaining capacitance 63.3% after 750 cycles.

Key words: composites carbon microcoil polyaniline microemulsion polymerization capacitive properties

Received: 29 June 2015

ZTFLH:

TB332

Fund: *Supported by Students Innovation-University-Level Key Program No. XZD1029014188.

About author: **To whom correspondence should be addressed, Tel: 13952267189, E-mail: zhuyabo@163.com

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	Shize ZHU
	Guoxia TANG
	Jian WANG
	Juan LU
	Yabo ZHU

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.361 OR https://www.cjmr.org/EN/Y2016/V30/I3/186

Fig.1 SEM images of H-CMCs (a), PANI (b), PANI/H-CMCs-1 (c), PANI/H-CMCs-2 (d) and PANI/H-CMCs-3 (e)

Fig.2 FT-IR spectra of H-CMCs (a), PANI (b) and PANI/H-CMCs-2(c)

Fig.3 FT-IR spectra of PANI/H-CMCs-1 (a) and PANI/H-CMCs-3 (b)

Fig.4 Schematic of microemulsion synthetic PANI/H-CMCs composite

Fig.5 Charge-discharge curves of H-CMCs (a), PANI (b) and PANI/H-CMCs-2 (c) at 500 mAg^-1

Fig.6 CV curves of PANI (a) and PANI/H-CMCs-2 (b)

Fig.7 Variation of specific capacitance of PANI/H-CMCs-2 and PANI with cycle numbers at a current density of 1 Ag^-1

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