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Chinese Journal of Materials Research  2015, Vol. 29 Issue (9): 693-700    DOI: 10.11901/1005.3093.2014.541
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Analyses on Connection Characteristics of Composites of Steel-Copper
Lintao CHEN Wenge HOU(),Yingbin LIU,Qiwen LUO
School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048 China
Cite this article: 

Lintao CHEN Wenge HOU,Yingbin LIU,Qiwen LUO. Analyses on Connection Characteristics of Composites of Steel-Copper. Chinese Journal of Materials Research, 2015, 29(9): 693-700.

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Abstract  

Composites 45 steel/T2 copper and 304 Stainless steel/T2 copper were prepared by high-temperature vacuum casting. The interface bonding strength, microstructure, microhardness and composition change of the phase boundary zone of the composites were investigated by SEM observation, EDS analysis, XRD and mechanical property test. The results show that interdiffusion occurred of alloy elements Fe, Cr and Cu of the two substrates resulting in formation of phases such as a new iron carbon compounds (CFe15.1) and solid solution Cu0.81 Ni0.19, and Cr-Ni-Fe-C, there existed a dentate interdiffusion layer of about 60 to 70 microns without obvious intermetallics in the transition zone and its microhardness is about 183 and 119HV for 45-T2 and 304-T2 respectively; tensile/shear strength of the composite are 278/263MPa and 217/201 MPa respectively for 45/T2 and 304/T2; break occurs in the copper side with typical ductile fracture characteristics. Cu element plays an important role in improvement of the stability and strength of the substrates 304 stainless steel and 45steel.

Key words:  composites      45 steel      304 Stainless      T2 copper      vacuum casting      interface analysis     
Received:  26 September 2014     
Fund: *Supported by Xi'an Science and Technology Project No. CXY1342(2).

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2014.541     OR     https://www.cjmr.org/EN/Y2015/V29/I9/693

Material Cu Zn Pb Mn Cr Fe Si C Ni Sb
T2 copper 99.9 0.005 0.005 - - 0.005 - - - 0.002
45steel <0.25 - - 0.5-0.8 <0.25 bal. <0.37 0.42-0.45 ≤0.3 -
304 - - - ≤2.0 18-20 - ≤1.0 ≤0.07 - -
Table 1  Chemical composition of 45 steel、T2、304 (%, mass fraction )
Fig.1  Sample of tensile testing (a) and casting (b)
Fig.2  Microstructure of 45 steel and T2 copper composites before and after corrosion
Fig.3  Microstructure of 304-T2 composites before and after corrosion
Fig.4  Interface microstructure of 304-T2/45钢-T2 (a, b) and line spectrum diagram of interface elements (c, d)
Fig.5  XRD pattern of fracture between 45-T2 (a) and 304-T2 composites (b)
Fig.6  stress-strain curve of Steel and copper in under the tensile (a) and the shear (b) stress-strain
Fig.7  Microhardness of 45-T2/304-T2 composites
Fig.8  Distribution curve of steel copper composites interface microhardness
Fig.9  Shear fracture SEM morphology of 45 steel-T2 copper (a, b) and 304 Stainless-T2 copper (c, d)
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