Interface Remelting of Tungsten Carbide Particles Reinforced Steel Composite

doi:10.11901/1005.3093.2013.790

Chinese Journal of Materials Research

2014, Vol. 28

Issue (3): 191-196 DOI: 10.11901/1005.3093.2013.790

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Interface Remelting of Tungsten Carbide Particles Reinforced Steel Composite

Haoke HUANG,Zulai LI(

),Quan SHAN,Yehua JIANG,Zhandong HOU

School of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093

Cite this article:

Haoke HUANG,Zulai LI,Quan SHAN,Yehua JIANG,Zhandong HOU. Interface Remelting of Tungsten Carbide Particles Reinforced Steel Composite. Chinese Journal of Materials Research, 2014, 28(3): 191-196.

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Abstract

A tungsten carbide particles reinforced steel matrix composite was fabricated by spark plasma sintering (SPS) technique, and then the composite was remelted in a vacuum tube furnace. The effect of remelting temperature on interface reaction was investigated meticulously. The results show that the interface reaction could occur when the matrix was still in solid state, the thickness of interface reaction layer increased with the increasing temperature. The interface reaction product, Fe₃W₃C, was resulted from the following two step reactions: firstly the reaction 2WC→W2C+C would occur within tungsten carbide particles at 1314℃, then the W₂C would react with Fe to produce Fe₃W₃C at temperatures above 1341℃.

Key words: composites interface reaction SPS Fe₃W₃C remelting

Received: 20 October 2013

Fund: *Supported by National Natural Science Foundation of China Nos. 51241002 & 51361019.

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	Haoke HUANG
	Zulai LI
	Quan SHAN
	Yehua JIANG
	Zhandong HOU

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https://www.cjmr.org/EN/10.11901/1005.3093.2013.790 OR https://www.cjmr.org/EN/Y2014/V28/I3/191

Table1 Nominal chemical composition of the powders

Table2 Parameters of the spark plasma sintering (SPS)

Fig.1 Temperature variation curves of tube furnace

Fig.2 XRD spectrum of test samples under different temperatures

Fig.3 Microstructures of test samples under different temperatures, (a) unheated, (b) 1340℃, (c) 1360℃, (d) 1380℃

Fig.4 SEM of test samples under different temperatures, (a) unheated, (b) 1340℃, (c) 1380℃

Table3 EDS microanalysis in the composite

Fig.5 XRD spectrum of test samples processed by cast-infiltration

Fig.6 SEM of test samples by cast-infiltration

Table 4 EDS microanalysis in the composite

Fig.7 T DSC curves of ferrous powder (a), tungsten carbide powder (b) and mixture powder (c)

Fig.8 Change of ΔG of possible reaction with temperature in tungsten carbide

1	ZHAO Minhai,LIU Aiguo, GUO Mianhuan, Research on WC reinforced metal matrix composite, Welding & Joining, (11), 26(2006)
1	(赵敏海, 刘爱国, 郭面焕, WC颗粒增强耐磨材料的研究现状, 焊接, (11), 26(2006))
2	TIAN Zhiyu,Research and application of particle reinforced metal matrix composite material, Metal Materials And Metallurgy Engineering, 136(1), 3(2008)
2	(田治宇, 颗粒增强金属基复合材料的研究及应用, 金属材料与冶金工程, 36(1), 3(2008))
3	Izabel Fernanda Machado,Luca Girardini, Ivan Lonardelli, Alberto Molinari, The study of ternary carbides formation during SPS consolidation process in the WC–Co–steel system, Int. Journal of Refractory Metals & Hard Materials, 27, 883(2009)
4	Tokita M. Development of square-shaped large size WC/Co/Ni system FGM fabricated by spark plasma sintering (SPS)-method its industrial applications, Mater Sci Forum, 711(8), 492(2005)
5	Zhuhui Qiao, Xianfeng Ma, Wei Zhao, Huaguo Tang, Microstructure, thermal stability and mechanical properties of the novel (W1xAlx)C–Co (x = 0.2, 0.33, 0.4, 0.5) cemented carbide. Int J Refract Met Hard Mater, 27, 48(2009)
6	D Lou,J Hellman, D Luhulima, J Liimatainen, V. K Lindroos. Interactions between tungsten carbide (WC) particulates and metal matrix in WC-reinforced composites, Mater Science Engineering, A340, 155(2003)
7	Fan Tongxiang, Shi Zhongliang, Zhang Di, The interfacial reaction characteristic in SiC/Al composite above liquidus during remelting. Materials Science and Engineering A, 2557, 281(1998)
8	OUYANG Liuzhang,LUO Chengping, LUO Zhuoxuan, SUI Xiandong, Study on Interface Characteristics of SiCp/ZL109 Aluminium Alloy Composites, Foundry, 3, 9(1999)
8	(欧阳柳章, 罗承萍, 骆灼旋, 隋贤栋, SiCp/ZL109复合材料界面研究, 铸造, 3, 9(1999))
9	LIU Zheng,LIU Xiaomei, Effects of interface on wear resistance of fiber reinforced aluminum-silicon alloy composites, Mining and Metallurgical Engineering, 23(3), 65(2003)
9	(刘政, 刘小梅, 界面对纤维增强铝硅合金复合材料耐磨性的影响, 矿业工程, 23(3), 65(2003))
10	LIU Zheng,ZHOU Bide, PENG Delin, AN Geying, A study of the interface of short alumina fiber reinforced aluminium alloy composites, Acta Materiae Compositae Sinica, 8(4), 1(1991)
10	(刘政, 周彼德, 彭德林, 安阁英, 氧化铝短纤维增强铝合金复合材料界面的研究, 复合材料学报, 8(4), 1(1991))
11	LIU Junyou,LIU Yingcai, LIU Guoquan, YIN Yansheng, SHI Zhongliang, Oxidation behavior of silicon carbide particales and their interfacial characterization in aluminum matrix composites, The Chinese Journal of Nonferrous Metals, 12(5), 961(2002)
11	(刘俊友, 刘英才, 刘国权, 尹衍升, 施忠良, SiC颗粒氧化行为及SiCp/铝基复合材料界面特征, 中国有色金属学报, 12(5), 961(2002))
12	LIU Junyou,SHI Zhongliang2, LIU Guoquan, GU Mingyuan, Lee Jae chul, Interfacial characteristics of aluminum matrix composites with oxidized SiCp articles as reinforcement, Journal of Chinese Electron Microscopy Society, 20(3), 206(2001)
12	(刘俊友, 施忠良, 刘国权, 顾明元, Lee Jae chul. 氧化的碳化硅颗粒增强铝-镁基复合材料的界面微结构特征. 电子显微学报, 20(3), 206(2001))
13	Arsenauil R.J,Shi N, Dislocation generation due to difference between the coefficient of thermal expansion, Materials Science and Engineering, 81, 175(1986)
14	Arsenauil R. J,Wang L, Strengthening of composites due to microstructural changes in the matrix, Acta Metall Mater, 39(1), 47(1991)
15	WEI Yonghui,SONG Yanpei, Wear resistance of in-situ synthesized Fe matrix composites, Special Casting & Nonferrous Alloys, 27(3), 229(2007)
15	(魏永辉, 宋延沛, 原位自生钢基复合材料耐磨性能的研究. 特种铸造及有色合金, 27(3), 229(2007))
16	ZENG Shaolian,LI Wei, WC Particle reinforced steel/iron matrix wear resistant composites, Special Casting & Nonferrous Alloys, 27(6), 441(2007)
16	(曾绍连, 李卫, 碳化钨增强钢铁基耐磨复合材料的研究和应用. 特种铸造及有色合金, 27(6), 441(2007))
17	SONG Yanpei,LI Bingzhe, WANG Wenzhang, XIE Jingpei, ZHU Jingzhi, Investigation of WCp/Fe composite roller ring, Chinese Journal of Mechanical Engineering, 37(1), 99(2001)
17	(宋延沛, 李秉哲, 王文众, 谢敬佩, 朱景芝, WC颗粒增强铁基复合材料辊环的研究, 机械工程学报, 37(1), 99(2001))
18	LIANG Yingjiao, CHE Yinchang, Handbook of Thermodynamic Data for Inorganic Material, ShenYang, Northeastern University Press, 1993
18	(梁英教,车荫昌,无机物热力学数据手册, 沈阳, 东北大学出版社, 1993)
19	D. V. Suetin, I. R. Shein, A. L. Ivanovskii,Structural, electronic and magnetic properties of η carbides (Fe3W3C, Fe6W6C, Co3W3C and Co6W6C) from first principles calculations, Physica B, 404, 3544(2009)

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