Interface Order-microstructure of Nano Pd–Ga Alloy/PMMA Composites

Chin J Mater Res

2011, Vol. 25

Issue (3): 303-307 DOI:

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Interface Order-microstructure of Nano Pd–Ga Alloy/PMMA Composites

XU Guocai, DAI Minghu, ZHANG Xiaomei, GAO Shengtao, XING Honglong

School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001

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XU Guocai DAI Minghu ZHANG Xiaomei GAO Shengtao XING Honglong. Interface Order-microstructure of Nano Pd–Ga Alloy/PMMA Composites. Chin J Mater Res, 2011, 25(3): 303-307.

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Abstract Nano Ga–Pd/poly methyl methacrylate (PMMA) composite materials were prepared with the palladium chloride solution containing metal galliumMMA as monomer without initiator or reducer. Results show that there are Pd, Ga, and Ga5Pd phase in PMMA matrix. There was a characteristic absorption peak at 200 nm for nano–Ga/PMMA polymer solution, at 209 nm for nano–Pd/PMMA polymer solution, and the absorption peak of nano Pd–Ga/PMMA shiftted to long wavelength at 218 nm; Nano Ga5Pd formed based on segment electronics shifting from gallium to palladium, and coordination formed found on part electronics diverted from gallium to oxygen of PMMA ester group. PMMA possess anisotropic ordered microstructure around nano Ga-Pd particles, illustrating that there are interaction between nano
Ga–Pd particles as dispersive and PMMA as continuous phase.

Key words: composites nano Pd–Ga PMMA ultrasonic interface structure nanocomposite

Received: 28 February 2011

ZTFLH:	O614
	TB333

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Supported by Natural Science Foundation of Anhui Province No.090414183.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2011/V25/I3/303

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