Construction and Anti-corrosion Performance of a Self-healing Coating on Ni-Co Plating/Q235 Carbon Steel

doi:10.11901/1005.3093.2020.134

Chinese Journal of Materials Research

2020, Vol. 34

Issue (10): 777-783 DOI: 10.11901/1005.3093.2020.134

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Construction and Anti-corrosion Performance of a Self-healing Coating on Ni-Co Plating/Q235 Carbon Steel

DUAN Tigang¹(

), HUANG Guosheng¹, MA Li¹, PENG Wenshan¹, ZHANG Wei², XU Likun¹, LIN Zhifeng¹, HE Hua³, BI Tieman³

1. State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266237, China
2. Center of Public Employment and Talent Service of Yantai, Yantai 264003, China
3. Dalian Shipbuilding Industry Co. , LTD, Dalian 116001, China

Cite this article:

DUAN Tigang, HUANG Guosheng, MA Li, PENG Wenshan, ZHANG Wei, XU Likun, LIN Zhifeng, HE Hua, BI Tieman. Construction and Anti-corrosion Performance of a Self-healing Coating on Ni-Co Plating/Q235 Carbon Steel. Chinese Journal of Materials Research, 2020, 34(10): 777-783.

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Abstract

Combining the advantages of organic coating with self-healing ability and alloy plating, a composite coating Cap(T+Y)/ Ni-Co was prepared on the Q235 substrate in order to improve the anti-corrosion ability and extend the service time of the coated steel. At first the Ni-Co alloy plating was electro-deposited on Q235 carbon steel, and subsequently, the two-component microcapsules containing organic coating was applied on the Ni-Co/Q235 to acquire a composite coating. Results of SEM observation and thermogravimetry analysis show that the diameter of microcapsules is about 3 μm with a coverage up to 49%. Besides, results of neutral salt spray tests and localized electrochemical tests show that the composite coating presents a well integrality after undergoing 380 h salt spray test. The anticorrosive composite coating has satisfactory self-healing activity and long-term protectiveness on the Q235 metal matrixes.

Key words: material failure and protection self-healing coating microcapsule Ni-Co alloy plating

Received: 23 April 2020

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	Articles by authors
	Tigang DUAN
	Guosheng HUANG
	Li MA
	Wenshan PENG
	Wei ZHANG
	Likun XU
	Zhifeng LIN
	Hua HE
	Tieman BI

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.134 OR https://www.cjmr.org/EN/Y2020/V34/I10/777

Fig.1 SEM image of Cap (T + Y)

Fig.2 Thermogravimetric curves in nitrogen atmosphere (a) weight loss and temperature curves; (b) DTG curves of UF、T、Y、Cap (T) and Cap (T+Y)

Fig.3 Images of Ni-Co alloy coating (a), scratched N-C-SR (b) and complete N-C-SR under neutral salt spray (c)

Fig.4 Result of N-C-SR self-repairing process under micro-electrochemical test

Fig.5 Self-repairing mechanism model of N-C-SR

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