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材料研究学报  2008, Vol. 22 Issue (6): 619-622    
  研究论文 本期目录 | 过刊浏览 |
各向异性Nd2Fe14B/α--Fe纳米晶复合磁体的制备和性能
牛培利;张久兴;岳明;李永利
北京工业大学新型功能材料教育部重点实验室 北京 100022
Preparation and properties of anisotropic Nd2Fe14B/α--Fe nanocomposite magnets
 NIU Peili; ZHANG Jiuxin; YUE Meng; LI Yongli
The Key Laboratory of Advanced Functional Materials; Ministry of Education;
Beijing University of Technology; Beijing 100022
引用本文:

牛培利 张久兴 岳明 李永利. 各向异性Nd2Fe14B/α--Fe纳米晶复合磁体的制备和性能[J]. 材料研究学报, 2008, 22(6): 619-622.
, , , . Preparation and properties of anisotropic Nd2Fe14B/α--Fe nanocomposite magnets[J]. Chin J Mater Res, 2008, 22(6): 619-622.

全文: PDF(821 KB)  
摘要: 

采用声化学法、放电等离子烧结技术(SPS)和热变形工艺制备致密各向同性和各向异性 Nd2Fe14B/α--Fe复合磁体, 研究了软磁相包覆对磁体的结构和性能的影响.结果表明,  软磁相α--Fe对各向同性Nd2Fe14B/α--Fe复合磁体的影响主要表现为增强两相间的交换耦合作用, 从而提高剩磁.当α--Fe体积分数的数值适当(不超过2%)时,各向异性 Nd2Fe14B/α--Fe磁体形成较好的$c$轴晶体织构,具有较高的磁性能. α--Fe体积分数为 1%的磁体性能最高:Br=1.367 T, Hci=712 kA/m, (BH)m=327 kJ/m3.

关键词 金属材料, Nd2Fe14B/α--Fe纳米晶复合磁体 声化学和放电等离子烧结 各向异性    
Abstract

Full dense isotropic and anisotropic Nd2Fe14B/α--Fe nanocomposite magnets were prepared via sonochemistry method, spark plasma sintering (SPS) and hot deformation method. The effects of α–Fe volume fraction on the structure and magnetic properties of the magnets were investigated. For the isotropic magnets, the exchanging coupling and remanence increase as the α–Fe content increases. For the anisotropic magnets, only the magnets with no more than 2% α–Fe exhibit strong c-axis crystal texture of Nd2Fe14B phase, and the better magnetic properties are Br=1.367 T, Hci=712 kA/m, (BH)m=327 kJ/m3.

Key wordsmetallic materials    nanocomposite magnets Nd2Fe14B/α--Fe    sonochemistry and spark plasma sintering    anisotropy
收稿日期: 2007-09-25     
ZTFLH: 

TM271

 
基金资助:

国家自然科学基金(50201001);北京市自然科学基金(2041001)

1 R.Coehoom, D.B.de Mooij, C.deWaard, Meltspun permanent magnet materials containing Fe3B as the main phase, J. Magn. Magn. Mater., 80, 101(1989)
2 DONG Shengzhi, LI Youmei, LI Wei, Structural and magnetic properties of nanocomposite alloy Nd4.5Fe76.3Ga0.2Co1.1B18, Acta Physica Sinica, 48, S62(1999)
(董生智, 李岫梅, 李卫, 复相合金的结构与磁性, 物理学报,48, S62(1999))
3 C.Wang, M.Yan, W.Y.Zhang, Effects of Nb and Zr additions on crystallization behavior microstructure and magnetic properties of melt-spun (Nd, Pr)
2Fe14B/α-Fe alloys, J. Magn. Magn. Mater, 306, 195(2006)
4 Z.Q.Jin, B.Z.Cui, J.P.Liu, Y.Ding, Z.L.Wang, N.N.Thadhani, Controlling the crystallization and magnetic properties of melt-spun Pr2Fe14B/α-Fe nanocomposites by Joule heating, Appl. Phys. Lette, 84(22), 4382(2004)
5 T.Saito, Production of bulk materials of an Nd4Fe77.5B18.5 alloy and their magnetic properties, IEEE Trans. on Magn., 37, 2561(2001)
6 Q.Zeng, Y.Zhang, M.J.Bonder, Bulk SmCo5/α–Fe composite by Plasma Pressure Consolidation, IEEE Trans on Magn., 39, 2974(2003)
7 Piotr Pawlik, Hywel A.Davies, Waldemar Kaszuwara. PrFeCoB-based magnets derived from bulk alloy glass, J Magn Magn Mater., 290, 1243(2005)
8 D.Lee, J.S.Hilton, S.Liu, Hot-pressed and hot deformed nanocomposite (Nd,Pr,Dy) 2Fe14B/α–Fe based magnets, IEEE Trans. on Magn., 39, 2947(2003)
9 D.Lee, J.S.Hilton, C.H.Chen, Bulk isotropic and anisotropic nanocomposite rare-earth magnets, IEEE Trans. on Magn., 40, 2904(2004)
10 D.Lee, S.Bauser, A.Higgins, C.Chen S.Liu, Y.G.Peng, D.E.Laughlin, Bulk anisotropic composite rare earth magnets, J. Appl. Phys., 99(8), 08b516(2006)
11 LI Yongli, LI Baowei, YUE Ming, ZHANG Jiuxing, Prepareation and properties of Nd-Fe-B/Fe nanocomposite magnets, J. Iron Steel Research, 13, 187(2006)
12 LI Baowei, LI Yongli, YUE Ming, ZHANG Jiuxing, Preparation and properties of Nd2Fe14B/α–Fe nanocomposite permanent magnets, Chinese Journal of Materials Research, 21(3), 319(2007)
(李保卫, 李永利, 岳\ \明, 张久兴, Nd2Fe14B/α--Fe纳米复合永磁的制备和性能, 材料研究学报, 21(3), 319(2007))
13 M.Tokita, Trends in advanced SPS spark plasma sintering system and technology, J. Soc. Powd. Tech., 30, 790(1993)
14 Yue Ming, Niu Peili, Zhang Jiuxing, Zhang Dongtao, Spark plasma sintering Fe3B-(Pr,Tb) 2Fe14B bulk nanocomposite permanent magnets, IEEE Trans. on Magn., 42, 2894(2006)
15 Yue Ming, Tian Meng, Zhang Jiuxing, Zhang Dongtao, Niu Peili, Yang Fang, Microstructure and mangetic properties of anisotropic Nd-Fe-B magnets produced by spark plasma sintering technique, Mater. Sci. Eng., 131, 18(2006)
16 Niu Peili, Yue Ming, Zhang Jiuxing, Zhang Dongtao, Effect of heat treatment on magnetic properties and microstructure of bulk Fe3B/Nd2Fe14B nanocomposite permanent magnets, Powder Metal., 50(3), 219(2007)

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