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材料研究学报  2026, Vol. 40 Issue (7): 553-560    DOI: 10.11901/1005.3093.2025.316
  研究论文 本期目录 | 过刊浏览 |
W/TiZrVAl高熵合金复合材料制备和性能
王雨晴1, 王金贺2, 李可馨2, 付华萌2(), 张海峰3
1.沈阳理工大学材料科学与工程学院 沈阳 110159
2.中国科学院金属研究所 沈阳 110016
3.东北大学冶金学院 沈阳 110819
Microstructure and Mechanical Properties for Composites of W/TiZrVAl High-entropy Alloy Sintered by Hot Isostatic Pressing
WANG Yuqing1, WANG Jinhe2, LI Kexin2, FU Huameng2(), ZHANG Haifeng3
1.School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China
2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.School of Metallurgy, Northeastern University, Shenyang 110819, China
引用本文:

王雨晴, 王金贺, 李可馨, 付华萌, 张海峰. W/TiZrVAl高熵合金复合材料制备和性能[J]. 材料研究学报, 2026, 40(7): 553-560.
Yuqing WANG, Jinhe WANG, Kexin LI, Huameng FU, Haifeng ZHANG. Microstructure and Mechanical Properties for Composites of W/TiZrVAl High-entropy Alloy Sintered by Hot Isostatic Pressing[J]. Chinese Journal of Materials Research, 2026, 40(7): 553-560.

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摘要: 

采用热等静压(HIP)烧结制备了W颗粒增强Ti7Zr1.5VAl0.5高熵合金复合材料并用X射线衍射(XRD)和扫描电子显微镜(SEM)等手段对其表征,系统研究了W含量对这种复合材料的微观结构、致密化以及室温压缩性能的影响。结果表明,W与Ti7Zr1.5VAl0.5高熵合金摩尔比为1∶1的复合材料综合力学性能最优,其屈服强度为1146 MPa、断裂应变为36%。随着W与Ti7Zr1.5VAl0.5高熵合金摩尔比的提高,这种复合材料的屈服强度和塑性呈降低的趋势。摩尔比为2∶1的复合材料,其屈服强度和断裂应变分别降低到892 MPa和16%。随着W含量的提高,这种材料的断裂机制由以韧性断裂为主逐渐转变为以脆性断裂为主。力学性能降低的原因是:W颗粒与基体之间显著的密度差异使材料中产生重力偏析和颗粒团聚,在一定程度上削弱了弥散强化。随着W含量的提高W颗粒表面的孔隙增多且在烧结过程中不能完全消除,导致复合材料的致密度降低。同时,这些微孔隙在外加载荷作用下产生应力集中,促进微裂纹的萌生和扩展而引发W颗粒与基体的界面脱粘,使复合材料发生断裂。

关键词 复合材料高熵合金热等静压微观结构力学性能    
Abstract

Composites with W particles as the reinforcement phase and Ti7Zr1.5VAl0.5 high-entropy alloy (HEA) as the matrix were fabricated via hot isostatic pressing (HIP) sintering. The effect of W content on the microstructure, densification behavior, and room-temperature compression properties of the composites were systematically investigated using X-ray diffraction, scanning electron microscopy and electronic universal testing machine. The results indicated that the composite with W:Ti7Zr1.5VAl0.5 of 1:1 (in molar ratio) exhibited the optimal comprehansive mechanical properties, achieving a yield strength of 1146 MPa and a plastic strain of 36%. As the molar ratio of W to Ti7Zr1.5VAl0.5 increased, both the yield strength and plasticity generally showed a declining trend. At a molar ratio of 2:1, the yield strength and plastic strain decreased to 892 MPa and 16%, respectively. Concurrently, the dominant fracture mechanism transitioned from ductile to brittle with the increasing W content. The deterioration in mechanical performance may be attributed to several factors. First, the significant density difference between W particles and the HEA matrix promoted gravity segregation and particle agglomeration, which weakened the dispersion-strengthening effect. In addition, a higher W content led to an increased number of inherent pores on the W particle surfaces; these pores could not fully be eliminated during sintering and consequently reduced the overall densification of the composite. Furthermore, under external loading, such micro-pores could act as stress-concentration sites, facilitating the initiation and propagation of micro-cracks and ultimately inducing interfacial debonding between the matrix and the W particles, which resulted in fracture.

Key wordscomposite    high-entropy alloy    hot isostatic pressing    microstructure    mechanical properties
收稿日期: 2025-10-27     
ZTFLH:  TB331  
基金资助:国家自然科学基金(52501195)
通讯作者: 付华萌,研究员,hmfu@imr.ac.cn,研究方向为非晶合金制备技术
Corresponding author: FU Huameng, Tel: (024)23971783, E-mail: hmfu@imr.ac.cn
作者简介: 王雨晴,女,2001年生,硕士生
图1  HEA粉和W颗粒的SEM照片
图2  不同比例的W颗粒与HEA粉混料5 h后的SEM照片
图3  高熵合金复合材料的SEM照片和EDS面扫描图
图4  WHC1复合材料的SEM照片和EDS线扫描图
图5  W/HEA复合材料的XRD谱
Compositesρt /g·cm-3ρe /g·cm-3RD
WHC111.6111.570.99
WHC212.8312.680.99
WHC313.3012.720.96
WHC414.0713.080.93
表1  W/HEA复合材料的理论密度和实际密度
图6  W/HEA复合材料的室温压缩工程应力-应变曲线
CompositesTheoretical yield stress / MPaYield stress/ MPaFracture strain / %
WHC1855.8114636
WHC2878.696531
WHC3886.895522
WHC4901.689216
HEA-94023
表 2  W/HEA复合材料的室温压缩力学性能
图7  HEA和WHC1复合材料在室温压缩断裂后的宏观和微观形貌
图8  复合材料HIP前后W颗粒表面孔隙示意图
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