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Chinese Journal of Materials Research  2014, Vol. 28 Issue (3): 173-179    DOI: 10.11901/1005.3093.2013.602
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Effect of Hot-press Sintering Temperature on Tribological Performance of Ni-Co-Al Superalloy
Chenglai XIN1,2,Qin MA1,Wenzhen WANG2,**(),Junhong JIA2
1. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou, 730050
2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000
Cite this article: 

Chenglai XIN,Qin MA,Wenzhen WANG,Junhong JIA. Effect of Hot-press Sintering Temperature on Tribological Performance of Ni-Co-Al Superalloy. Chinese Journal of Materials Research, 2014, 28(3): 173-179.

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Abstract  

A Ni-Co-Al superalloy was prepared by powder metallurgy(mechanical alloying + hot-press sintering). Then the effect of hot-press sintering temperature on the mechanical property of the alloy at ambient temperatures and the tribological performance at 800℃ were investigated. Results show that the density, hardness and compressive strength of the alloy increase with the increase of sintering temperature, while these properties change little when the sintering temperature above 1200℃. As the sintering temperature increases, the tribological performance of the alloy at 800℃gets better. The examination of the worn surface morphology by SEM and XPS found that a glaze-like oxide scale formed on the worn surface, which seemed to be beneficial to the tribological performance. The adhesive strength between the oxide scale and the substrate affects the tribological performance of the alloy, which may relate to higher density induced by higher sintering temperature. The examination of the worn surface with 3D non-contact surface mapping profiler exhibits that the depth of abrasion grooves is dependent on the hot-pressing temperature.

Key words:  metal material      P/M superalloy      hot-press sintering temperature      tribological performance     
Received:  20 August 2013     
Fund: *Supported by National Natural Science Foundation of China No. 51101166.

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2013.602     OR     https://www.cjmr.org/EN/Y2014/V28/I3/173

Sample code Temperature /℃ Pressure/MPa Sintering time/min Heating rate℃/min Density/g/cm3 Relative density %
1# 1100 20 60 10 7.44 93.2
2# 1200 20 60 10 7.73 96.9
3# 1260 20 60 10 7.79 97.6
Table 1  Parameters of hot-pressing sintering in vacuum
Fig.1  SEM images of powder after different high energy ball-milling time (a) 30 h, (b) 40 h,(c) 50 h
Fig.2  XRD pattern of powder after different high energy ball-milling time
Fig.3  XRD pattern of Ni-10Co-5Al alloy
Fig.4  SEM micrograph of Ni-10Co-5Al alloy sintered at 1260℃
Fig.5  Variations of hardness、compressive strength with sintering temperature of Ni-10Co-5Al alloy
Fig.6  Variation of friction coefficient of Ni-10Co-5Al alloy with sintering temperature
Fig.7  Variation of wear rate of Ni-10Co-5Al alloy with sintering temperature
Fig.8  SEM micrograghs of wore surfaces of Ni-10Co-5Al alloy sintered at 1100℃ (a), sintered at 1200℃ (b) and sintered at 1260℃ (c)
Fig.9  3D contour map of wore surface of Ni-10Co-5Al sintered at1100℃ (a), sintered at 1200℃ (b) and sintered at 1260℃ (c)
Fig.10  XPS patterns of worn surface of Ni-10Co-5Al sintered at 1260℃
Sample Ni metal / ev NiO / ev Ni2O3 / ev Co metal / ev CoO / ev
BE Ni2p3/2 BE=852.5 Ni2p3/2 BE=854.0 Ni2p3/2 BE=855.5 Co2p3/2 BE=778.0. Co2p3/2 BE=780.5
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Table 2  Comparison table of Binding energy
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