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Chinese Journal of Materials Research  2012, Vol. 26 Issue (5): 533-537    DOI:
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Synthesis and Electrochemical Properties of HDI Trimer Modified Polyurethane/Polypyrrole
LENG Cuiting, LI Xiaorui, FEI Guiqiang, WANG Haihua
Key Laboratory of Aids Chemistry & Technology for Light Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xian 710021
Cite this article: 

LENG Cuiting LI Xiaorui FEI Guiqiang WANG Haihua. Synthesis and Electrochemical Properties of HDI Trimer Modified Polyurethane/Polypyrrole. Chinese Journal of Materials Research, 2012, 26(5): 533-537.

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Abstract  

Pyrrole was polymerized into HDI trimer modified silicone polyurethane (HESO) foam by in–situ adsorption polymerization process in order to manufacture conductive silicone polyurethane (PPy/HESO). The effects of different preparative conditions including feeding ratios, feeding sequences and reaction conditions were investigated. The results show that the optimum preparative conditions arepyrrole to HESO mass ratio 12.5:100, ferric chloride and anthraquinone –2–sulfonate(AQS) to pyrrole
molar ratio of 2.2 : 1.2 : 1, feeding sequence: HESO–Pyrrole–AQS–FeCl3, reaction temperature 0℃,  pH=3 of the reaction solution. Effect of the Si and polypyrrole on electrochemical properties has a concertedness. It is more conducive to PPy/HESO, and forming a continuous core–shell–type conductive polymer in the HESO latex surface or at the interface.

Key words:  composites      silicone polyurethane      in–situ adsorption polymerization      electrochemical properties     
Received:  05 July 2012     
ZTFLH:  TB324  
  TQ323  
Fund: 

Supported by National Natural Science Foundation of China No.50973057.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I5/533

1 YIN Wusheng, Progress in the synthetic methods of polypyrrole conducting material, Journal of Functional Materials, 27(2), 97(1996)

(尹五生, 聚吡咯导电材料合成方法的进展, 功能材料,  27(2), 97(1996))

2 LI Liangbo, LIU Laitao, MENG Pingrui, DONG Chenguang, DU Xinying, Study of electrically conductive coating made of water–based polyurethane/cement/carbon black, 25(2), 28(2009)

(李良波, 刘来涛, 孟平蕊, 董辰光, 杜辛颖, 水性聚氨酯/水泥/碳黑导电涂层的研究, 化学建材,  25(2), 28(2009))

3 Z.C.Xing, W.P.Chae, J.Y.Baek, M.J.Choi, Y.Jung, I.K.Kang, In vitro assessment of antibacterial activity and cytocompatibility of silver containing PHBV nanofibrous scaffolds for tissue engineering, Biomacromolecules, 11, 1248(2010)

4 C.Y.Li, W.Y.Chiu, T.M.Don, Polyurethane/polyaniline and polyurethane–poly (methylmeth–acrylate)/polyaniline conductive core–shell Part 2: preparation, morphology, and conductivity, J. Poly. Sci.: Poly. Chem., 45(3), 3902(2007)

5 ZHANG Sha, SUN Dongcheng, Preparation and application of conducting polyurethane dispersion, Guang Zhou Chemical Industry, 38(4), 77(2010)

(张 莎, 孙东成, 导电聚氨酯分散体的制备及应用, 广州化工,  38(4), 77(2010))

6 K.Kofuji, Y.Murata, S.Kawashima, Sustained insulin release with biodegradation of chitosangel beads prepared by copperions, International Journal of Pharmaceutics, 303(1–2), 95(2005)

7 ZHOU Xiangdong, LIU Pengsheng, Superfine conductive powder modified PU elastomer and its characterization, China Plastics, 19(4), 45(2005)

(周向东, 刘朋生, 超细导电粉末改性聚氨酯弹性体及其性能表征, 中国塑料,  19(4), 45(2005))

8 I.Sapurina, J.Stejskal, Spirkova M, Polyurethane latex modified with polyaniline, Synth. Metal., 151(2), 93(2005)

9 S.Bhadra, D.Khastgir, N.Ksingha, Progress in preparation, processing and applications of polyaniline, Prog. Polym. Sci., 34(8), 78(2009)

10 FU Chao, LI Zhanglin, ZHU Xian, YANHao, Electrochemical synthesis of polypyrrole thin film in supercritical CO2/ionic liquid biphase system, Chemical Research, 20(4), 24(2009)

(付 超, 李章林, 朱 宪, 鄢 浩, 聚吡咯薄膜在超临界CO2与离子液体两相体系中的电化学合成, 化学研究,  20(4), 24(2009))

11 N.V.Blinova, J.Stejskal, M.Trchova, The oxidation of aniline with silver nitrate to polyaniline silver composites, Polymer, 50(1), 50(2009)

12 NI Wei, XU Qun, Preparation and application of PU–based polyaniline conducting composite, Polyurethane Industry, 22(6), 6(2007)

(倪 伟, 许 群, 聚氨酯/聚苯胺导电复合材料的制备与应用, 聚氨酯工业,  22(6), 6(2007))

13 C.Yang, C.Chen, Y.Zeng, Fourier transform infrared spectra of transition metalion containing polyanilines synthesized in different reaction conditions, Spectrochim Acta, Part A, 66(1), 37(2007)

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