AgPbSbTe Thermoelectric Materials Fabricated by Mechanical Alloying and Spark Plasma Sintering (SPS)

Chin J Mater Res

2010, Vol. 24

Issue (2): 154-158 DOI:

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AgPbSbTe Thermoelectric Materials Fabricated by Mechanical Alloying and Spark Plasma Sintering (SPS)

ZHOU Min¹; LI Laifeng¹; LI Jingfeng²

1.the Key Laboratory of Cryogenics; Technical Institute of Physics and Chemistry; Chinese Academy of Sciences; Beijing 100190
2. State Key Laboratory of New Ceramics and Fine Processing; Department of Materials Science and Engineering; Tsinghua University; Beijing 100084

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ZHOU Min LI Laifeng LI Jingfeng. AgPbSbTe Thermoelectric Materials Fabricated by Mechanical Alloying and Spark Plasma Sintering (SPS). Chin J Mater Res, 2010, 24(2): 154-158.

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Abstract

High performance AgPbSbTe thermoelectric materials were fabricated by mechanical alloying (MA) and spark plasma sintering (SPS). The effect of preparation technique on the thermoelectric properties was studied. The results showed that the phase composition and thermoelectric properties are related to the mechanical alloying. Appropriate SPS technique could decrease crystal growing, increase phonon scattering and reduce thermal conductivity. A maximum power factor of 18 μW/K²cm and a minimum thermal conductivity of 1.1 W/m K were obtained. A maximum ZT value of 1.2 was obtained at 700 K for the sample fabricated by MA (350 rpm for 4 hrs) and SPS (sintering at 673 K for 5 minute).

Key words: inorganic non–metallic materials thermoelectric materials mechanical alloying spark plasma sintering

Received: 15 December 2009

Fund:

Supported by National Basic Research Program of China No.2007CB607500, National Natural Science Foundation of China (Nos.50802101, 50325207 and 50820145203).

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1 R.Venkatasubramanian, E.Siivola, V.Colpitts, B.O'Quinn, Thin–film thermoelectric devices with high room–temperature figures of merit, Nature, 413(6856), 597(2001)
2 M.Zhou, C.D.Feng, L.D.Chen, X.Y.Huang, Effects of partial substitution of Co by Ni on the thermoelectric properties of TiCoSb–based half–Heusler compounds, Journal of Alloy Compd., 194, 391(2005)
3 M.Zhou, L.D.Chen, C.D.Feng, X.Y.Huang, Synthesis and electrical transport properties of TiCo1−xPdxSb half– Heusler compounds, Key Eng. Mater., 283, 405 (2005)
4 L.D.Hicks, T.C.Harman, X.S.Sun, Dresselhaus M S, Experimental study of the effect of quantum–well structures on the thermoelectric figure of merit, Phys. Rev. B: Condens. Matter Mater. Phys., 53, R10493(1996)
5 X.J.Zheng, L.L.Zhu, Y.H.Zhou, Q.J.Zhang, Impact of grain sizes on phonon thermal conductivity of bulk thermoelectric materials, Appl. Phys. Lett., 87(24), 242101(2005)
6 D.M.Rowe, CRC Handbook of Thermoelectrics, (New York: CRC press, 1995) p.257
7 B.C.Sales, D.Mandrus, R.K.Williams, Filled Skutterudite Antimonides: A New Class of Thermoelectric Materials, Science, 272, 1325(1996)
8 B.C.Sales, B.C.Chakoumakos, D.Mandrus, R.K.Williams, J. Solid State Chem., 146(2), 528(1999)
9 YU Boling, QI Qiong, TANG Xinfeng, ZHANG Qingjie, Effect of grain size on thermoelectric properties of CoSb3 compound, Acta Physica Sinica, 54(12), 5763(2005)
(余柏林, 祁琼, 唐新峰, 张清杰, 晶粒尺寸对CoSb3化合物热电性能的影响, 物理学报, 54(12), 5763(2005))
10 T.C.Harman, P.J.Taylor, M.P.Walsh, B.E.Laforge, Quantum Dot Superlattice Thermoelectric Materials and Devices, Science, 297, 2229(2002)
11 T.C.Harman, D.L.Spears, M.J.Manfra, High thermoelectric figures of merit in PbTe quantum wells, J Electron Mater., 25(7), 1121(1996)
12 H.Beyer, J.Nurnus, H.Bottner, A.Lambrecht, T.Roch, G.Bauer, PbTe based superlattice structures with high thermoelectric efficiency, Appl. Phys. Lett., 80(7), 1216(2002)
13 T.C.Harman, M.P.Walsh, B.E.Laforge, G.W.Turne, Nanostructured thermoelectric materials, J Electron Mater., 34(5), 680(2005)
14 K.F.Hsu, S.Loo, F.Guo, W.Chen, J.S.Dyck, C.Uher, T.Hogan, E.K.Polychroniadis, M.G.Kanatzidis, Cubic AgPbmSbTem+2: bulk thermoelectric materials with high figure of merit, Science, 303, 818(2004)
15 ZHOU Min, LI Jinfeng, WANG Heng, Fabrication and property of high-performance Ag–Pb–Sb–Te system semiconduction thermoelectric materials, Chinese Science Bulletin, 52(1),114 (2007)
(周敏, 李敬锋, 王衡, 高性能Ag--Pb--Sb--Te体系半导体热电材料的制备与性能, 科学通报, 52(1), 114(2007))
16 M Zhou, J F Li, T Kita, Nanostructured AgPbmSbTem+2 system bulk materials with enhanced thermoelectric performance, J. Am. Chem. Soc., 130(13), 4527(2008)

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