|
|
Effect of Ratio of Monomer to Crosslinker on Synthesis of BeO Nanopowders via Polyacrylamide Gel Method |
WANG Xiaofeng, WANG Richu, PENG Chaoqun, LI Tingting, LIU Bing |
School of Materials Science and Engineering, Central South University, Changsha 410083 |
|
Cite this article:
WANG Xiaofeng WANG Richu PENG Chaoqun LI Tingting LIU Bing. Effect of Ratio of Monomer to Crosslinker on Synthesis of BeO Nanopowders via Polyacrylamide Gel Method. Chin J Mater Res, 2010, 24(6): 572-578.
|
Abstract The effects of the ratio of the monomer to crosslinker on the process and property of BeO nanopowders were investigated. The results show that the sulfate salt is disintegrated by the auxiliary three-dimensional (3D) tangled network of polymers, so its thermo-decomposing temperature declines obviously. When the ratio of the monomers and cross linker is 6 : 1, the decline degree of the thermo-decomposing temperature is the highest which is around 177oC; the average particle size of the powders with narrow particles distribution and less aggregation is the smallest which is about 16 nm. When the ratio deviates from 6 : 1, the decline degree of the thermo-decomposing temperature becomes smaller, and the average particle size of the powders increases.
|
Received: 07 September 2010
|
|
Fund: Supported by the National Science Foundation Coordinated for Civil No.MKPT-03-182. |
[1]NI Meng, Leung Michael K.H..Leung Dennis Y.C..Technology development in nano-sized photocatalyst powder preparation technologies. Powder Metallurgy Technology,2006,24:379-383
[2]倪 萌, Leung Michael K. H., Leung Dennis Y. C..光催化剂纳米粉体的制备技术.粉末冶金技术,2006,24:379-383
[3]Igor Djerdj, Denis Ar?on, Zvonko Jagli?i?, Markus Niederberger.Nonaqueous synthesis of metal oxide nanoparticles: Short review and doped titanium dioxide as case study for the preparation of transition metal-doped oxide nanoparticles.Journal of Solid State Chemistry,2008,181:1571-1581
[4]G.C.C. Costa, R. Muccillo.Synthesis of scandia-stabilized zirconia nanoparticles by the polyacrylamide technique.Solid State Ionics,2008,179:1219-1222
[5]Douy A., Odier P..The polyacrylamide gel: a novel route to ceramic and glassy oxide powders.Materials Research Bulletin,1989,24:1119-1126
[6]André Douy.Polyacrylamide gel: an efficient tool for easy synthesis of multicomponent oxide precursors of ceramics and glasses.International Journal of Inorganic Materials,2001,3:699-707
[7]SHAO Zhongbao, LI Guo-rong.Prepararion of nanometer-sized Zinc oxide powders by polyacrylamide gel method.Chinese Journal of Materials Research,2001,15:681-685
[8]邵忠宝, 李国荣.高分子网络凝胶法制备纳米ZnO粉料.材料研究学报,2001,15:681-685
[9]H. Wang, L. Gao, Weiqun li, Qiang li.Preparation of nanoscale α-Al2O3 by the polyacrylamide gel method.NanoStructured Materials,1999,11:1263-1267
[10]M. Tahmasebpour, A.A. Babaluo, S. Shafiei, E. Pipelzadeh.Studies on the synthesis of α-Al2O3 nanopowders by the polyacrylamide gel method.Powder Technology,2009,191:91-97
[11]M. Tahmasebpour, A.A. Babaluo, M.K. Razavi Aghjeh.Synthesis of zirconia nanopowders from various zirconium salts via polyacrylamide gel method.Journal of the European Ceramic Society,2008,28:773-778
[12]Chuanyi Pan, Xuehui Li, Furong Wang, Lefu Wang.Synthesis of bismuth oxide nanoparticles by the polyacrylamide gel route.Ceramics International,2008,34:439-441
[13]Ning Liu, Yupeng Yuan, P. Majewski, F. Aldinger.Synthesis of La0.85Sr0.15Ga0.85Mg0.15O2.85 materials for SOFC applications by acrylamide polymerization.Materials Research Bulletin,2006,41:461-468
[14]A. Tarancón, G. Dezanneau, J. Arbiol, F. Peiro.J.R. Morante. Synthesis of nanocrystalline materials for SOFC applications by acrylamide polymerization.Journal of Power Sources,2003,118:256-264
[15]13 PAN Zuren, Polymer Chemistry, (Beijing, Chemical Industry Press, 2006) p. 78-8
[16](潘祖仁, 高分子化学 (北京, 化学工业出版社, 2006) p.78-80
[17]14 FANG Daobin, GUO Ruiwei, Ha Runhua, Polymers of acrylamide, (Beijing, Chemical Industry Press, 2006) p. 143-18
[18](方道斌, 郭睿威, 哈润华, 丙烯酰胺聚合物, (北京, 化学工业出版社, 2006) p. 143-181
[19]Dollimore D., Konieczay J. L..The thermal decomposition of beryllium oxalate and related materials.Thermochimica Acta,1998,318:155-163
[20]LI Jinfeng, SUN Yishi, RUN Zhu, On copolymerization of acrylamide with N.N’–methylenebisacylamide.Acta Polymerica Sinica,1990,5:593-599
[21]李金峰, 孙以实, 阮竹, 丙烯酰胺与N.N’-亚甲基双丙烯酰胺的共聚反应研究.高分子学报,1990,5:593-599
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|