钛合金表面<strong>Si</strong>改性铝化物涂层制备及其高温氧化行为

doi:10.11901/1005.3093.2024.052

材料研究学报

2024, Vol. 38

Issue (12): 881-892 DOI: 10.11901/1005.3093.2024.052

研究论文

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钛合金表面Si改性铝化物涂层制备及其高温氧化行为

刘国强¹, 冯长杰¹, 辛丽²(

), 马天宇³, 常皓², 潘钰璇², 朱圣龙²

1 沈阳航空航天大学材料科学与工程学院沈阳 110136
2 中国科学院金属研究所师昌绪先进材料创新中心沈阳 110016
3 东北大学材料科学与工程学院沈阳 110819

Preparation and High Temperature Oxidation Resistance of Si Modified Aluminide Coating on Titanium Alloy

LIU Guoqiang¹, FENG Changjie¹, XIN Li²(

), MA Tianyu³, CHANG Hao², PAN Yuxuan², ZHU Shenglong²

1 School of Materials Science & Engineering, Shenyang Aerospace University, Shenyang 110136, China
2 Shi -Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3 School of Materials Science &Engineering, Northeastern University, Shenyang 110819, China

引用本文:

刘国强, 冯长杰, 辛丽, 马天宇, 常皓, 潘钰璇, 朱圣龙. 钛合金表面Si改性铝化物涂层制备及其高温氧化行为[J]. 材料研究学报, 2024, 38(12): 881-892.
Guoqiang LIU, Changjie FENG, Li XIN, Tianyu MA, Hao CHANG, Yuxuan PAN, Shenglong ZHU. Preparation and High Temperature Oxidation Resistance of Si Modified Aluminide Coating on Titanium Alloy[J]. Chinese Journal of Materials Research, 2024, 38(12): 881-892.

全文: PDF(28056 KB) HTML

摘要:

用多弧离子镀技术在钛合金表面沉积不同Si含量的Al-Si涂层并对其进行真空扩散退火处理，研究了Si含量对这种涂层的显微结构和高温抗氧化性能的影响。结果表明，这种Si改性扩散铝化物涂层具有层状结构，主要由TiAl₃、TiAl₂和TiAl等Ti-Al金属间化合物相以及Ti₅Si₃和Ti₅Si₄析出相组成，部分Si替位固溶在TiAl₃中生成了Ti(Al,Si)₃。在650℃循环氧化后Si改性铝化物涂层表现出优良的抗高温氧化性能；在750℃循环氧化，随着涂层中Si含量的提高涂层的抗高温氧化性能随之提高。

关键词 ：金属材料, Si改性铝化物涂层, 钛合金, 高温氧化, 扩散

Abstract：

Al-Si coatings with different Si content were deposited on the surface of Ti-alloy Ti-6Al-4V by multi-arc ion plating, then which were subjected to vacuum heat treatment at 900^oC for 1 h and thereby Si-modified aluminide coatings with gradually decreasing Al-content along the normal of coating inwards were acquired The aluminide coatings exhibited layered structure and were mainly composed of Ti-Al intermetallics including TiAl₃, TiAl₂, TiAl and precipitates including Ti₅Si₃ and Ti₅Si₄, and certain amount of Si atoms were dissolved in the TiAl₃ as substitutes and formed Ti(Al, Si)₃. The Si modified aluminide coatings showed excellent cyclic oxidation resistance at 650^oC. It is worthy to note that at 750^oC, the cyclic oxidation resistance of the aluminide coatings increased with the increasing of Si content.

Key words： metallic materials Si modified aluminide coating titanium alloy high temperature oxidation diffusion

收稿日期: 2024-01-22

ZTFLH:

TG156

基金资助:国家自然科学基金(52371085);兴辽英才计划(XLYC2002031)

通讯作者: 辛丽，研究员，xli@imr.ac.cn，研究方向为高温腐蚀与防护以及高温防护涂层

Corresponding author: XIN Li, Tel: 13664116162, E-mail: xli@imr.ac.cn

作者简介: 刘国强，男，1999年生，硕士生

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图1 0Si、5.2Si、12.5Si和25.7Si涂层的XRD谱

图2 0Si、5.2Si、12.5Si和25.7Si涂层的表面形貌、截面形貌以及EDS截面元素分布

表1 图2中标示区域的EDS成分

表2 在900℃真空退火过程中可能发生反应的标准Gibbs自由能

图3 TC4、0Si、5.2Si、12.5Si和25.7Si涂层在650℃的循环氧化动力学曲线

图4 在650℃循环氧化后试样的宏观形貌

图5 0Si、5.2Si、12.5Si和25.7Si涂层在650℃循环氧化300周期后的XRD谱

图6 涂层在650℃循环氧化300周期后表面和截面的SEM形貌

表3 在650℃循环氧化300周期后0Si、5.2Si、12.5Si和25.7Si涂层氧化膜表面的EDS成分分析

图7 TC4、0Si、5.2Si、12.5Si和25.7Si涂层在750℃循环氧化动力学曲线

图8 在750℃循环氧化后试样的宏观照片

图9 0Si、5.2Si、12.5Si和25.7Si涂层在750℃氧化不同时间后的XRD谱

图10 涂层在750℃循环氧化后SEM表面和截面的形貌

图11 在750℃循环氧化300周期后涂层截面的EPMA元素分布

表4 图10中标示区域的EDS成份分析

1	Peters M, Kumpfert J, Ward C H, et al. Titanium alloys for aerospace applications [J]. Adv. Eng. Mater., 2003, 5(6): 419
2	Veiga C, Davim J P, Loureiro A J R. Properties and applications of titanium alloys: a brief review [J]. Rev. Adv. Mater. Sci., 2012, 32: 133
3	Pushp P, Dasharath S M, Arati C. Classification and applications of titanium and its alloys [J]. Mater. Today: Proc., 2022, 54: 537
4	Cui C X, Hu B M, Zhao L C, et al. Titanium alloy production technology, market prospects and industry development [J]. Mater. Des., 2011, 32(3): 1684
5	Vaché N, Cadoret Y, Dod B, et al. Modeling the oxidation kinetics of titanium alloys: review, method and application to Ti-64 and Ti-6242s alloys [J]. Corros. Sci., 2021, 178: 109041
6	Berthaud M, Popa I, Chassagnon R, et al. Study of titanium alloy Ti6242S oxidation behaviour in air at 560 ^oC: effect of oxygen dissolution on lattice parameters [J]. Corros. Sci., 2020, 164: 108049
7	Satko D P, Shaffer J B, Tiley J S, et al. Effect of microstructure on oxygen rich layer evolution and its impact on fatigue life during high-temperature application of α/β titanium [J]. Acta Mater., 2016, 107: 377
8	Ebach-Stahl A, Eilers C, Laska N, et al. Cyclic oxidation behaviour of the titanium alloys Ti-6242 and Ti-17 with Ti-Al-Cr-Y coatings at 600 and 700 ^oC in air [J]. Surf. Coat. Technol., 2013, 223: 24
9	Chaia N, Cossu C M, Parrisch C J, et al. Growth kinetics of TiAl₃diffusion coating by pack cementation on beta 21-S [J]. J. Phase Equilib. Diffus., 2020, 41(3): 181
10	Das D K, Alam Z. Cyclic oxidation behaviour of aluminide coatings on Ti-base alloy IMI-834 at 750 ^oC [J]. Surf. Coat. Technol., 2006, 201: 3406
11	Oukati Sadeq F, Sharifitabar M, Shafiee Afarani M. Synthesis of Ti-Si-Al coatings on the surface of Ti-6Al-4V alloy via hot dip siliconizing route [J]. Surf. Coat. Technol., 2018, 337: 349
12	Alam Z, Das D K. Effect of cracking in diffusion aluminide coatings on their cyclic oxidation performance on Ti-based IMI-834 alloy [J]. Corros. Sci., 2009, 51(6): 1405
13	McMordie B G. Oxidation resistance of slurry aluminides on high temperature titanium alloys [J]. Surf. Coat. Technol., 1991, 49(1-3): 18
14	Chen C, Feng X M, Shen Y F. Oxidation behavior of a high Si content Al-Si composite coating fabricated on Ti-6Al-4V substrate by mechanical alloying method [J]. J. Alloys Compd., 2017, 701: 27
15	Cammarota G P, Casagrande A, Sambogna G. Effect of Ni, Si and Cr in the structural formation of diffusion aluminide coatings on commercial-purity titanium [J]. Surf. Coat. Technol., 2006, 201(1-2): 230
16	Yan W, Sun F J, Wang Q J, et al. Hot corrosion behavior of arc-ion plating Ti-Al-Cr(Si,Y) coatings on Ti60 alloy [J]. Acta Metall. Sin., 2009, 45(10): 1171
16	闫伟, 孙凤久, 王清江等. Ti60合金表面电弧离子镀Ti-Al-Cr(Si, Y)防护涂层的热腐蚀行为 [J]. 金属学报, 2009, 45(10): 1171
17	Li Z H, Chai L J, Qi L, et al. Laser-cladded Al-Cr-Ti ternary alloy coatings on Ti-4Al-2V alloy: specific microstructure and enhanced surface performance [J]. Surf. Coat. Technol., 2023, 452: 129073
18	Feng Y, Chen Z Y, Jiang S M, et al. Effect of a NiCrAlSiY coating on cyclic oxidation and room temperature tensile properties of Ti65 alloy plate [J]. Chin. J. Mater. Res., 2023, 37(7): 523 doi: 10.11901/1005.3093.2022.145
18	冯叶, 陈志勇, 姜肃猛等. 一种NiCrAlSiY涂层对Ti65钛合金板材循环氧化和室温力学性能的影响 [J]. 材料研究学报, 2023, 37(7): 523
19	Zhang M M, Cheng Y X, Xin L, et al. Cyclic oxidation behaviour of Ti/TiAlN composite multilayer coatings deposited on titanium alloy [J]. Corros. Sci., 2020, 166: 108476
20	Li C G, Wang Y, Tian W, et al. Nanostructured Al₂O₃-TiO₂ coatings for high-temperature protection of titanium alloy during ablation [J]. Mater. Charact., 2010, 61: 796
21	Xiao Z Q, Tan F T, Wang W, et al. Oxidation protection of commercial-purity titanium by Na₂O-CaO-SiO₂ and Na₂O-CaO-Al₂O₃-SiO₂ glass-ceramic coatings [J]. Ceram. Int., 2015, 41(1): 325
22	Yang Y F, Jiang C Y, Yao H R, et al. Cyclic oxidation and rumpling behaviour of single phase β-(Ni, Pt)Al coatings with different thickness of initial Pt plating [J]. Corros. Sci., 2016, 111: 162
23	Zhu G L, Shu D, Dai Y B, et al. First principles study on substitution behaviour of Si in TiAl₃ [J]. Acta Phys. Sin., 2009, 58(suppl.1) : 210
23	祝国梁, 疏达, 戴永兵等. Si在TiAl₃中取代行为的第一性原理研究 [J]. 物理学报, 2009, 58(): 210
24	Bulanova M, Tretyachenko L, Golovkova M, et al. Phase equilibria in the α-Ti-Al-Si region of the Ti-Si-Al system [J]. J. Phase Equilib. Diffus., 2004, 25(3): 209
25	Zhang K, Xin L, Lu Y L, et al. Improving oxidation resistance of γ-TiAl based alloy by depositing TiAlSiN coating: effects of silicon [J]. Corros. Sci., 2021, 179: 109151
26	Rao K P, Zhou J B. Characterization of mechanically alloyed Ti-Al-Si powder blends and their subsequent thermal stability [J]. Mater. Sci. Eng., 2002, 338A: 282
27	Li Y, Gu Q F, Luo Q, et al. Thermodynamic investigation on phase formation in the Al-Si rich region of Al-Si-Ti system [J]. Mater. Des., 2016, 102: 78
28	Kahrobaee Z, Palm M. Experimental investigation of Ti-Al-Si phase equilibria at 800~1200^oC [J]. J. Alloys Compd., 2022, 924: 166223
29	Sujata M, Bhargava S, Sangal S. On the formation of TiAl₃during reaction between solid Ti and liquid Al [J]. J. Mater. Sci. Lett., 1997, 16: 1175
30	Li J. Effect of Si in al alloy on intermetallic compounds growth behavior during reaction between solid Ti and liquid Al [D]. Harbin: Harbin Institute of Technology, 2012
30	李晶. Si对Ti/Al固液界面金属间化合物生长行为的影响 [D]. 哈尔滨: 哈尔滨工业大学, 2012
31	Hu X Y, Li F G, Shi D M, et al. A design of self-generated Ti-Al-Si gradient coatings on Ti-6Al-4V alloy based on silicon concentration gradient [J]. J. Alloys Compd., 2020, 830: 154670
32	Chaze A M, Coddet C. Influence of silicon on the oxidation of titanium between 550 and 700 ^oC [J]. Oxid. Met., 1987, 27(1-2): 1
33	Vojtěch D, Bártová B, Kubatı́k T. High temperature oxidation of titanium-silicon alloys [J]. Mater. Sci. Eng., 2003, 361A(1-2) : 50
34	Ikuma Y, Shimada E, Sakano S, et al. Oxygen self-diffusion in cylindrical single-crystal mullite [J]. J. Electrochem. Soc., 1999, 146(12): 4672
35	Fielitz P, Borchardt G, Schmücker M, et al. Oxygen grain-boundary diffusion in polycrystalline mullite ceramics [J]. J. Am. Ceram. Soc., 2004, 87: 2232
36	Gorai P, Hollister A G, Pangan-Okimoto K, et al. Kinetics of oxygen interstitial injection and lattice exchange in rutile TiO₂ [J]. Appl. Phys. Lett., 2014, 104: 191602
37	Maeda K, Suzuki S, Ueda K, et al. Experimental and theoretical study of the effect of Si on the oxidative behavior of Ti-6Al-4V alloys [J]. J. Alloys Compd., 2019, 776: 519

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