<strong>FeCoCrNiMo/Al-10Si</strong>复合材料的制备及其摩擦磨损性能

doi:10.11901/1005.3093.2025.367

材料研究学报

2026, Vol. 40

Issue (10): 746-756 DOI: 10.11901/1005.3093.2025.367

研究论文

本期目录 | 过刊浏览

FeCoCrNiMo/Al-10Si复合材料的制备及其摩擦磨损性能

胡勇(

), 乔增欢, 辛宇

华东交通大学材料科学与工程学院南昌 330013

Fabrication and Tribological Performance of FeCoCrNiMo/Al-10Si Composites

HU Yong(

), QIAO Zenghuan, XIN Yu

School of Materials Science and Engineering, East China Jiaotong University, Nanchang 330013, China

引用本文:

胡勇, 乔增欢, 辛宇. FeCoCrNiMo/Al-10Si复合材料的制备及其摩擦磨损性能[J]. 材料研究学报, 2026, 40(10): 746-756.
Yong HU, Zenghuan QIAO, Yu XIN. Fabrication and Tribological Performance of FeCoCrNiMo/Al-10Si Composites[J]. Chinese Journal of Materials Research, 2026, 40(10): 746-756.

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摘要:

用激光沉积制备了FeCoCrNiMo/Al-10Si复合材料，使用光学显微镜(OM)、扫描电镜(SEM)、透射电镜(TEM)、UMT-3摩擦磨损机等手段表征其组织形貌、微区成分和性能，研究了这种材料的摩擦磨损性能。结果表明，随着FeCoCrNiMo高熵合金增强相含量的提高，α-Al的晶粒尺寸逐渐减小，增强相由球状转变为花瓣状最后变为粗大鱼骨状。FeCoCrNiMo高熵合金增强相与Al基体之间生成了厚度约30 nm的Al₃Ni₂界面反应层。随着FeCoCrNiMo高熵合金增强相含量的提高，FeCoCrNiMo/Al-10Si复合材料的耐磨性随之提高，但是FeCoCrNiMo高熵合金含量高于10% (质量分数)时，耐磨性提高的幅度降低。随着FeCoCrNiMo高熵合金增强相含量的提高，这种复合材料的磨损机制由疲劳磨损和粘着磨损转变为磨粒磨损。

关键词 ：复合材料, FeCoCrNiMo, 铝基复合材料, 激光沉积, 显微组织, 耐磨性能

Abstract：

Composites of FeCoCrNiMo/Al-10Si were fabricated by laser deposition technique with mixed powder of FeCoCrNiMo and Al-10Si as raw material. The microstructure, local composition and tribological properties of the composites were characterized by optical microscopy, scanning electron microscopy, transmission electron microscopy, and UMT-3 tribometer. The results demonstrate that the α-Al grain size gradually decreases with the increasing mass fraction of FeCoCrNiMo reinforcements. The morphology of the reinforcing phase evolves from initially spherical to petal-like, and finally to a coarse fishbone structure. A distinct interfacial reaction layer with a thickness of approximately 30 nm is formed between the FeCoCrNiMo high-entropy alloy and the Al matrix, which can be identified as Al₃Ni₂. As the mass fraction of the FeCoCrNiMo reinforcements increases, the wear resistance of the composites was improved correspondingly. However, when the mass fraction of FeCoCrNiMo exceeds 10%, the enhancement in wear resistance becomes less pronounced. The dominant wear mechanism shifts from fatigue and adhesive wear to abrasive wear.

Key words： composites FeCoCrNiMo Al-matrix composites laser deposition microstructure wear resistance

收稿日期: 2025-12-16

ZTFLH:

TB331

基金资助:国家自然科学基金(51865011)

通讯作者: 胡勇，教授，huyong@ecjtu.edu.cn，研究方向为金属及其复合材料

Corresponding author: HU Yong, Tel: 13576012078, E-mail: huyong@ecjtu.edu.cn

作者简介: 胡勇，男，1982年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2025.367 或 https://www.cjmr.org/CN/Y2026/V40/I10/746

图2 FeCoCrNiMo/Al-10Si复合材料晶粒的平均尺寸

图1 FeCoCrNiMo/Al-10Si复合材料的显微组织

图3 FeCoCrNiMo/Al-10Si复合材料中增强相的形貌

图4 FeCoCrNiMo增强相晶粒的平均尺寸

图5 A10复合材料的SEM-EDS分析

图6 A15复合材料的TEM照片

表1 不同元素之间的ΔHmix值(kJ/mol)

表2 A15复合材料中扩散层的点扫描

图7 A15复合材料的亮场(BF)图和选区电子衍射(SAED)图

图8 FeCoCrNiMo/Al-10Si复合材料的显微硬度

图9 FeCoCrNiMo/Al-10Si复合材料的摩擦系数

图10 FeCoCrNiMo/Al-10Si复合材料的磨痕三维轮廓形貌

图11 FeCoCrNiMo/Al-10Si复合材料磨痕的宏观形貌

图12 FeCoCrNiMo/Al-10Si复合材料的磨痕截面轮廓和磨损率

表3 FeCoCrNiMo/Al-10Si磨损表面的EDS分析

图13 FeCoCrNiMo/Al-10Si复合材料磨面的形貌

[1]	Ni D R, Wang J J, Zhou Z N, et al. Fabrication and mechanical properties of bulk NiTip/Al composites prepared by friction stir processing [J]. J. Alloy. Compd., 2014, 586: 368 doi: 10.1016/j.jallcom.2013.10.013
[2]	Lu T W, Chen W P, Wang P, et al. Enhanced mechanical properties and thermo-physical properties of 7075Al hybrid composites reinforced by the mixture of Cr particles and SiCp [J]. J. Alloy. Compd., 2018, 735: 1137 doi: 10.1016/j.jallcom.2017.11.227
[3]	Kumar S, Balasubramanian V. Effect of reinforcement size and volume fraction on the abrasive wear behaviour of AA7075 Al/SiCp P/M composites—A statistical analysis [J]. Tribol. Int., 2010, 43(1-2): 414 doi: 10.1016/j.triboint.2009.07.003
[4]	Wu Q J, Yan H, Liu Y, et al. Effect of Sr modification on microstructures and mechanical properties of Al₃Ti/ADC₁₂ composites [J]. Rare Met. Mater. Eng., 2018, 47: 742 doi: 10.1016/S1875-5372(18)30102-4
[5]	Pazhouhanfar Y, Eghbali B. Microstructural characterization and mechanical properties of TiB₂ reinforced Al6061 matrix composites produced using stir casting process [J]. Mater. Sci. Eng., 2018, 710A: 172
[6]	Rahman M H, Al Rashed H M M. Characterization of silicon carbide reinforced aluminum matrix composites [J]. Procedia Eng., 2014, 90: 103 doi: 10.1016/j.proeng.2014.11.821
[7]	Shi Q Y, Cao X, Li J Y, et al. Improved mechanical properties in friction stir processed carbon fiber reinforced aluminum composites [J]. J. Tsinghua Univ. (Sci. Technol.), 2017, 57(8): 792
[7]	史清宇, 曹雄, 李积元等. FSP制备碳纤维增强铝基复合材料的强韧化机理 [J]. 清华大学学报(自然科学版), 2017, 57(8): 792 doi: 10.16511/j.cnki.qhdxxb.2017.22.039
[8]	Dutkiewicz J, Rogal Ł, Wajda W, et al. Aluminum matrix composites strengthened with CuZrAgAl amorphous atomized powder particles [J]. J. Mater. Eng. Perform., 2015, 24(6): 2266 doi: 10.1007/s11665-014-1282-3
[9]	Li Y Z, Shi Y. Microhardness, wear resistance, and corrosion resistance of Al _x CrFeCoNiCu high-entropy alloy coatings on aluminum by laser cladding [J]. Opt. Laser Technol., 2021, 134: 106632 doi: 10.1016/j.optlastec.2020.106632
[10]	Chen Y, Ren Y M, Li K, et al. Laser powder bed fusion of oxidized microscale SiC-particle-reinforced AlSi10Mg matrix composites: Microstructure, porosity, and mechanical properties [J]. Mater. Sci. Eng., 2023, 870A: 144860
[11]	Yu W H, Sing S L, Chua C K, et al. Particle-reinforced metal matrix nanocomposites fabricated by selective laser melting: A state of the art review [J]. Prog. Mater. Sci., 2019, 104: 330 doi: 10.1016/j.pmatsci.2019.04.006
[12]	Xue G, Ke L D, Liao H L, et al. Effect of SiC particle size on densification behavior and mechanical properties of SiCp/AlSi10Mg composites fabricated by laser powder bed fusion [J]. J. Alloy. Compd., 2020, 845: 156260 doi: 10.1016/j.jallcom.2020.156260
[13]	Wang X J, Wang N Z, Wang L Y, et al. Processing, microstructure and mechanical properties of Micro-SiC particles reinforced magnesium matrix composites fabricated by stir casting assisted by ultrasonic treatment processing [J]. Mater. Des., 2014, 57: 638 doi: 10.1016/j.matdes.2014.01.022
[14]	Xue G, Ke L D, Zhu H H, et al. Influence of processing parameters on selective laser melted SiCp/AlSi10Mg composites: Densification, microstructure and mechanical properties [J]. Mater. Sci. Eng., 2019, 764A: 138155
[15]	Wang J Y, Li Z Q, Fan G L, et al. Reinforcement with graphene nanosheets in aluminum matrix composites [J]. Scr. Mater., 2012, 66(8): 594 doi: 10.1016/j.scriptamat.2012.01.012
[16]	Hu J N, Zhang J, Luo G Q, et al. Effectively enhanced strength by interfacial reactions in in-situ carbon reinforced Al matrix composites [J]. Vacuum, 2021, 188: 110148 doi: 10.1016/j.vacuum.2021.110148
[17]	Zhang S Z, Chen Z, Wei P, et al. Wear properties of Graphene/Zirconia biphase nano-reinforced aluminium matrix composites prepared by SLM [J]. Mater. Today Commun., 2022, 30: 103009
[18]	He W, Li H, Han X D, et al. High-temperature dry sliding friction and wear behavior of in-situ (Al₃Zr+ZrB₂)/AA6016 aluminum matrix composites [J]. Mater. Today Commun., 2024, 39: 108951
[19]	Diao G J, Tang Y Q, He A Q, et al. Tune Al/Ti to adjust FCC+L2₁ hetero-structured Ni-based high-entropy alloys for improved mechanical properties and wear resistance [J]. Acta Mater., 2024, 281: 120399 doi: 10.1016/j.actamat.2024.120399
[20]	Cui X H, Jiang P F, Nie M H, et al. Microstructure and wear behavior of laser cladding FeCoCrNiMo coating with gradient transition entropy interlayer [J]. Tribol. Int., 2024, 198: 109913 doi: 10.1016/j.triboint.2024.109913
[21]	Chuang M H, Tsai M H, Wang W R, et al. Microstructure and wear Behavior of Al _x Co_1.5CrFeNi_1.5Ti _y high-entropy alloys [J]. Acta Mater., 2011, 59(16): 6308 doi: 10.1016/j.actamat.2011.06.041
[22]	Zhang F, He Z Y, Lu K, et al. Interfacial microstructure and mechanical properties of 2124 aluminum alloy reinforced by AlCoCrFeNi high entropy alloy [J]. J. Mater. Res. Technol., 2023, 26: 8846 doi: 10.1016/j.jmrt.2023.09.184
[23]	Dwivedi S P, Sharma S, Singh A. Tailoring AlSi7Mg0.3 composite properties with CoCrMoNbTi high entropy alloy particles addition via FSP technique [J]. Mater. Chem. Phys., 2024, 315: 129038 doi: 10.1016/j.matchemphys.2024.129038
[24]	Zhang Y, Lei G, Luo K G, et al. Tribological behavior of high-entropy alloy particle reinforced aluminum matrix composites and their key impacting factors [J]. Tribol. Int., 2022, 175: 107868 doi: 10.1016/j.triboint.2022.107868
[25]	Liang G, Jin G, Cui X F, et al. The directional array TiN-reinforced AlCoCrFeNiTi high-entropy alloy synthesized in situ via magnetic field-assisted laser cladding [J]. Appl. Surf. Sci., 2022, 572: 151407 doi: 10.1016/j.apsusc.2021.151407
[26]	Zhang Z J, Li X M. Wear and corrosion resistance of laser cladding CoCrFeNiSi _x high entropy alloy coating [J]. Chin. J. Mater. Res., 2024, 38(10): 741
[26]	张泽疆, 李新梅. 激光熔覆CoCrFeNiSi _x 高熵合金涂层的耐磨和耐蚀性能 [J]. 材料研究学报, 2024, 38(10): 741 doi: 10.11901/1005.3093.2023.562
[27]	Lv J P, Wu Y P, Hong S, et al. Effects of WC addition on the erosion behavior of high-velocity oxygen fuel sprayed AlCoCrFeNi high-entropy alloy coatings [J]. Ceram. Int., 2022, 48(13): 18502 doi: 10.1016/j.ceramint.2022.03.120
[28]	Sahlberg M, Karlsson D, Zlotea C, et al. Superior hydrogen storage in high entropy alloys [J]. Sci. Rep., 2016, 6: 36770 doi: 10.1038/srep36770 pmid: 27829659
[29]	Liu Y Z, Chen J, Li Z, et al. Formation of transition layer and its effect on mechanical properties of AlCoCrFeNi high-entropy alloy/Al composites [J]. J. Alloy. Compd., 2019, 780: 558 doi: 10.1016/j.jallcom.2018.11.364
[30]	Huang X J, Zhang J Y, Miao J S, et al. On the interactions between molten aluminum and high entropy alloy particles during aluminum matrix composite processing [J]. J. Alloy. Compd., 2022, 895: 162712 doi: 10.1016/j.jallcom.2021.162712
[31]	Jiang J, Shen Y F. Microstructure and mechanical properties of FeCoNiCrMn high entropy alloy reinforced aluminum matrix composites prepared by friction stir processing [J]. Trans. Nanjing Univ. Aeronaut. Astronaut., 2023, 40(1): 98
[31]	江剑, 沈以赴. 搅拌摩擦加工制备FeCoNiCrMn高熵合金增强铝基复合材料的组织与力学性能研究 [J]. 南京航空航天大学学报, 2023, 40(1): 98
[32]	Yang X, Liang Z M, Wang L W, et al. Interface structure and tensile behavior of high entropy alloy particles reinforced Al matrix composites by spark plasma sintering [J]. Mater. Sci. Eng., 2022, 860A: 144273
[33]	Liu S Y, Li Y X, Yang Y X, et al. Effects of laser power on microstructure and properties of laser cladding NiCoCrAlY coating [J]. J. Netshape Form. Eng., 2022, 14(3): 50
[33]	刘思远, 李玉新, 杨宜鑫等. 激光功率对激光熔覆NiCoCrAlY涂层组织及性能的影响 [J]. 精密成形工程, 2022, 14(3): 50
[34]	Wang P, Du B R, Xu P X, et al. Microstructure evolution and wear-corrosion properties of FeCoCrNiMo coatings manufactured by high-speed laser cladding [J]. Surf. Coat. Technol., 2025, 518: 132917 doi: 10.1016/j.surfcoat.2025.132917
[35]	Zhao D P, Guo J Q, Li X. Friction and wear behavior of Cu/Graphite composite coating electroplated on TC4 alloy [J]. Rare Met. Mater. Eng., 2020, 49(8): 2861
[36]	Naik S N, Walley S M. The Hall-Petch and inverse Hall-Petch relations and the hardness of nanocrystalline metals [J]. J. Mater. Sci., 2020, 55(7): 2661 doi: 10.1007/s10853-019-04160-w
[37]	Li X F, Feng Y H, Liu B, et al. Influence of NbC particles on microstructure and mechanical properties of AlCoCrFeNi high-entropy alloy coatings prepared by laser cladding [J]. J. Alloy. Compd., 2019, 788: 485 doi: 10.1016/j.jallcom.2019.02.223
[38]	Archard J F. Contact and rubbing of flat surfaces [J]. J. Appl. Phys., 1953, 24(8): 981 doi: 10.1063/1.1721448
[39]	Jeong D H, Erb U, Aust K T, et al. The relationship between hardness and abrasive wear resistance of electrodeposited nanocrystalline Ni-P coatings [J]. Scr. Mater., 2003, 48(8): 1067 doi: 10.1016/S1359-6462(02)00633-4
[40]	Jeong D H, Gonzalez F, Palumbo G, et al. The effect of grain size on the wear properties of electrodeposited nanocrystalline nickel coatings [J]. Scr. Mater., 2001, 44(3): 493 doi: 10.1016/S1359-6462(00)00625-4
[41]	Tang Y Q, Kumar A, Chen D L, et al. Bauschinger effect on wear of cold-worked Cu and Mg-A study combining molecular dynamics modeling and experimental investigation [J]. Wear, 2023, 522: 204726 doi: 10.1016/j.wear.2023.204726
[42]	Chen Z, Jing Y Z, Zhang C, et al. Feasibility study of NiCoCrFeAl_0.8Si_0.1(NbMoTaW)_0.1 denary alloy as a bond coat for thermal barrier coatings: from structural stability to high-temperature oxidation behavior [J]. Surf. Coat. Technol., 2025, 512: 132314 doi: 10.1016/j.surfcoat.2025.132314

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