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Characterization of Surface Film of Nb-60Ta-2Zr Alloy Immersed in Simulated Plasma Solution and Whole Blood |
Huizhe LI1,Xiumei LI2,Jian XU1,*( ) |
1. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016 2. School of Stomatology, China Medical University, Shenyang, 110002 |
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Cite this article:
Huizhe LI,Xiumei LI,Jian XU. Characterization of Surface Film of Nb-60Ta-2Zr Alloy Immersed in Simulated Plasma Solution and Whole Blood. Chinese Journal of Materials Research, 2014, 28(8): 601-609.
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Abstract X-ray photoelectron spectroscopy (XPS) was used to characterize the surface films formed on Nb-60Ta-2Zr alloy with an immersion in simulated plasma solution (r-SBF) and human whole blood. Significant difference in the chemical composition and thickness of the oxide films formed on the alloy immersed in these two media was identified. After immersion in r-SBF solution for 24 h, an oxide film of mixed Nb2O5 and Ta2O5 formed on the alloy surface, while on top of which a 50 nm thick deposition film containing Ca and P could be clearly detected. In contrast, for the alloy immersed in whole blood, only a 24 nm thick oxide film of mixed Nb2O5 and Ta2O5 existed, but no deposition film containing Ca and P was detected. It was indicated that even though the ion concentration in these two media is nearly identical, the organic components in human blood such as proteins and blood cells may play a role to inhibit the deposition of Ca and P elements.
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Received: 09 May 2014
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