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Chinese Journal of Materials Research  2013, Vol. 27 Issue (4): 425-431    DOI:
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Influence of Nano- CaCO3 Concentrates on Corrosion Resistance of the Epoxy Coatings
Liu Mingming1 Liu Fuchun1 Han En-Hou1 Tang Nan2 Wan Junbiao2 Deng Jingwei2
1. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2. Jiangxi Electric Power Research Institute, Nanchang 330096
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Liu Mingming Liu Fuchun Han En-Hou Tang Nan Wan Junbiao Deng Jingwei. Influence of Nano- CaCO3 Concentrates on Corrosion Resistance of the Epoxy Coatings. Chinese Journal of Materials Research, 2013, 27(4): 425-431.

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Abstract  In highly-dispersed and stable nano-CaCO3 concentrates, the Sa10 hyperdispersant firmly adsorbed on the surface of CaCO3 nanoparticles and a adsorptive layer formed. Nano-CaCO3 concentrates improved the epoxy coating adhesion and the corrosion resistance. A adsorptive layer produced steric effect and hindered the nano-CaCO3 particles to aggregate, while the solvatable layer transfered nano-CaCO3 particles from the polarity shift to nonpolarity, increasing their compatibility with the epoxy resin, which ensured their uniformity and stable dispersion in the epoxy coatings. Thereby nano-CaCO3 concentrates enhanced the physical shielding of the coatings, and improved the corrosion resistance.
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