Low Temperature Sintering and Performance of CBS/Al2O3 Glass–Ceramic Doped With Li2CO3

Chinese Journal of Materials Research

2012, Vol. 26

Issue (5): 515-520 DOI:

Current Issue | Archive | Adv Search

Low Temperature Sintering and Performance of CBS/Al₂O₃ Glass–Ceramic Doped With Li₂CO₃

FANG Yihang¹, YANG Qinghua¹, LI Hongwei¹, WANG Huanping¹, MA Hongping², XU Shiqing¹

1.College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018
2.School of Mechanical & Automotive Engineering, Zhejiang University of Science and Technology, Hangzhou 310023

Cite this article:

FANG Yihang, YANG Qinghua, LI Hongwei, WANG Huanping, MA Hongping, XU Shiqing. Low Temperature Sintering and Performance of CBS/Al₂O₃ Glass–Ceramic Doped With Li₂CO₃. Chinese Journal of Materials Research, 2012, 26(5): 515-520.

Download:

PDF(947KB)
Export: BibTeX | EndNote (RIS)

Abstract

CBS/Al2O3 glass–ceramic was prepared by using CaO–B2O3–SiO2 (CBS) glass and Al2O3 powders as the raw materials with the mass ratio of 50/50, and the influence of the additive of Li2CO3 on the sintering property, dielectric property and mechanical properties of CBS/Al2O3 composites was investigated. The results show that the additive of Li2CO3 can lower the softening point and viscosity of CBS glass by modifying the structure of CBS glass, and can react with Al2O3 to form low melting phase of Li2AlO2, which can promote the sintering process of CBS/Al2O3 glass–ceramic and result in lowering down the sintering temperature to 830 . However, the excess Li2CO3 can deteriorate the dielectric property and mechanical properties of CBS/Al2O3 glass–ceramic because of the volatilization of Li–compounds. With 0.50% Li2CO3 addition, the CBS/Al2O3 glass–ceramic could be sintered at 830℃ and obtained excellent properties.

Key words: inorganic non–metallic materials CBS/Al2O3 glass–ceramic low temperature sintering

Received: 06 August 2012

ZTFLH:

TQ174，TB321

Fund:

Supported by the Science and Technology Innovative Research Team of Zhejiang Province No.2010R50016 and the Natural Science Foundation of Zhejiang Province No.Y1110648.

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

URL:

https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2012/V26/I5/515

1 TIAN Mingbo, Electronic Pakaging Technology, first edition, (Beijing, Tsinghua University Press, 2003) p.405

(田民波, 电子封装工程, 第1版, (北京, 清华大学出版社, 2003) p.405)

2 CHEN Guohua, Study on Preparation, Properties and Mechanism of Low–Temperature Co–fired Glass Ceramic Materials, Doctoral Dissertation, Central South University (2006)

(陈国华, 低温共烧玻璃陶瓷的制备及性能研究, 博士学位论文, 中南大学(2006))

3 A A El–Kheshen, Effect of alumina addition on properties of glass/ceramic composite, British Ceramic Transactions, 102(5), 205(2003)

4 SHI Keshun, Low temperature co–firing technique for electronic ceramics, Journal of the Chinese Ceramics Society, 35(S1), 108(2007)

(史可顺, 电子陶瓷和器件的低温共烧技术, 硅酸盐学报, 35(S1), 108(2007))

5 YANG Juan, DU Yongguo, ZHANG Weijun, ZHOU Wenyuan, Development of low temperature cofired ceramics, Material Review, 20(10), 12(2006)

(杨娟, 堵永国, 张为军, 周为渊, 低温共烧基板材料研究进展, 材料导报, 20(10), 12(2006))

6 TANG Bin, ZHANG Shuren, ZHOU Xiaohua, YUAN Ying, Temperature–capacitance characteristics of CBS glass and Mn2+ co–doped BaTi03 ceramics, Chinese Journal of materials Research, 21(5), 551(2007)

(唐斌, 张树人, 周晓华, 袁颖, CBS玻璃和Mn2+复合掺杂BaTiO3陶瓷的电容量温度特性, 材料研究学报, 21(5), 551(2007))

7 ZHANG Qingxue, LI Wenlan, ZHUANG Hanrui, Sintering at low temperature and performance for AIN/glass composites, Chinese Journal of materials Research, 17(1), 79(2003)

(张擎雪, 李文兰, 庄汉锐, AIN/玻璃复合材料的低温烧结和性能, 材料研究学报, 17(1), 79(2003))

8 TANG Lifeng, Study on Preparation and Properties of CBS/Al2O3 Glass Ceramics, Master Dissertation, Tianjin University(2008)

(唐利峰, CBS/Al2O3玻璃陶瓷的制备及其性能研究, 硕士学位论文, 天津大学(2008))

9 XU Yang, ZHONG Chaowei, ZHOU Xiaohua, ZHANG Shure, Study of low temperature cofired Al2O3/glass composite substrate material, Development and Application of Materials, 22(6), 20(2007)

(徐洋, 钟朝位, 周晓华, 张树人, 低温共烧氧化铝/玻璃复合基板材料的研究, 材料开发与应用, 22(6), 20(2007))

10 M.M.R.A.Lima, R.C.C.Monteiro, M.P.F.Graca, M.G.Ferreira da Silva, Structural, electrical and thermal properties of borositicate glass–alumina, Journal of Alloys and Compounds, 538, 66(2012)

11 Xiaohua Zhou, Enzhu Li, Shilin Yang, Bo Li, Bin Tang, Ying Yuan, Shuren Zhang, Effects of La2O3–B2O3 on the flexural strength and microwave dielectric properties of low temperature co–fired CaO–B2O3–SiO2 glass–ceramic, Ceramics International, 38, 5551(2012)

12 FANG Liang, ZHOU Hongqian, WEI Pengfei, ZHU Haikui, LIU Ming, Densification and dielectric properties of CABS/Al2O3 system glass–ceramics, Journal of Functional Materials and Devices, 16(6), 575(2010)

(方亮, 周洪庆, 韦鹏飞, 朱海奎, 刘明, 钙铝硼硅/氧化铝系玻璃--陶瓷致密化过程及介电性能, 功能材料与器件学报, 16(6), 575(2010))

13 HAO Yongde, LI Kun, WU Zhaochun, Improvement of LTCC properties of CBS series using Bi2O3, Journal of HuaZhong University of Sci. & Tech. (Natural Science Edition), 39(2), 105(2011)

(郝永德, 李坤, 吴兆春, Bi2O3对CBS系LTCC性能的改进分析, 华中科技大学学报(自然科学版), 39(2),105(2011))

14 HU Yichen, XU Ting, WANG Wen, WANG Zhongjian, JIN Shuo, Study on low temperature Co–fired CaO–ZnO–B2O3–SiO2 Glass/Al2O3 composite ceramic substrate, Glass & Enamel, 38(6), 1(2010)

(胡一晨, 徐庭, 王雯, 王中检, 金硕, CaO--ZnO--B2O3--SiO2玻璃/Al2O3低温共烧复合陶瓷基板研究, 玻璃与搪瓷, 38(6), 1(2010))

15 K.Kata, I.Yasui, The role of glass on alumina–composites, Journal of Ceramics Society of Japan, 97(7), 306(1989) 16 S.H.Wang, H.P.Zhou, Sintering and properties of CaO–Al2O3–B2O3–SiO2 system glass ceramics, Advanced Ceramics and Composites Key Engineering Materials, 247, 389(2003)

17 TANG Lifeng, LIANG Hui, LI Xiaolei, Influence of Li2O doping on the properties of CBS/Al2O3 glass ceramic, Piezoelectrics & Acoustooptic, 31(5), 699(2009)

(唐利锋, 梁辉, 李晓雷, Li2O掺杂对CBS/Al2O3玻璃陶瓷性能的影响, 压电与声光, 31(5), 699(2009))

18 LI Naichao, YI Baolian, LIN Huaxin, KONG Lianying, ZHANG Enjun, QU Tianxi, CHEN Yingcai, Preparation of LiAlO2 used as matrix materials in molten carbonate fuel cells, Journal of Inorganic Materials, 12(2), 211(1997)

(李乃朝, 衣宝廉, 林化新, 孔连英, 张恩俊, 曲天锡, 程英才, 熔融碳酸盐燃料电池隔膜用LiAlO2制备, 无机材料学报, 12(2), 211(1997))

19 C.J.Dileep Kumar, E.K.Sunny, N.Raghu, N.Venkataramani, Ajit R. Kulkarni, Synthesis and characterization of crystallizable anorthite–based glass for a low–temperature cofired ceramic application, Journal of American Ceramics Society, 91(2), 652(2008)

[1]	ZHANG Jingxian HONG Qiuhong SUN Xuetong ZHANG Xinping. Preparation and Properties of Porous TiO₂/HA/TiO₂Composite Coating[J]. 材料研究学报, 2012, 26(6): 572-576.
[2]	ZHANG Wenjie CHEN Jinlei WANG Hong HE Hongbo. Effects of Calcination Temperature on the Photocatalytic Activity of In–TiO₂ Nano–material[J]. 材料研究学报, 2012, 26(6): 561-566.
[3]	LIN Xiaoyan YANG Weihua YANG Wutao WANG Meiqing. Preparation and Characterization of Ti-Supported PbO2 Electrode Doped with Rare Earth Er[J]. 材料研究学报, 2012, 26(4): 367-371.
[4]	GAO Jiacheng WU Shufang YANG Xiaodong CHANG Xin. Effect of Pre–oxidation Powders on Sintering Properties of Uranium Dioxide Pellets[J]. 材料研究学报, 2012, 26(3): 279-283.
[5]	LIU Jia NI Wen YU Miao. Preparation of High–strength Concrete by Using Fly Ash and Iron Ore Tailings as Major Raw Materials[J]. 材料研究学报, 2012, 26(3): 295-301.
[6]	WEI Xiaoqing NI Xingyuan SHEN Jun ZU Guoqing ZHANG Zhihua DU Ai. Synthesis of Thermal Insulation Material Alumina Aerogels and Thermal Properties[J]. 材料研究学报, 2012, 26(3): 261-266.
[7]	ZHANG Wenjie YANG Bo. Synthesis and Photocatalytic Properties of B–doped TiO2[J]. 材料研究学报, 2012, 26(2): 149-154.
[8]	MENG Jinhong CHEN Weihong LIU Yu SUN Jie CAO Xiaohui WANG Wenju YU Mingxun. Synthesis of the Plate–shaped Barium Ferrites by the Second Chemical Co–precipitation Method and Investigation of the Magnetic Properties[J]. 材料研究学报, 2012, 26(1): 107-112.
[9]	YANG Wutao YANG Weihua FU Fang. Preparation and Characterization of PbO2 Electrode Modified With a Mixture of PEG and CPB[J]. 材料研究学报, 2012, 26(1): 8-12.
[10]	WEI Xiaoling YANG Hui SHEN Xiaodong. The Effect of Titania Dopant on the Performance of Sodium-beta''–alumina[J]. 材料研究学报, 2011, 25(6): 597-601.
[11]	XI Xiaowang HU Linhua LIU Weiqing DAI Songyuan. Electron Transport Research in Dye–Sensitized Solar Cells Based on 4–Tert–Butylpyridine[J]. 材料研究学报, 2011, 25(6): 613-617.
[12]	DONG Hongzhou DONG Lifeng. Research on Electrocatalytic Activity of Carbon Nanotube–Supported Pt–bimetallic Nanoparticles for Methanol and Ethanol Oxidations[J]. 材料研究学报, 2011, 25(6): 579-584.
[13]	NI Zifeng LIU Liguo WANG Yongguang. Synthesis and Characterization of Silica Nanowires Catalysted by Tin[J]. 材料研究学报, 2011, 25(2): 183-186.
[14]	QI Enlei MAN Liying WANG Sunhao WANG Jieqiang. Microwave Homogeneous Synthesis and Photocatalytic Property of CeO2 Nanorods[J]. 材料研究学报, 2011, 25(2): 219-224.
[15]	HE Yilun ZHOU Wuxi LI Songlin LIU Huaifei LAI Tianmiao TANG Shenglong. Preparation and High Temperature Phase Stability of La2O3–Y2O3–ZrO2 Composite Ceramic Nanopowder[J]. 材料研究学报, 2011, 25(1): 32-38.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed