Please wait a minute...
Chin J Mater Res  2010, Vol. 24 Issue (6): 592-596    DOI:
论文 Current Issue | Archive | Adv Search |
Aluminum Evaporation from Metallurgical Silicon in Electron Beam Melting Process
DONG Wei1,2,   WANG Qiang1,2,   PENG Xu1,2,   TAN Yi1,2,   JIANG  Dachuan1,2,   LI Guobin1
1.Key Laboratory for Solar Energy Photovoltaic of Liaoning Province, Dalian 116204
2.School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024
Cite this article: 

DONG Wei WANG Qiang PENG Xu TAN Yi JIANG Dachuan LI Guobin. Aluminum Evaporation from Metallurgical Silicon in Electron Beam Melting Process. Chin J Mater Res, 2010, 24(6): 592-596.

Download:  PDF(916KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  Metallurgical grade silicon was purified by electron beam melting (EBM) method. The distribution of aluminum in the ingot was found that aluminum was dragged from the bottom to the top and from the edge to the center of the ingot. The aluminum content in the edge was the lowest, even lower than the detection limit (1×10−5%) of ICP–AES. The evaporation of aluminum during EBM process was studied both theoretically and experimentally. The relationship between the removal efficiency for aluminum and the surface temperature of the melting silicon and melting time was deduced from Langmuir’s equation and Henry law. It showed that the removal efficiency of impurity aluminum increased with the increase of the melting time and the surface temperature of the melting silicon. Good agreement was found between the calculated value and the measured value.
Key words:  inorganic non--metallic materials        silicon        electron beam melting        segregation       evaporation     
Received:  19 April 2010     
ZTFLH: 

TF114.17

 

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2010/V24/I6/592

1 L.J. Liu, S. Nakano, K. Kakimoto, Carbon concentration and particle precipitation during directional solidification of multi-crystalline silicon for solar cells, Journal of Crystal Growth, 310(7-9), 2192(2008) 2 LV Dong, MA Wenhui, WU Jijun, YANG Bin, DAI Yongnian, New process principle and research advances of production of solar grade silicon by metallurgical method, Materials Review, 23(3), 30(2009) (吕东,马文会,武继君,杨斌,戴永年,冶金法制备太阳能级多晶硅新工艺原理及研究进展,材料导报, 23(3),30(2009)) 3 F. A. Trumbore, Solid solubilities of impurity elements in germanium and silicon, Bell System Technical Journal, 39, 205(1960) 4 K. Morita, T. Miki, Thermodynamics of solar-grade-silicon refining, Intermetallics, 11, 1111 (2003) 5 K. Choudhury, E. Hengsberger, Electron beam melting and refining of metals and alloys, ISIJ International, 32(5), 673(1992) 6 T. Ikeda, M. Maeda, Purification of metallurgical silicon for solar-grade silicon by electron beam button melting, ISIJ International, 32(5), 635(1992) 7 K. Hanazawa, N. Yuge, Y. Kato, Y. Kato, Evaporation of phosphorus in molten silicon by an electron beam irradiation method, Materials Transaction, 45(3), 844(2004) 8 HU Gengxiang, CAI Xun, RONG Yonghua, Fundamentals of Material Science(Shanghai, Shanghai Jiaotong University Press, 2006) p.267 (胡赓祥,蔡珣,戎咏华,材料科学基础(上海,上海交通大学出版社,2006) p.267) 9 E. K. Ohriner, Purification of indium by electron beam melting, Journal of Alloys and Compounds, 461(1-2), 633(2008) 10 H. G. Lee, Chemical Thermodynamics for Metals and Materials (London, Imperial College Press, 1999) p.121 11 T. Miki, K. Morita, N. Sano, Thermodynamics of phosphorus in molten silicon, Metallurgical and Materials Transaction B, 29(5) 29, 1043(1998) 12 O. Kubachewski, C.B. Alock, Metallurgical Thermo chemistry (New York, Pergamon Press, 1979) p.187
[1] ZHOU Shuyu,JIN Xiaozhe,LIU jia,TIAN Ruixue,WU Aimin,HUANG Hao. Storage and Transport Properties of Sodium-ions of Carbon-constraint NiS2 Nanostructure as Cathode for Na-S Batteries[J]. 材料研究学报, 2020, 34(3): 191-197.
[2] WANG Song MU Mingwei PENG Ce LI Wa LI Fengyun CAI Qiang** LI Hengde. Synthesis of Mesoporous Carbon/Silica Using the Oligomer of Urea-formaldehyde Resin as Carbon Source and the Influence of Carbonization Temperature[J]. 材料研究学报, 2013, 27(4): 385-390.
[3] HU Jianqing ZHENG Zhixian ZHU Haijun TU Weiping WANG Feng. Synthesis and Characterization of Polyfunctional Aziridine/Polyester Microcapsules by W/O/W Multiple Emulsion–solvent Evaporation[J]. 材料研究学报, 2010, 24(6): 619-624.
[4] TIAN Xiao JIA Qing CUI Yuyou YANG Rui. Thermal Decomposition and Crystallization of Precursor Sol for Preparing Oxidation Resistant Coatings on Intermetallic TiAl[J]. 材料研究学报, 2010, 24(5): 483-486.
[5] LI Li WANG Kuanling LI Jiabo ZHANG Wenjie. Effect of Hydrochloric Acid Modification of NaZSM--5 Zeolite on the Properties of TiO2/ZSM--5 Photocatalyst[J]. 材料研究学报, 2010, 24(5): 535-539.
[6] LIU Donglin LIU Mingxing WANG Xianwen SU Jiangtao. Preparation of Silicon Nanotubes with AAO Template[J]. 材料研究学报, 2010, 24(4): 439-443.
[7] LIAN Xiaonan CHEN Mingcai XU Kai . Preparation of magnesium hydroxide nanoparticles in silicone oil/water mixture[J]. 材料研究学报, 2009, 23(6): 663-667.
[8] PENG Yingcai FU Guangsheng. Approach to quantum dot solar cells[J]. 材料研究学报, 2009, 23(5): 449-457.
[9] ZHU Yuankun ZHU Jiaqi HAN Jiecai LIANG Jun ZHANG Yuanchun. High–temperature thermal stability research on SiC thin films by magnetron sputtering[J]. 材料研究学报, 2009, 23(4): 410-414.
[10] XU Yue ZHANG Tong LI Liuan LI Hongdong LU Xianyi JIN Zengsun. Analysis of residual stress and micro--stress in free--standing boron--doped polycrystalline diamond films by XRD[J]. 材料研究学报, 2009, 23(3): 264-268.
[11] SONG Bing CHENG Ke WU Chao DU Zuliang. Synthesis and their optical characterizations of CdS quantum dots[J]. 材料研究学报, 2009, 23(1): 89-92.
[12] YAN Baiping; ZHU Bingsheng(Xi'an University of Technology) (Xi'an Jiaotong University)LIU Daoxin(The Northwestern Polytechnical University). ORGANIZATION FORM AND HUMIDITY SENSITIVITY OF Sn-SnO_x THIN FILM[J]. 材料研究学报, 1996, 10(1): 73-76.
[13] XU Jian;SUN Xiukui;CHEN Wenxiu;FAN Xueshu;WEI Wenduo(State Key Laboratory of RSA;Institute of Metal Research;Academia Sinica). SYNTHESIS OF Cu ULTRAFINE PARTICLES USING GAS EVAPORATION METHOD[J]. 材料研究学报, 1992, 6(3): 209-213.
[14] LIN Chengfu HUANG Rongfang YU Bing QIAN Shengwei GUAN Kan (Institute of Metal Research;Academia Sinica). PREPARATION SUPERFINE POWDER BY VACUUM ARC PLASMA JET EVAPORATION METHOD[J]. 材料研究学报, 1991, 5(6): 489-493.
[15] WEI Jinyun LIAO Hua WANG Dongcheng (Yunnan Normal University). VACUUM Co-EVAPORATED DEPOSITION FOR CuInSe_2 THIN FILM BY THREE-SOURCES PROCESS[J]. 材料研究学报, 1991, 5(6): 472-476.
No Suggested Reading articles found!