材料研究学报  2008, Vol. 22 Issue (4): 353-356

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纳米复合材料TiO2/ZnFe2O4的制备及光催化性能

陈雪冰;邵忠宝;田彦文;杨雪

东北林业大学

Surface properties Characterization of Melamine Polyphosphate by Inverse Gas Chromatography

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东北林业大学

陈雪冰; 邵忠宝; 田彦文; 杨雪 . 纳米复合材料TiO2/ZnFe2O4的制备及光催化性能[J]. 材料研究学报, 2008, 22(4): 353-356.
, , , . Surface properties Characterization of Melamine Polyphosphate by Inverse Gas Chromatography[J]. Chin J Mater Res, 2008, 22(4): 353-356.

摘要 参考文献 相关文章 Metrics 全文: PDF(827 KB)   关键词 ： 多聚磷酸蜜胺盐,  酸碱性质,  表面自由能,  反相     Abstract：The surface properties of zinc modified melamine polyphosphate (Zn-MPP) and melamine polyphosphate (MPP) were analyzed by inverse gas chromatography (IGC) in this work.. Four n–alkanes (C6, C7, C8, and C9) were chosen as apolar probes to characterize the dispersive component of surface free energy. Trichloromethane (CHCl3), acetone, ether and tetrahydrofuran (THF) were chosen as polar probes to detect the Lewis acid–base parameters. It was found the dispersive component of free energy of zinc modified melamine polyphosphate (Zn-MPP) was 63.3, 61.9, 61.1, and 59.0 mJ/m2 at 100, 110, 120, and 130℃, respectively. And the dispersive component of free energy of melamine polyphosphate (MPP) was 52.9, 53.9, 55.8, and 56.5 mJ/m2 at 100, 110, 120, and 130℃, respectively. The Lewis acidic number Ka of the Zn-MPP was 0.44, and the basic number Kb was 1.02. And the Lewis acidic number Ka of the MPP was 0.24, and the basic number Kb was 0.96. The result means the Zn-MPP and MPP was a weak Lewis basic material. The Lewis acidic number Ka of the Zn-MPP is higher than the MPP. The ratio of Lewis acid–base numbers (Kb /Ka) of Zn-MPP is smaller than MPP. Key words： melamine polyphosphate    Acid–base properties    Surface free energy    IGC 收稿日期: 2007-10-30      ZTFLH:  O643   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 陈雪冰 邵忠宝 田彦文 杨雪 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2008/V22/I4/353 1 M.Koelsch,S.Cassaignon,J.F.Guillemoles,J.P.Jolivet, Comparision of optical and electrochemical properties of anatase and brookite TiO_2 synthesized by the sol-gel method,Thin Solid Films,403,312(2002) 2 S.Andrzej,D.Lukasz,Photocatalytic destruction of cate- chol on illuminated titanic,Reaction Kinetics and Catal- ysis Letters,82,213(2004) 3 M.Zlamal,J.M.Macak,P.Schmuki,J.Kr(?)sa,Electrochem- ically assisted photocatalysis on self-organized TiO_2 nan- otubes,Electrochemistry Communications,9,2822(2007) 4 GAO Lian,ZHEN Shah,ZHANG Qinghong,Photocat- alytic property and application of nanoscale TiO_2 Mate- rials(Beijing,Chemical Industry Press,2002)p.12 (高濂，郑珊，张青红，纳米氧化铁光催化材料及应用(北京，化学工业出版社，2002)p．12) 5 I.Alessandri,E.Comini,E.Bontempi,G.Faglia, L.E.Depero,G.Sberveglieri,Cr-inserted TiO_2 thin films for chemical gas sensors,Sensors and Actuators B: Chemical,128,31(2007) 6 A.I.kokorin,V.M.Arakelyan,V.M.Arutyunian,Spectro- scopic study of polycrystalline TiO_2 doped with vana- dium,Russian Chemical Bulletin:International Edition, 52,93(2003) 7 Y.B.Xie,C.W.Yuan,Visable light induced photocatal- ysis of ceriumion modified titania sol and nanocrystal- lites,Journal of Materials Science and Technology,20(1), 14(2004) 8 HOU Guiqin,LI Zhongqiu,ZHANG Wenli,Progress in nanometer-sized zinc ferrite preparation,China Ceramic Industry,13(1),44(2006) (侯桂芹，李中秋，张文丽，纳米铁酸锌制备方法研究进展，中国陶瓷工业，13(1)，44(2006)) 9 LIU Hui,WEI Yu,ZHANG Yanfeng,JIA Zhenbin,Prepa- ration of nanometer-sized ferrite,Journal of Inorganic Ma- terials,17(1),56(2002) (刘辉，魏雨，张艳峰，贾振斌，纳米铁酸盐的制备研究，无机材料学报，17(1)，56(2002)) 10 M.A.Valenzuela,P.Bosch,J.J.Becerrill,O.Quiroz, A.I.Páez,Preparation,characterization and photocat- alytic activity of ZnO,Fe_2O_3 and ZnFe_2O_4,Journal of Photochemistry and Photobiology A,148,177(2002) 11 K.J.Xu,Preparation and characterization of nano- ZnFe_2O_4/TiO_2 films,Journal of Natural Gas Chem- istry,1(18),100(2007) 12 YUAN Zhihao,SUN Yongchang,WANG Yuhong,Effect of ZnFe_2O_4 dopant on structural phase transformation and photocatalytic activity of TiO_2 nanopowders,Chem- ical Journal of Chinese University,10(24),1875(2004) (袁志好，孙永昌，王玉红，铁酸锌掺杂对二氧化钛结构相变及光催化性能的影响，高等学校化学学报，10(24)，1875(2004)) 13 SHAO Zhongbao,CHEN Yanfang,LUAN Wanqiang, CHEN Xuebing,Preparation and photocatalytic charac- teristics of nanometer-sized TiO_2 by the polyacrylamide gel method,Chinese Journal of Materials Research,19(2), 213(2005) (邵忠宝，陈艳芳，栾万强，陈雪冰，纳米二氧化钛的制备及其光催化活性，材料研究学报，19(2)，213(2005)) 14 ZHENG Guangtao,SHI Jianwei,CHEN Mingxia,YUAN Jian,SHANGGUAN Wenfeng,Transformation and photo- catalytic activities of nano-sized TiO_2 doped by transition metal ions,Journal of Chemical Industry and Engineering, 57(3),564(2006) (郑广涛，施建伟，陈铭夏，袁坚，上官文峰过渡金属离子掺杂纳米TiO_2的相变与光催化活性，化工学报，57(3)，564(2006)) 15 WANG Jun,PAN Zhijun,ZHANG Chaohong,ZHANG Xiangdong,WEN Fuyu,SUN Wei,ZHANG Hanyu,Tran- sition crystal nanometer TiO_2 preparation and sonocat- alytic activity,Chinese Journal of Inorganic Chemistry, 21(10),1566(2005) 王君，潘志军，张朝红，张向东，温福宇，孙伟，张邯玉，转晶纳米TiO_2的制备及其声催化活性的研究，无机化学学报，21(10)，1566(2005) [1] 雷文娟,马应霞,喇培清,刘二燕,李向前,张文娟. 磁性Fe3O4/P(St-co-MMA)微纳米复合物的制备和性能*[J]. 材料研究学报, 2016, 30(9): 711-716. [2] 郭瑞松; 丁湘; 梁青菊; 郭多力; 齐海涛; 杨正方; 陈玉如 . 用反相微乳液法制备陶瓷墨水[J]. 材料研究学报, 2001, 15(5): 581-586. [3] 刘庆普;王燕军;哈润华;姚康德. 过硫酸钾-脲氧化还原引发的甲基丙烯酸乙酯基三甲基氯化铵反相乳液聚合[J]. 材料研究学报, 1997, 11(2): 222-224. Viewed Full text Abstract Cited   Shared      Discussed