基于吩噻嗪的 α， β 不饱和酮衍生物的合成及其非线性光学特性

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Synthesis and Nonlinear Optical Properties of Phenothiazine-functionalized α, β-unsaturated Ketone Derivatives

CHEN Songhua, ZHU Xiangzhao, HU Hongdan, XUE Kai, SONG Yinglin, XIN Dandan, LU Yaqi, LIN Shuidong, YUAN Yaofeng

表1 COP和CNP中的电子和空穴数据

Table 1 Electron and hole data for COP and CNP

Sample Excited state D / nm Sr H / nm t / nm HDI EDI E / eV COP S0-S1 0.0777 0.478 0.215 -0.0211 24.1 10.7 3.41 S0-S2 0.197 0.194 0.683 0.0845 6.65 5.85 3.49 S0-S3 0.196 0.213 0.683 0.0820 6.62 5.85 3.49 S0-S4 0.0466 0.774 0.398 -0.0533 6.23 7.21 4.00 CNP S0-S1 0.412 0.137 0.582 0.227 6.55 5.79 3.07 S0-S2 0.412 0.136 0.582 0.227 6.55 5.79 3.07 S0-S3 0.0034 0.832 0.345 -0.227 6.71 7.12 3.60 S0-S4 0.150 0.679 0.356 -0.0383 6.20 6.73 3.76