高容量锂电池负极材料TiNb2O7的合成及其机理
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谢礼兰, 杨冬升, 凌静
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Synthesis and Formation Mechanism of Lithium Battery High-Capacity Anode Material TiNb2O7
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XIE Lilan, YANG Dongsheng, LING Jing
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表2 TiNb2O7 和 Ti2Nb10O29的晶格参数
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Table 2 Lattice parameters of TiNb2O7 and Ti2Nb10O29
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Compounds/Crystal | Lattice parameters (nm) | JCPDS file no. |
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structure (space group) | This work | Literature[23] |
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TiNb2O7monoclinic(C2/m(12)) | a = 2.0376 | a = 2.0351 | 77-1374 | b =0.3802 | b = 0.3801 | c = 1.1894 | c = 1.1882 | β (°) =120.19 | β (°) =120.19 | Ti2Nb10O29monoclinic (A2/m(12)) | a = 1.5599 | a = 1.557 | 72-0159 | b = 0.3815 | b = 0.3814 | c = 2.0534 | c = 2.054 | β (°) = 113.683 | β (°) = 113.683 |
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