新型Ru(Ⅱ)配合物的合成及其自组装膜的光电性能
杨丽1,2,3,唐志远1,2,3,李腾腾1,2,3,段琪伟1,2,3,胡佳丽1,2,3,张素芳1,2,3,郑照强1,2,3(
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Preparation and Photovoltaic Performance of Novel Ruthenium Complex and Its Self-assembly Membrane
Li YANG1,2,3,Zhiyuan TANG1,2,3,Tengteng LI1,2,3,Qiwei DUAN1,2,3,Jiali HU1,2,3,Sufang ZHANG1,2,3,Zhaoqiang ZHENG1,2,3()
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图1. Ru-1的合成路线
Fig.1. Synthetic route of Ru-1 complex (i) 2,6-bis (1’-methyl-benzimidazolyl)-4-bromopyridine, PdCl2(dppf) CH2Cl2, KOAc in dry DMF; (ii) BBr3 in dry CH2Cl2; (iii) 1-(4-bromobutyl) pyrene and K2CO3 in DMF; (iv) RuCl3·3H2O in DMF: glycerine (1:1)
