Synthesis and Properties of Polyester Ureide Multiblock Copolymers Composed of Poly (butylene-succinate-uera) and Poly (adipate-succinate-uera)

doi:10.11901/1005.3093.2015.577

Chinese Journal of Materials Research

2016, Vol. 30

Issue (7): 553-560 DOI: 10.11901/1005.3093.2015.577

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Synthesis and Properties of Polyester Ureide Multiblock Copolymers Composed of Poly (butylene-succinate-uera) and Poly (adipate-succinate-uera)

DAI Hong, LIU Yuejun^**(

), TAN Haiying, CUI Lingna, YANG Wei

(Key Laboratory of New Materials and Technology for Packaging, HunanUniversity of Technology, Zhuzhou 412007, China)

Cite this article:

DAI Hong, LIU Yuejun, TAN Haiying, CUI Lingna, YANG Wei. Synthesis and Properties of Polyester Ureide Multiblock Copolymers Composed of Poly (butylene-succinate-uera) and Poly (adipate-succinate-uera). Chinese Journal of Materials Research, 2016, 30(7): 553-560.

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Abstract

A series of polyester ureidemultiblock copolymers (PBSu-co-PBAu) composed of the pre-prepared poly(butylene-succinate-urea) (PBSu) and poly(adipate-succinate-uera) (PBAu) were successfully synthesizedby melt polymerization processes with toluene-2, 4-diisocyanate(TDI) as a chain extender. Then the structure, thermal properties, mechanical properties and biodegradable properties of the copolymers were characterized by means of¹H-NMR, DSC, TG, XRD, universal tensile machine and hydrolytictest respectively. The results indicated that the toughness of multiblock copolymers was enhanced by the incorporation of PBAu. The multiblock copolymers possessed excellent thermal stability and biodegradable properties, as well as tensile properties superiorto the homopolymers PBSu and PBAu, the unmodified-PBS and -PBA. Besides, the thermal properties, biodegradability and mechanical properties of the multiblock copolymers can be adjusted by varying the dose of PBSu and PBAu.

Key words: organic polymer materials multiblock copolymers chain extension biodegradability

Received: 15 October 2015

Fund: *Supported by National Natural Science Foundation of China No11372108, National Science Foundation of Hunan Province No14JJ5021 and the Open Fund Project Innovation Platform of University in Hunan No13K098

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	Hong DAI
	Yuejun LIU
	Haiying TAN
	Lingna CUI
	Wei YANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.577 OR https://www.cjmr.org/EN/Y2016/V30/I7/553

Fig.1 ¹H-NMR spectra of PBAu/PBA (A) and PBSu/PBS (B)

Fig.2 ¹H-NMR spectrum of multiblock copolymers

Table 1 Composition for multiblock copolymers and homopolymer (%, mass fraction)

Fig.3 TG curves of copolymers

Table 2 Data for TG analysis of copolymers

Fig.4 DSC curves of copolymers (a) the second heating scan, (b) cooling scan

Table 3 Data for DSC analysis of copolymers

Fig.5 XRD curves of copolymers

Fig.6 The relevance between crystallinity and tensile strength of copolymers (Undetectable. The number in the X axis indicated the percentage composition of PBAu in polyester ureidemultiblock copolymers)

Table 4 Tensile properties of copolymers films

Fig.7 The relevance between crystallinity and weight lost of copolymers. (Undetectable. The number in the X axis indicated the percentage composition of PBAu in polyester ureidemultiblock copolymers)

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