Effect of Molybdenum on Mechanical Properties of ZG04CR13Ni4Mo Stainless Steel

doi:10.11901/1005.3093.2021.627

Chinese Journal of Materials Research

2023, Vol. 37

Issue (1): 65-69 DOI: 10.11901/1005.3093.2021.627

ARTICLES

Current Issue | Archive | Adv Search

Effect of Molybdenum on Mechanical Properties of ZG04CR13Ni4Mo Stainless Steel

ZHANG Yutuo¹^,², ZOU Hao¹, WANG Pei²(

), LIU Gongmei³

^1.School of Materials Science and Engineering, Shenyang Ligong University, Shenyang, 110159, China
^2.Shenyang National Laboratory for Materials Science, Institute of Metal Research. CAS, Shenyang 110016, China
^3.Three Gorges Mechanical and Electrical Engineering Technology Co., Ltd., Chengdu, 610041, China

Cite this article:

ZHANG Yutuo, ZOU Hao, WANG Pei, LIU Gongmei. Effect of Molybdenum on Mechanical Properties of ZG04CR13Ni4Mo Stainless Steel. Chinese Journal of Materials Research, 2023, 37(1): 65-69.

Download:

HTML

PDF(1623KB)
Export: BibTeX | EndNote (RIS)

Abstract

The phase transformation and mechanical properties of two steels of ZG04Cr13Ni4Mo with 12% Cr and 13% Cr, which being subjected to 893 K one-stage tempering and 893 K + 863 K two-stage tempering respectively, were investigated by means of thermal dilatometer, XRD and tensile tester, in order to clarify the effect of Mo and Cr, the two key alloying elements in ZG04Cr13Ni4Mo martensitic stainless steel, a candidate material used widely for hydraulic turbine runners. The results show that with the increase in Mo and Cr content, the A_s temperature (the beginning temperature of austenitization) decreases gradually. For steels with different Mo contents, the amount of martensite converted into reversed austenite in the heating and isothermally holding stage may definitely different with that by directly cooling down to ambient temperature after tempering, when they are subjected to primary tempering at 893 K within the intercritical temperature zone. Therefore, due to such difference in microstructure evolution, when Mo content increases from ~0.3% to ~0.6%, the yield strength of ZG04Cr13Ni4Mo steel containing 12% Cr decreases slightly, while the ultimate tensile strength increases slightly; in the contrast, the yield strength and tensile strength of ZG04Cr13Ni4Mo steel containing 13% Cr all slightly increased after 893K tempering with the same change in Mo content.

Key words: ferrous metals and their alloys ZG04Cr13Ni4Mo stainless steel mechanical properties Mo content tempering

Received: 12 November 2021

ZTFLH:

TG141

Fund: the Scientific Research Project of China Three Gorges Corporation(JD-YJ-05006)

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Yutuo ZHANG
	Hao ZOU
	Pei WANG
	Gongmei LIU

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2021.627 OR https://www.cjmr.org/EN/Y2023/V37/I1/65

Table 1 Chemical compositions of experimental steels (mass fraction, %)

Fig.1 Variations of A_s and A_f with different Mo contents in ZG04Cr13Ni4Mo stainless steels (a) Cr: 12%; (b) Cr: 13%

Fig.2 Variations of R_p0.2, R_m and A₅ Elongation at room temperature with different Mo contents in ZG04Cr13Ni4Mo stainless steels with 12%Cr after 893 K one-stage tempering

Fig.3 Variations of R_p0.2, R_m and A₅ Elongation at room temperature with different Mo contents in ZG04Cr13Ni4Mo stainless steels with 13%Cr after 893 K one-stage tempering

Fig.4 Variations of R_p0.2, R_m and A₅ elongation at room temperature with different Mo contents in ZG04Cr13Ni4Mo stainless steels with 12%Cr after 893 K+863 K two-stage tempering

Fig.5 Variations of R_p0.2, R_m and A₅ elongation at room temperature with different Mo contents in ZG04Cr13Ni4Mo stainless steels with 13%Cr after 893 K+863 K two-stage tempering

Table 2 Volume fraction of reversed austenite in the samples after one- and two-stage tempering (Volume fraction, %)

1	Arakawa J, Kakuta M, Hayashi Y, et al. Fatigue strength of USP treated ASTM CA6NM for hydraulic turbine runner [J]. Surf. Eng., 2014, 30(9): 662 doi: 10.1179/1743294414Y.0000000308
2	Roa C V, Valdes J A, Larrahondo F, et al. Comparison of the resistance to cavitation erosion and slurry erosion of four kinds of surface modification on 13-4 Ca6NM hydro-machinery steel [J]. J. Mater. Eng. Perform., 2021, 30: 7195 doi: 10.1007/s11665-021-05908-9
3	Prasetyo M A, Puspasari V, Anwar M S, et al. Mechanical properties of modified cast martensitic stainless steel CA6NM with addition of molybdenum and nitrogen [A]. Proceedings of the 3rd International Seminar on Metallurgy and Materials [C]. Indonesia, 2020
4	Lu S P, Wang P. The Material and Welding of Hydraulic Turbine Runner Used in Three Gorges [M]. Beijing: China Science and Technology Press, 2014
	陆善平, 王培. 三峡水轮机转轮材料与焊接 [M]. 北京: 中国科学技术出版社, 2014
5	Geng C W, He S S, Yu B. Investigating and manufacturing of ZG0Cr13Ni4Mo martensitic stainless steel [J]. Physical Test, 1992, (4): 13
	耿承伟, 何树生, 于波. ZG0Cr13Ni4Mo马氏体不锈钢研制 [J]. 物理测试, 1992, (4): 13
6	Song Y, Cui J, Rong L. Microstructure and mechanical properties of 06Cr13Ni4Mo steel Treated by quenching-tempering-partitioning process [J]. J. Mater. Sci. Technol., 2016, 32: 189 doi: 10.1016/j.jmst.2015.10.004
7	Wang P. Microstructure and property control of 13Cr4Ni stainless steel and its application in Three Gorges turbine runner [D]. Shen-yang: University of Chinese Academy of Sciences, 2011
	王培. 13Cr4Ni不锈钢组织性能控制及其在三峡水轮机转轮上的应用 [D]. 沈阳: 中国科学院大学, 2011
8	Bilmes P D, Llorente C, Ipina J P. Toughness and microstructure of 13Cr4NiMo high-strength steel welds [J]. J. Mater. Eng. Perform., 2000, 9: 609 doi: 10.1361/105994900770345458
9	Amrei M M, Monajati H, Thibault D, et al. Microstructure characterization and hardness distribution of 13Cr4Ni multipass weld metal [J], Mater. Charact., 2016, 111: 128 doi: 10.1016/j.matchar.2015.11.022
10	Du L, Wang X. Effect of Mo content on microstructure and properties of 00Cr12Ni9Mo(x)Cu2Ti margaging stainless steel [J]. J. Mater. Sci. Eng., 2013, 31(2): 235
	杜乐一, 王小祥. Mo含量对00Cr12Ni9Mo(x)Cu2Ti马氏体时效不锈钢组织和性能的影响 [J]. 材料科学与工程学报, 2013, 31(2): 235
11	Wang P, Lu S, Li D. Investigation on phase transformation of low carbon martensitic stainless steel ZG06Cr13Ni4Mo in tempering process with low heating rate [J]. Acta Metall. Sin., 2008, 44(6): 681
	王培, 陆善平, 李殿中等. 低加热速率下ZG06Cr13Ni4Mo低碳马氏体不锈钢回火过程的相变研究 [J]. 金属学报, 2008, 44(6): 681
12	Wang P, Xiao N, Lu S, et al. Investigation of the mechanical stability of reversed austenite in 13%Cr-4%Ni martensitic stainless steel during the uniaxial tensile test [J]. Mater. Sci. Eng. A, 2013, 586: 292 doi: 10.1016/j.msea.2013.08.028
13	Zhang S H, Wang P, Li D, et al. In situ investigation on the deformation-induced phase transformation of metastable austenite in Fe-13%Cr-4%Ni martensitic stainless steel [J]. Mater. Sci. Eng. A, 2015, 635: 129 doi: 10.1016/j.msea.2015.03.084
14	Zhang S H, Wang P, Li D, et al. Investigation of the evolution of retained austenite in Fe-13%Cr-4%Nimartensitic stainless steel during intercritical tempering [J]. Mater. Design, 2015, 84: 385
15	Zhang S H, Wang P, Li D Z, et al. Investigation of TRIP effect in ZG06Cr13Ni4Mo martensitic stainless steel by in situ synchrotron high energy X-ray diffraction [J]. Acta Metall. Sin., 2015, 51(11): 1306
	张盛华, 王培, 李殿中等. ZG04Cr13Ni4Mo马氏体不锈钢中TRIP效应的同步辐射高能X射线原位研究 [J]. 金属学报, 2015, 51(11): 1306

[1]	MAO Jianjun, FU Tong, PAN Hucheng, TENG Changqing, ZHANG Wei, XIE Dongsheng, WU Lu. Kr Ions Irradiation Damage Behavior of AlNbMoZrB Refractory High-entropy Alloy[J]. 材料研究学报, 2023, 37(9): 641-648.
[2]	QIN Heyong, LI Zhentuan, ZHAO Guangpu, ZHANG Wenyun, ZHANG Xiaomin. Effect of Solution Temperature on Mechanical Properties and γ' Phase of GH4742 Superalloy[J]. 材料研究学报, 2023, 37(7): 502-510.
[3]	FENG Ye, CHEN Zhiyong, JIANG Sumeng, GONG Jun, SHAN Yiyin, LIU Jianrong, WANG Qingjiang. Effect of a NiCrAlSiY Coating on Cyclic Oxidation and Room Temperature Tensile Properties of Ti65 Alloy Plate[J]. 材料研究学报, 2023, 37(7): 523-534.
[4]	SHI Chang, DU Yuhang, LAI Liming, XIAO Siming, GUO Ning, GUO Shengfeng. Mechanical Properties and Oxidation Resistance of a Refractory Medium-entropy Alloy CrTaTi[J]. 材料研究学报, 2023, 37(6): 443-452.
[5]	XIA Bo, WANG Bin, ZHANG Peng, LI Xiaowu, ZHANG Zhefeng. Effect of Tempering Temperature on Microstructure and Impact Properties of Two High-strength Leaf Spring Steels[J]. 材料研究学报, 2023, 37(5): 341-352.
[6]	JIANG Shuimiao, MING Kaisheng, ZHENG Shijian. A Review on Grain Boundary Segregation, Interfacial Phase and Mechanical Property Adjusting-controlling for Nanocrystalline Materials[J]. 材料研究学报, 2023, 37(5): 321-331.
[7]	CHEN Zhipeng, ZHU Zhihao, SONG Mengfan, ZHANG Shuang, LIU Tianyu, DONG Chuang. An Ultra-high-strength Ti-Al-V-Mo-Nb-Zr Alloy Designed from Ti-6Al-4V Cluster Formula[J]. 材料研究学报, 2023, 37(4): 308-314.
[8]	YE Jiaofeng, WANG Fei, ZUO Yang, ZHANG Junxiang, LUO Xiaoxiao, FENG Libang. Epoxy Resin-modified Thermo-reversible Polyurethane with High Strength, Toughness, and Self-healing Performance[J]. 材料研究学报, 2023, 37(4): 257-263.
[9]	ZHAO Yunmei, ZHAO Hongze, WU Jie, TIAN Xiaosheng, XU Lei. Effect of Heat Treatment on Microstructure and Properties of TIG Welded Joints of Powder Metallurgy Inconel 718 Alloy[J]. 材料研究学报, 2023, 37(3): 184-192.
[10]	LIU Dongyang, TONG Guangzhe, GAO Wenli, WANG Weikai. Anisotropy of 2060 Al-Li Alloy Thick Plate[J]. 材料研究学报, 2023, 37(3): 235-240.
[11]	ZHOU Cong, ZAN Yuning, WANG Dong, WANG Quanzhao, XIAO Bolv, MA Zongyi. High Temperature Properties and Strengthening Mechanism of (Al₁₁La₃+Al₂O₃)/Al Composite[J]. 材料研究学报, 2023, 37(2): 81-88.
[12]	YU Cong, CHEN Leping, JIANG Hongxiang, ZHOU Quan, YANG Chenggang. Effect of Deep Cryogenic-Aging Treatment on Microstructure and Mechanical Properties of 7075 Al-alloy[J]. 材料研究学报, 2023, 37(2): 120-128.
[13]	ZHOU Yi, TU Qiang, MI Zhonghua. Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics[J]. 材料研究学报, 2023, 37(10): 739-746.
[14]	XIE Donghang, PAN Ran, ZHU Shize, WANG Dong, LIU Zhenyu, ZAN Yuning, XIAO Bolv, MA Zongyi. Effect of Reinforced Particle Size on the Microstructure and Tensile Properties of B₄C/Al-Zn-Mg-Cu Composites[J]. 材料研究学报, 2023, 37(10): 731-738.
[15]	WANG Wei, ZHOU Shanqi, GONG Penghui, ZHANG Haoze, SHI Yaming, WANG Kuaishe. Effect of Anneal Treatment on Microstructure, Texture and Mechanical Properties of TC4 Alloy Plates[J]. 材料研究学报, 2023, 37(1): 70-80.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed