Conversion of Water-insoluble Aluminum Sources into Metal-organic Framework MIL-53(Al) and its Adsorptive Removal of Roxarsone

doi:10.11901/1005.3093.2017.313

Chinese Journal of Materials Research

2017, Vol. 31

Issue (7): 495-501 DOI: 10.11901/1005.3093.2017.313

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Conversion of Water-insoluble Aluminum Sources into Metal-organic Framework MIL-53(Al) and its Adsorptive Removal of Roxarsone

Shuliang HOU¹, Huigong LU¹, Yifan GU¹, Xiaoliang MA¹, Yinan WU¹(

), Ying WANG²(

), Fengting LI¹

1 College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, 200092, China
2 Department of Chemistry, Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, 200092, China

Cite this article:

Shuliang HOU, Huigong LU, Yifan GU, Xiaoliang MA, Yinan WU, Ying WANG, Fengting LI. Conversion of Water-insoluble Aluminum Sources into Metal-organic Framework MIL-53(Al) and its Adsorptive Removal of Roxarsone. Chinese Journal of Materials Research, 2017, 31(7): 495-501.

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Abstract

The MIL-53(Al) was prepared by hydrothermal method from water-insoluble aluminum sources: alumina, aluminum hydroxide, boehmite. The products were characterized by SEM, XRD, N₂ sorption and TGA, simultaneously compared with MIL-53(Al) prepared from aluminum nitrate. The results show that the water-insoluble aluminum sources can be good candidates for the synthesis of typical MIL-53(Al), BET surface areas of which are about 700-1000 m²/g. It’s also noticed that there is different framework flexibility of synthesized MIL-53(Al) from water-insoluble and soluble aluminum sources. The framework of MIL-53(Al) prepared from alumina mainly shows large-pore structure and less flexibility. The adsorption behavior of roxarsone on MIL-53(Al) was investigated. MIL-53(Al) prepared from alumina shows better adsorptive performance towards roxarsone. The adsorption of MIL-53(Al) from alumina fits well with secondary dynamic mode.

Key words: metal-organic frameworks MIL-53 breathing effect roxarsone adsorption

Received: 20 December 2016

ZTFLH:

TB34

Fund: Supported by National Natural Science Foundation of China (Nos. 51203117 & 21305046) and the Fundamental Research Funds for the Central Universities (Nos. 2014KJ007 & 2015KJ001) (Tongji University)

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	Shuliang HOU
	Huigong LU
	Yifan GU
	Xiaoliang MA
	Yinan WU
	Ying WANG
	Fengting LI

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https://www.cjmr.org/EN/10.11901/1005.3093.2017.313 OR https://www.cjmr.org/EN/Y2017/V31/I7/495

Fig.1 Views of the 3D structure of MIL-53(Al) (left) and its breathing effect (right)

Fig.2 XRD pattern of MIL-53(Al) prepared from different four kinds of aluminum sources

Fig.3 SEM pictures of MIL-53(Al) prepared from different four kinds of aluminum sources

Fig.4 Nitrogen adsorption-desorption isotherms of MIL-53(Al) prepared from different four kinds of aluminum sources

Table 1 Textural properties of MIL-53(Al) prepared from different four kinds of aluminum sources

Fig.5 TGA curves of MIL-53(Al) prepared from different four kinds of aluminum sources

Fig.6 Adsorptionkinetics of MIL-53(Al) materials prepared from different four kinds of aluminum sources and structural formula of ROX inserted

Table 2 Parameters of ROX adsorption on MIL-53(Al) materials prepared from different four kinds of aluminum sources when fitting the adsorption data using primary dynamic model, secondary dynamic model and morries-weber model

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