Preparation and Electrochemical Properties of Li-rich Cathode Material Prepared by Spray Drying Method

doi:10.11901/1005.3093.2018.690

Chinese Journal of Materials Research

2019, Vol. 33

Issue (7): 481-487 DOI: 10.11901/1005.3093.2018.690

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Preparation and Electrochemical Properties of Li-rich Cathode Material Prepared by Spray Drying Method

Pengfei ZHOU,Peng ZHANG(

),Yunhui DU,Yujie WANG,Cheng ZUO

School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044, China

Cite this article:

Pengfei ZHOU,Peng ZHANG,Yunhui DU,Yujie WANG,Cheng ZUO. Preparation and Electrochemical Properties of Li-rich Cathode Material Prepared by Spray Drying Method. Chinese Journal of Materials Research, 2019, 33(7): 481-487.

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Abstract

Li-rich cathode material of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ was prepared by spray drying method. The structure, morphology and electrochemical properties of the materials were characterized and the effect of sintering temperature on electrochemical properties of the material were investigated. Results show that the cathode material has a good layered structure, the primary particles exhibited rather uniform size distribution with average size of 100 nm. The initial discharge specific capacity of the prepared material can reach 220.2 mAh/g. The coulomb efficiency of the material prepared by sintering at 800oC can reach 72.5%, and the capacity retention rate can reach 96.8% after 18 cycles. Meanwhile, it also showed good electrochemical performance in electrochemical impedance and cyclic voltammetry.

Key words: materials science spray drying method Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material electrochemical performance

Received: 05 December 2018

ZTFLH:

TM911

Fund: Supported by Natural Science Foundation of Beijing(2162036)

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	Pengfei ZHOU
	Peng ZHANG
	Yunhui DU
	Yujie WANG
	Cheng ZUO

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https://www.cjmr.org/EN/10.11901/1005.3093.2018.690 OR https://www.cjmr.org/EN/Y2019/V33/I7/481

Fig.1 TG-DTA curves of the precursor

Fig.2 XRD patterns of ma terials sintered at different temperatures (a) 800℃ (b) 850℃ (c) 900℃

Table 1 Lattice parameters of materials sintered at different temperatures

Fig.3 SEM images of sample sintered at 800℃

Fig.4 TEM image of sample of sample sintered at 800℃

Fig.5 First charge/discharge curves of sample sintered at different temperatures

Table 2 First charge/discharge parameter of sample sintered at different temperatures

Fig.6 Charge/Discharge curves of sample sintered at different temperatures under different cycles (a) 800℃ (b) 850℃ (c) 900℃

Fig.7 Discharge mid-point voltage of sample sintered at different temperatures

Fig.8 Cyclic performance of sample sintered at different temperatures

Table 3 Cyclic parameter of sample sintered at different temperatures

Fig.9 Cyclic voltammetry of sample sintered at 800℃

Fig.10 EIS curves and equivalent circuit of sample sintered at different temperatures

Table 4 Impedance of equivalent circuit of sample sintered at different temperatures

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