Effects of Pulsed Electromagnetic Field on the Morphology and Powder Size during Nickel Oxalate Salt Produced by Wet Chemical Method

doi:10.11901/1005.3093.2017.161

Chinese Journal of Materials Research

2017, Vol. 31

Issue (12): 947-954 DOI: 10.11901/1005.3093.2017.161

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Effects of Pulsed Electromagnetic Field on the Morphology and Powder Size during Nickel Oxalate Salt Produced by Wet Chemical Method

Shujing PENG, Lidan TANG, Bing WANG, Jianzhong WANG(

), Jing LIN

School of Chemical and Environmental Engineering, Liaoning University of Technology, Jinzhou 121001, China

Cite this article:

Shujing PENG, Lidan TANG, Bing WANG, Jianzhong WANG, Jing LIN. Effects of Pulsed Electromagnetic Field on the Morphology and Powder Size during Nickel Oxalate Salt Produced by Wet Chemical Method. Chinese Journal of Materials Research, 2017, 31(12): 947-954.

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Abstract

Fibrous particles of nickel oxalate salt were prepared by wet chemical method under the action of pulsed electromagnetic field (PEMF) using NiCl₂ solution as original liquid and (NH4)₂C₂O₄ solution as precipitant reagents, and which then were characterized by means of X-ray diffractometer (XRD), Fourier transform infrared spectrum (FT-IR), scanning electron microscopy (SEM) and laser granularity analyzer. The effect of PEMF parameters on the morphology and powder size of nickel oxalate salt was examined and the relevant mechanism model of interaction between PEMF and reaction system was preliminarily disccussed. Results show that in comparison to the conventional precipitation method, the feeding speed for the present process can be enhanced from 2 mL/min to 5 mL/min, and the aspect ratio of fibrous particles of nickel oxalate salt increased from 7:1 to 25:1 for the produced fibrous particles under PEMF with voltage 600 V, frequency 4 Hz and treatment time 3 min. Besides, not obvious agglomeration could be seen for the products. Finally, the desired fibrous particles of nickel oxalate salt could be prepared by a process in solutions with ammonia to nickel within a range of 0.5 to 2.5 and with appropriate PEMF parameters.

Key words: inorganic non-metallic matericals nickel oxalate salt wet chemical method pulsed electromagnetic field morphology powder size

Received: 02 March 2017

ZTFLH:

TF76

Fund: Supported by Natural Science Foundation of Liaoning Province (No. 201202096), Program for Liaoning Innovative Research Team in University (No. LT2013014), Foundation Department of Education of Liaoning Province (No. L2015236)

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	Shujing PENG
	Lidan TANG
	Bing WANG
	Jianzhong WANG
	Jing LIN

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https://www.cjmr.org/EN/10.11901/1005.3093.2017.161 OR https://www.cjmr.org/EN/Y2017/V31/I12/947

Fig.1 Schematic diagram of the reactor with PEMF system

Fig.2 SEM micrographs of nickel oxalate salt with different pulse voltage (PEMF frequency: 4 Hz; treatment time: 3 min)

Fig.3 SEM micrographs of nickel oxalate salt with different pulse frequency (PEMF voltage: 600 V; treatment time: 3 min)

Fig.4 SEM micrographs of nickel oxalate salt with different pulse period (PEMF voltage: 600 V; PEMF frequency: 4 Hz)

Fig.5 XRD patterns of nickel oxalate salt with different pulse voltage (PEMF frequency: 4 Hz; treatment period: 3 min)

Fig.6 Size distribution of nickel oxalate salt with different pulse voltage (PEMF frequency: 4 Hz; treatment period: 3 min)

Fig.7 IR spectra of nickel oxalate salt with different pulse voltage (PEMF frequency: 4 Hz; treatment period: 3 min)

Fig.8 Electrical conductivity of nickel oxalate salt with different pulse voltage (PEMF frequency: 4 Hz; treatment period: 3 min)

Fig.9 Mechanism model of interaction between PEMF and reaction system

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