Synthesis and Electrochemical Properties of Flower-like SnS2 by Triton X-100 Assisted Hydrothermal Method as Negative Electrode Material for Lithium Ion Batteries

doi:10.11901/1005.3093.2015.406

Chinese Journal of Materials Research

2016, Vol. 30

Issue (1): 63-67 DOI: 10.11901/1005.3093.2015.406

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Synthesis and Electrochemical Properties of Flower-like SnS₂ by Triton X-100 Assisted Hydrothermal Method as Negative Electrode Material for Lithium Ion Batteries

ZHANG Juan¹, CHEN Xiujuan^2,^**(

), ZHANG Penglin¹

1. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2. School of Mechanical and Electronical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

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ZHANG Juan, CHEN Xiujuan, ZHANG Penglin. Synthesis and Electrochemical Properties of Flower-like SnS₂ by Triton X-100 Assisted Hydrothermal Method as Negative Electrode Material for Lithium Ion Batteries. Chinese Journal of Materials Research, 2016, 30(1): 63-67.

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Abstract

Flower-like nanostructured SnS₂ was synthesized by polyethylene glycol octylphenol ether(Triton X-100)-assisted hydrothermal method, the effect of the amount of surfactant Triton X-100 on the ingredient, morphology and electrochemical properties of the synthesized product was studied. Results show that the product is single-phase SnS₂ with crystal structure of hexagonal CdI₂. The Triton X-100 plays a dominative role in controlling the morphology of SnS₂. With a dosage of 0.5 mL Triton X-100 the synthesized SnS₂ possesses the highest degree of crystallinity with a fully flower-like morphology . A rechargeable Li-ion batteries with the as-prepared flowerlike nanostructured SnS₂ as anode exhibits excellent electrochemical performance with high initial discharge specific capacity 1598 mAhg^-1and reversible capacity 656 mAhg^-1 respectively, in a voltage range of 0.01-1.2 V and a rate of 0.15C. After 50 cycles with a rate of 0.15C, the specific capacities retain 572 mAhg^-1 and capacity retention rate can reach 87.2%.

Key words: synthesizing and processing technics Triton X-100 hydrothermal method flower-like SnS2 nanostructure electrochemical properties

Received: 15 July 2015

Fund: *Supported by National Natural Science Foundation of China No.51161012

About author: **To whom correspondence should be addressed, Tel:(0931)2973562, E-mail: chxj305@163.com

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.406 OR https://www.cjmr.org/EN/Y2016/V30/I1/63

Fig.1 XRD patterns of the as-prepared samples with Triton X-100

Fig.2 EDS patterns of the as-prepared samples with 0.5 mL Triton X-100

Fig.3 SEM images of the as-prepared samples with Triton X100 (a) 0 mL, (b) 0.5 mL, (c) a single pattern structure of 0.5 mL, (d) local pattern structure of 0.5 mL, (e) 1 mL, (f) 2 mL

Fig.4 Charge-discharge curves of the as-prepared samples with Triton X-100 at a current density of about 100 mAhg^-1(0.15 C)

Fig.5 Cyclic behavior of the as-prepared samples electrodes with Triton X-100 at a current density of about 100 mAhg^-1(0.15 C)

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