TC11合金表面MLG/Fe2O3纳米颗粒摩擦层的稳定性

doi:10.11901/1005.3093.2019.283

材料研究学报

2019, Vol. 33

Issue (10): 763-770 DOI: 10.11901/1005.3093.2019.283

研究论文

本期目录 | 过刊浏览

TC11合金表面MLG/Fe₂O₃纳米颗粒摩擦层的稳定性

周银¹(

),王树奇²,赵振江¹,许胜¹,王健¹

1. 泰州学院船舶与机电工程学院泰州 225300
2. 江苏大学材料科学与工程学院镇江 212013

Stability of MLG/Fe2O3 Nano-particulate Tribo-layer on TC11 Ti-alloy

ZHOU Yin¹(

),WANG Shuqi²,ZHAO Zhenjiang¹,XU Sheng¹,WANG Jian¹

1. School of Shipping and Mechatronic Engineering, Taizhou University, Taizhou 225300, China
2. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China

引用本文:

周银,王树奇,赵振江,许胜,王健. TC11合金表面MLG/Fe₂O₃纳米颗粒摩擦层的稳定性[J]. 材料研究学报, 2019, 33(10): 763-770.
Yin ZHOU, Shuqi WANG, Zhenjiang ZHAO, Sheng XU, Jian WANG. Stability of MLG/Fe2O3 Nano-particulate Tribo-layer on TC11 Ti-alloy[J]. Chinese Journal of Materials Research, 2019, 33(10): 763-770.

全文: PDF(10539 KB) HTML

摘要:

使用MPX-2000型摩擦磨损实验机对TC11合金在不同载荷和纳米润滑材料条件下进行摩擦磨损实验。使用SEM、EDS、XRD等手段对其磨损表面和剖面的形貌、成分、结构进行了对比观察和分析。结果表明：将不同种类的纳米材料添加到摩擦副的滑动界面，在TC11合金磨损表面均能形成纳米颗粒摩擦层，摩擦层的稳定性取决于其组成和各组分的含量。只含MLG的摩擦层因承载能力差而具有较低的稳定性，极易破坏。只含Fe₂O₃的摩擦层在低载时稳定性较高，能减少磨损但是不能降低摩擦。同时含MLG和Fe₂O₃的双层摩擦层兼具良好的润滑性和承载能力，稳定性强，使TC11合金的摩擦磨损性能显著提高。添加富Fe₂O₃纳米复合材料的双层MLG/Fe₂O₃纳米颗粒摩擦层具有更高的稳定性，能更有效地提高钛合金的摩擦学性能。

关键词 ：材料失效与保护, 纳米颗粒摩擦层, 摩擦磨损, TC11合金, 石墨烯, 稳定性

Abstract：

The tribological behavior of TC11 Ti-alloy was studied via an MPX-2000 type friction and wear tester with TC11Ti-alloy as pin and GCr15 steel as disc in conditions of applying different loads and incorporating various nano-lubricants onto the interface of pin/disc. The surface morphology, cross-section morphology, composition and structure of worn TC11 Ti-alloy were comparatively characterized by means of scanning electron microscopy with energy dispersive spectroscope and X-ray diffractometer. The results show that tribo-layer of nano-particulates could form on the worn surface of TC11 Ti-alloy when different type of nanomaterials were incorporated onto the sliding interface of the tribo-pairs. The stability of the tribo-layer depends on its composition and the relative content of each component. The multi-layered graphene (MLG) containing tribo-layer possessed poor stability and readily damaged because of its low load-bearing capacity. The Fe₂O₃containing tribo-layer possessed good stability under lower loads, resulting in the reduced wear and increased friction. The double-layered tribo-layer composed simultaneously of MLG and Fe₂O₃ possessed high stability, which can be ascribed to the good lubrication and load-bearing capacity. As a result, the friction and wear performance of TC11 Ti-alloy was markedly enhanced. Especially the double-layered MLG/Fe₂O₃ nano-particulate tribo-layer with Fe₂O₃-rich nanocomposite possessed higher stability and thus the tribological properties of TC11 Ti-alloy could be much effectively improved.

Key words： materials failure and protection nano-particulate tribo-layer friction and wear TC11 alloy graphene stability

收稿日期: 2019-05-30

ZTFLH:

TH117.1

基金资助:江苏省高等学校自然科学基金(18KJB430025);江苏省高端结构材料重点实验室开放基金(hsm1807);泰州市科技支撑计划(TS201820);泰州学院高层次人才科研启动基金(TZXY2017QDJJ013)

作者简介: 周银，男，1988年生，博士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	周银
	王树奇
	赵振江
	许胜
	王健
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2019.283 或 https://www.cjmr.org/CN/Y2019/V33/I10/763

图1 MLG和MLG/Fe2O3的制备过程

图2 盘改造的示意图

图3 纳米颗粒的微观形貌

图4 使用不同纳米润滑材料时TC11合金的磨损率与载荷的关系

图5 在纳米润滑材料和载荷不同的条件下滑动体系的平均摩擦系数

图6 在纳米润滑材料和载荷不同的条件下TC11合金的磨面XRD图谱

图7 在纳米润滑材料和载荷不同的条件下TC11合金的磨面形貌

图8 图7中标记区域的EDS分析

图9 在纳米润滑材料和载荷不同的条件下TC11合金的磨损剖面形貌

图10 在纳米润滑材料不同的条件下临界载荷的比较

图11 双层MLG/Fe2O3纳米颗粒摩擦层的形成机理示意图

[1]	Kim H J, Emge A, Karthikeyan S ,et al. Effects of tribooxidation on sliding behavior of aluminum [J]. Wear, 2005, 259: 501
[2]	Straffelini G, Molinari A. Dry sliding wear of Ti-6Al-4V alloy as influenced by the counterface and sliding conditions [J]. Wear, 1999, 236: 328
[3]	Molinari A, Straffelini G, Tesi B ,et al. Dry sliding wear mechanisms of the Ti6Al4V alloy [J]. Wear, 1997, 208: 105
[4]	Qiu M, Zhang Y Z, Yang J H ,et al. Effects of friction heat on tribological properties of Ti6Al4V alloy sliding against GCr15 steel [J]. Tribology, 2006, 26: 203
[4]	邱明, 张永振, 杨建恒等. 摩擦热对Ti6Al4V合金摩擦磨损性能的影响 [J]. 摩擦学学报, 2006, 26: 203
[5]	Sahoo R, Jha B B, Sahoo T K. Dry sliding wear behaviour of Ti-6Al-4V alloy consisting of bimodal microstructure [J]. Trans. Indian Inst. Met., 2014, 67: 239
[6]	Mao Y S, Wang L, Chen K M ,et al. Tribo-layer and its role in dry sliding wear of Ti-6Al-4V alloy [J]. Wear, 2013, 297: 1032
[7]	Wang L, Wang S Q, Zhang Q Y. Effect of the formation of tribo-layer on the wear performance of TC4 alloy [J]. Tribology, 2014, 34: 673
[7]	王兰, 王树奇, 张秋阳. 摩擦层的形成对TC4合金磨损性能的影响 [J]. 摩擦学学报, 2014, 34: 673
[8]	Zhang Q Y, Zhou Y, Wang L ,et al. Investigation on tribo-layers and their function of a titanium alloy during dry sliding [J]. Tribol. Int., 2016, 94: 541
[9]	Li X X, Zhang Q Y, Zhou Y ,et al. Mild and severe wear of titanium alloys [J]. Tribol. Lett., 2016, 61: 1
[10]	Chelliah N, Kailas S V. Synergy between tribo-oxidation and strain rate response on governing the dry sliding wear behavior of titanium [J]. Wear, 2009, 266: 704
[11]	Yao X F, Xie F Q, Han Y ,et al. Effects of temperature on wear properties and friction coefficient of TC4 alloy [J]. Rare Met. Mater. Eng., 2012, 41: 1463
[11]	姚小飞, 谢发勤, 韩勇等. 温度对TC4钛合金磨损性能和摩擦系数的影响 [J]. 稀有金属材料与工程, 2012, 41: 1463
[12]	Shin J H, Lim D S, Ahn H S. Effect of annealing and Fe2O3 addition on the high temperature tribological behavior of the plasma sprayed yttria-stabilized zirconia coating [J]. Surf. Coat. Technol., 2000, 133-134: 403

[1]	幸定琴, 涂坚, 罗森, 周志明. C含量对VCoNi中熵合金微观组织和性能的影响[J]. 材料研究学报, 2023, 37(9): 685-696.
[2]	王伟, 解泽磊, 屈怡珅, 常文娟, 彭怡晴, 金杰, 王快社. Graphene/SiO₂ 纳米复合材料作为水基润滑添加剂的摩擦学性能[J]. 材料研究学报, 2023, 37(7): 543-553.
[3]	张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407.
[4]	李桥, 牛犇, 张瑞谦, 刘会群, 林国强, 王清. Ta/Zr对Fe-Cr-Al-Mo-Nb合金温轧板材高温组织稳定性的影响[J]. 材料研究学报, 2023, 37(6): 423-431.
[5]	姜水淼, 明开胜, 郑士建. 晶界偏析以及界面相和纳米晶材料力学性能的调控[J]. 材料研究学报, 2023, 37(5): 321-331.
[6]	王春锦, 陈文革, 亢宁宁, 杨涛. 石墨烯调控3D打印功能钛的组织和性能[J]. 材料研究学报, 2023, 37(10): 791-800.
[7]	陈开旺, 张鹏林, 李树旺, 牛显明, 胡春莲. 莫来石粉末化学镀镍和涂层的高温摩擦学性能[J]. 材料研究学报, 2023, 37(1): 39-46.
[8]	程红杰, 刘黄娟, 姜婷, 王法军, 李文. 近红外反射超疏水黄色涂层的制备和性能[J]. 材料研究学报, 2022, 36(9): 687-698.
[9]	李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[10]	刘艳云, 刘宇涛, 李万喜. rGO/PANI/MnO₂ 三元复合材料的制备和电化学性能[J]. 材料研究学报, 2022, 36(7): 552-560.
[11]	高巍, 刘江南, 魏敬鹏, 要玉宏, 杨巍. TC4钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能[J]. 材料研究学报, 2022, 36(6): 409-415.
[12]	黄欢, 张迅韬, 杨尚科, 肖刘鑫, 张兆鑫, 严磊, 蔺海兰, 卞军, 陈代强. 氧化石墨烯/苯甲酸钠复合成核剂协同改性PA6纳米复合材料的性能[J]. 材料研究学报, 2022, 36(6): 416-424.
[13]	张姝琪, 董丹丹, 万鹏, 王清, 董闯, 杨锐. 含Al耐热奥氏体不锈钢的团簇式成分设计[J]. 材料研究学报, 2022, 36(5): 353-364.
[14]	杨留洋, 谭卓伟, 李同跃, 张大磊, 邢少华, 鞠虹. 利用WBE及EIS测试技术对管道缺陷区动态冲刷腐蚀行为的研究[J]. 材料研究学报, 2022, 36(5): 381-391.
[15]	刘佳良, 徐东卫, 陈平. 磁性多孔rGO@Co/CoO复合材料的制备和吸波性能[J]. 材料研究学报, 2022, 36(5): 332-342.

Viewed

Full text

Abstract

Cited

Shared

Discussed