Co和Ni对(Fe71.2B24Y4.8)96Nb4块体非晶合金因瓦效应的影响

doi:10.11901/1005.3093.2018.115

材料研究学报

2018, Vol. 32

Issue (9): 691-696 DOI: 10.11901/1005.3093.2018.115

本期目录 | 过刊浏览

Co和Ni对(Fe_71.2B₂₄Y_4.8)₉₆Nb₄块体非晶合金因瓦效应的影响

王金苗¹, 胡强²(

), 严意宏¹, 胡曹生³, 谢盛辉¹, 曾燮榕^1,⁴(

)

1 深圳大学材料学院深圳 518060
2 江西省科学院应用物理研究所南昌 330029
3 江西大有科技有限公司宜春 336000
4 东莞劲胜精密组件股份有限公司东莞 441900

Influence of Co and Ni on Invar Effect of (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ Bulk Metallic Glass

Jinmiao WANG¹, Qiang HU²(

), Yihong YAN¹, Caosheng HU³, Shenghui XIE¹, Xierong ZENG^1,⁴(

)

1 College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
2 Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang, 330029, China
3 Jiangxi Dayou Technology Co. Ltd., Yichun 336000, China
4 Dongguan Janus Precision Components Co. Ltd., Dongguan 441900, China

引用本文:

王金苗, 胡强, 严意宏, 胡曹生, 谢盛辉, 曾燮榕. Co和Ni对(Fe_71.2B₂₄Y_4.8)₉₆Nb₄块体非晶合金因瓦效应的影响[J]. 材料研究学报, 2018, 32(9): 691-696.
Jinmiao WANG, Qiang HU, Yihong YAN, Caosheng HU, Shenghui XIE, Xierong ZENG. Influence of Co and Ni on Invar Effect of (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ Bulk Metallic Glass[J]. Chinese Journal of Materials Research, 2018, 32(9): 691-696.

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摘要:

进行了[(Fe_100-_xCo_x)_71.2B₂₄Y_4.8]₉₆Nb₄(x=0~60)和[(Fe_100-_xNi_x)_71.2B₂₄Y_4.8]₉₆Nb₄(x=0~20)块体非晶合金的热膨胀实验。结果表明,加入Co和Ni使合金的因瓦效应减弱,替代量x相同时减弱的程度也基本相同。这些结果说明,添加Co和Ni对Fe原子局域结构的主要影响是减少了Fe-Fe原子对的数目。同时还发现,居里温度与磁性相变结束后的热膨胀系数呈反向变化,与结构弛豫导致的自由体积释放有关。

关键词 ：金属材料, 铁基块体非晶合金, 因瓦效应, 热膨胀, 居里温度

Abstract：

Thermal expansion behavior of bulk metallic glasses [(Fe_100-_xCo_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (x=0~60) and [(Fe_100-_xNi_x)_71.2B₂₄Y_4.8]₉₆Nb₄ (x=0~20) was investigated. Results show that the Invar effect of the (Fe_71.2B₂₄Y_4.8)₉₆Nb₄ decreases after the addition of Co or Ni, and the decreasing extent is almost the same if the amount of x is the same for Co and Ni respectively. These phenomena indicate that the decreasing amount of the Fe-Fe atomic pairs is the main influence of Co and Ni on the Fe atomic local structure. In addition, the thermal expansion coefficient after the magnetic transition changes oppositely with the Curie temperature, which is mostly related to the free volume annihilation in the structural relaxation.

Key words： metallic materials Fe-based bulk metallic glasses invar effect thermal expansion Curie temperature

收稿日期: 2018-01-18

ZTFLH:

TG139

基金资助:深圳市科技计划(JCYJ20150324141711663, JCYJ20160422104921235)和东莞市引进创新科研团队项目(2014607109)

作者简介:

作者简介王金苗,女,1990年生,硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2018.115 或 https://www.cjmr.org/CN/Y2018/V32/I9/691

图1 [(Fe100-xCox)71.2B24Y4.8]96Nb4和[(Fe100-xNix)71.2B24Y4.8]96-Nb4块体非晶的XRD图谱

表1 Fe、Co、Ni的原子半径ra,熔点Tm和居里温度Tc,原子磁矩M和价电子结构VE以及与B元素的混合焓ΔHTm-B

图2 [(Fe100-xCox)71.2B24Y4.8]96Nb4和[(Fe100-xNix)71.2B24Y4.8]96-Nb4块体非晶的热膨胀曲线

图3 [(Fe100-xCox)71.2B24Y4.8]96Nb4和[(Fe100-xNix)71.2B24Y4.8]96Nb4块体非晶的热膨胀曲线

图4 特征热膨胀系数的定义

图5 Co和Ni元素对特征热膨胀系数和居里温度的影响

图6 磁性转变结束后的热膨胀系数与居里温度的对应关系

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